520 results about "Nano tio2" patented technology

The invention discloses a high-temperature-resistant epoxy resin composite material and a preparation method thereof, and relates to the technical field of composite materials. The high-temperature-resistant epoxy resin composite material is prepared from the following raw materials in parts by weight: 70 to 80 parts of modified epoxy resin, 8 to 15 parts of high-temperature-resistant modifier, 15 to 30 parts of curing agent, 3 to 8 parts of nano reinforcing filler, 1 to 3 parts of coupling agent, 3 to 6 parts of carbon fiber, 2 to 5 parts of nano titanium dioxide, 5 to 10 parts of organic silicon rubber, 1 to 3 parts of conductive agent, 3 to 7 parts of flame retardant and 2 to 4 parts of zinc borate. The high-temperature-resistant epoxy resin composite material has outstanding advantages and strong thermal stability, and can bear high temperature; mechanical performance is excellent, and firmness and durability are achieved; the self-repairing capability is achieved, and the service cycle can be prolonged; the anti-permeability is good, and gas and liquid can be effectively blocked; the surface is smooth, the friction coefficient is low and the application prospect is wide.

The invention discloses ultra-high performance concrete and a preparation method thereof. The ultra-high performance concrete comprises the following components in percentage by mass: 15%-25% of cement, 3%-6% of nano SiO2, 30%-35% of fly ash or steel slag powder, 35%-40% of recycled aggregate, 1%-4% of fiber, 0.5% of a microbial remediation agent and 1%-3% of nano TiO2. The preparation method comprises the following steps: S1, pretreating the recycled aggregate; and S2, packaging the microbial remediation agent: mixing the bacillus pasteurii spores with calcium lactate, and wrapping the mixture in calcium phosphate microspheres. S3, step-by-step stirring; S3.1, dry mixing: uniformly stirring the cement, the fly ash, the nano SiO2, the nano TiO2 and the recycled aggregate; s3.2, wet mixing is carried out, water solution fibers containing the polycarboxylic acid water reducing agent are added, uniform stirring is carried out, and the water-binder ratio of the water solution containing the polycarboxylic acid water reducing agent is 0.18; s3.3, final mixing: adding the packaged microbial remediation agent, and uniformly stirring; and S4, directional curing: performing steam curing at 80 DEG C for 48 hours, performing ultraviolet irradiation, and performing constant-temperature and constant-humidity curing for 7 days. The ultra-high performance concrete has the effects of low cost, low carbon emission, multi-function integration and repeatable crack self-repairing.

The invention relates to the technical field of polypropylene plastics, in particular to a high-strength antibacterial polypropylene plastic and a preparation method thereof. The antibacterial polypropylene material comprises the following components in parts by weight: 60-80 parts of polypropylene resin, 5-15 parts of nano titanium dioxide and nano zinc oxide composite particles modified by a special organosilicon polymer, 3-8 parts of an antibacterial agent compounded by quaternary ammonium salt and bioactive peptide, 5-10 parts of a core-shell structure MBS toughening agent and 0.5-2 parts of a hindered phenol-thioether composite antioxidant. 1-3 parts of a calcium stearate processing aid; and 3-8 parts of dopamine modified chopped carbon fibers. The composite material is high in strength, tensile strength, bending strength and impact strength are remarkably improved, and larger external force can be borne; the antibacterial performance is excellent, and the antibacterial rate reaches 95%-99%; the preparation process is environment-friendly and efficient, and the product is good in stability and recoverable; product safety can be guaranteed, the service life is prolonged, and economic and social benefits are good.

The invention relates to the technical field of PET optical film coatings, in particular to a coating liquid for a PET optical film coating and a preparation method of the coating liquid. The coating liquid for the PET optical film coating is prepared from the following preparation raw materials in parts by mass: 20 to 25 parts of polyurethane acrylic resin, 10 to 15 parts of N-hydroxymethyl acrylamide, 1 to 2 parts of a coupling agent, 4 to 6 parts of a photoinitiator, 8 to 10 parts of modified nano titanium dioxide, 0.2 to 0.3 part of an ultraviolet light absorber and 40 to 47 parts of a reactive diluent. The coating liquid for the PET optical film coating prepared by the invention is excellent in adhesive force, weather resistance, scratch resistance, light transmittance and the like, and has a wide application prospect.

The invention relates to a polymer-based composite solid electrolyte, a preparation method and a sodium solid-state battery, and belongs to the technical field of solid-state batteries. The polymer-based composite solid electrolyte is prepared from the following components in parts by mass: 8 to 12 parts of alkene polymer, 4 to 8 parts of sodium salt and 1 to 8 parts of filler, and the filler is nitrided nano TiO2. The polymer-based composite solid electrolyte can be prepared in a simple and efficient mode, the ionic conductivity is high, the electrochemical stability window is wide, the ionic conductivity reaches 0.3-1.2 mS / cm, and the electrochemical stability window reaches 4.3-5.5 V; and meanwhile, the formation of good SEI can be promoted in the sodium solid-state battery, and the interface stability between the electrolyte and the electrode is improved.

The invention discloses a water-based weather-resistant mildew-proof coating and a preparation method and application thereof.The mildew-proof coating comprises a water-based coating, organic mildew-proof agent missible oil and an inorganic nano-material, the water-based coating comprises water-based acrylic resin and alkyd resin, the mass ratio of the water-based acrylic resin to the alkyd resin is (20-25): 1, the organic mildew-proof agent missible oil is 1: 1, and the inorganic nano-material is 1: 1. The inorganic nano material comprises at least one of nano titanium dioxide, nano zinc oxide and nano silicon dioxide. The preparation method comprises the following steps: mixing the water-based paint, the organic mildew preventive missible oil, the inorganic nano-material, the coalescing agent, the nonionic surfactant and the deionized water to form a mixed solution, and emulsifying the mixed solution under a water bath condition of 50-60 DEG C to obtain the water-based weather-resistant mildew-proof paint. The stability and the storage stability of the mildew-proof coating are at least doubled compared with those of an existing scheme, and the mildew-proof performance is improved by 80% or above.

The invention provides a sintered hollow batten for buildings and a preparation method, and belongs to the technical field of novel wall materials, the sintered hollow batten for buildings comprises the following raw materials: high-calcium fly ash, construction waste recycled aggregate, clay, sulphoaluminate cement, a foaming agent, reinforced fibers and an additive; wherein the particle size of the construction waste recycled aggregate is 0.5-5mm, and the construction waste recycled aggregate is subjected to plasma activation treatment; a nano TiO2 photocatalytic coating is loaded on the surface of the construction waste recycled aggregate; the reinforced fibers are composite fibers of basalt fibers and polypropylene fibers, and the mass ratio of the basalt fibers to the polypropylene fibers is (1: 1)-(1: 2). According to the sintered hollow batten for the building, the building waste recycled aggregate subjected to plasma activation treatment is adopted, and the nano titanium dioxide photocatalytic coating is loaded, so that the bonding strength of the aggregate is greatly improved, and the hollow batten is endowed with the function of degrading pollutants such as formaldehyde.

The invention provides a Claus tail gas hydrogenation catalyst as well as a preparation method and application thereof, and belongs to the technical field of sulfur recovery, the Claus tail gas hydrogenation catalyst comprises an aluminum-titanium-silicon-based composite carrier and active components, the aluminum-titanium-silicon-based composite carrier comprises Al2O3, nano TiO2 and SiO2, the aluminum-titanium-silicon-based composite carrier further comprises an antioxidant, and the active components comprise an active component and an antioxidant. Preparing an aluminum-titanium-silicon-based composite carrier by adopting a mixing and kneading mode; wherein the active components comprise oxides of VIII group metals, oxides of VIB group metals and oxides of rare earth metals, the rare earth metals are mixed and kneaded in the form of oxides and added into the composite carrier, and cobalt and molybdenum are loaded on the carrier by a dipping method. The catalyst has the characteristics of high low-temperature activity and strong oxidation resistance, has the function of catalyzing CO conversion, is suitable for being widely applied to hydrogenation reactors of sulfur recovery devices in the industries of petroleum refining, coal chemical industry and the like, and is particularly suitable for treating acid gas with relatively high CO2 content.

The invention belongs to the field of polymer modification and processing, and particularly relates to a nano photocatalytic self-cleaning composite material, a fresh-keeping cover and a preparation method of the fresh-keeping cover. The composite material comprises aliphatic nylon, a maleic anhydride grafted copolymer, nano titanium dioxide, carbon nanotubes, boron nitride, a coupling agent, a release agent and an antioxidant. The nano photocatalytic self-cleaning composite material is prepared by taking nano titanium dioxide as an antibacterial active agent and adding a certain amount of carbon nanotubes and boron nitride powder. The carbon nanotubes can conduct electrons, have high surface area and high adsorption capacity, and are good dopants and carriers for titanium dioxide as photocatalysts. Hexagonal boron nitride can effectively improve separation and transfer of photo-induced electron-hole pairs of the material, so that the visible light response photocatalytic activity is enhanced. And by adding the carbon nanotubes and boron nitride, the dispersing performance of nano titanium dioxide can be physically improved, titanium dioxide agglomeration is prevented, and the photocatalytic self-cleaning performance of the nano titanium dioxide is improved.

The invention relates to the technical field of high polymer material and polymer modification, in particular to modified asphalt based on nano material reinforcement and a preparation method, the modified asphalt comprises matrix asphalt subjected to molecular cutting and compounding, a nano titanium dioxide-graphene-carbon nano tube ternary composite material, zwitter-ion and silane synergistically modified nano montmorillonite, the rubber powder subjected to special treatment, the bio-based and traditional compound plasticizer and the 2-mercaptobenzimidazole and sulfur compound stabilizer are synergistically modified. The modified asphalt has the advantages of excellent performance, high-temperature stability, low-temperature crack resistance, strong aging resistance, efficient and environment-friendly preparation process, low energy consumption, short period and good nanometer material dispersion, and adopts the bio-based plasticizer to promote the green development of the asphalt industry.

The invention belongs to the technical field of building materials, and discloses a preparation method of reflective heat-insulation waterproof real stone paint, which comprises the following three process stages: core layer synthesis, shell layer loading and real stone paint integration: coating a continuous SiO layer on the surface of nano TiO in situ to form TiO-coated SiO particles; graphene quantum dots and a hindered amine light stabilizer are loaded on the surfaces of TiOatSiO particles to form a composite functional filler; adding the composite functional filler into the acrylic emulsion base material in batches at a low speed, and adjusting the rheological property with the aid to obtain a finished product. The preparation process disclosed by the invention is completely compatible with an existing real stone paint industrial production line, does not need to add special equipment, and has excellent reflective heat insulation, heat preservation, water resistance, weather resistance and aging resistance and large-scale industrial feasibility; the technical problems of resin oxidative degradation caused by TiO photocatalytic activity, rapid attenuation of solar radiation reflectivity, failure of waterproof and hydrophobic performance and easiness in damage and stripping of a coating structure of the existing nano TiO-based reflective heat-insulation real stone paint are solved.

The invention relates to the field of coatings, and discloses weather-resistant and scratch-resistant coated glass and a preparation method thereof.The coated glass comprises a glass substrate and a functional coating formed by thermocuring of a coating composition, and the coating composition comprises waterborne polyurethane, a functional additive and modified graphene oxide; the functional additive is prepared from silica sol and aminopropyl double-terminated polydimethylsiloxane grafted modified nano titanium dioxide; the modified nano titanium dioxide is prepared by enabling 2-(2, 4-dihydroxyphenyl)-2H-benzotriazole and a chloropropyl silane coupling agent to react, grafting the reaction product on the surface of nano titanium dioxide, and then grafting isophorone diisocyanate and pentaerythritol triacrylate; the modified graphene oxide is prepared by grafting a flame-retardant modifier prepared by reacting 3-amino-1, 2, 4-triazole, an amino silane coupling agent, terephthalaldehyde and DOPO with graphene oxide, and the coated glass prepared by the preparation method disclosed by the invention is high in hardness, good in flame retardance and antifouling effect and excellent in wear resistance and ultraviolet resistance.

The invention relates to a honeycomb catalyst for CO and NOx synergistic coupling removal and a preparation method, the catalyst takes nano TiO2-CeO2 as a carrier, and the surface of the carrier is loaded with an active component; the active component comprises a main catalyst and an auxiliary catalyst, the main catalyst is LaCuOx active powder, and the auxiliary catalyst is SmFeOx active powder. According to the present invention, the active material of the conventional catalyst is changed, and the carrier performance of the conventional catalyst is modified, such that the catalyst has good chemical activity and good thermal stability so as to achieve the purpose of stable and synergistic CO removal and NOx removal; meanwhile, the catalyst material is high in mechanical strength and long in chemical life, and the water resistance and the sulfur resistance of the catalyst material are also verified.

The invention relates to the technical field of sewage treatment, in particular to an electrostatic spinning PVDF nanofiber membrane for sewage treatment and a preparation method and application of the electrostatic spinning PVDF nanofiber membrane. The preparation method comprises the following steps: dissolving PVDF (Polyvinylidene Fluoride) particles in a mixed solvent of DMF (Dimethyl Formamide) and acetone, adding nano TiO2 particles subjected to APTES (Aminopropyltriethoxysilane) surface modification, and adding PVP (Polyvinyl Pyrrolidone) into the solution to obtain a uniform spinning solution; spinning by adopting electrostatic spinning equipment to obtain a PVDF / TiO2 / PVP nanofiber membrane; the nanofiber membrane is soaked in a sodium hydroxide solution, then the membrane is soaked in a Tris-HCl buffer solution containing dopamine, and the final electrostatic spinning PVDF nanofiber membrane is obtained. The average diameter of nanofibers of the nanofiber membrane is 200-300nm, the porosity of the membrane is 70-80%, and the water contact angle is less than 60 degrees; when the nanofiber membrane is used for treating sewage containing organic pollutants and heavy metal ions, the removal rate of the nanofiber membrane on methyl orange can reach 95% or above; the rejection rate of copper ions can reach 90% or above; the removal efficiency of organic pollutants and heavy metal ions is obviously improved.

The invention discloses a high-transparency PVB intermediate film and a production process and application thereof, and relates to the technical field of PVB intermediate films, the high-transparency PVB intermediate film comprises the following raw materials by weight: 100 parts of PVB resin, 20-30 parts of a composite plasticizer, 0.5-0.9 part of an LDH-based composite antioxidant, 0.5-1 part of an ultraviolet light absorber, 0.1-1.5 parts of nano lanthanum hexaboride, 0.1-1.5 parts of porous hollow nano copper sulphide, and 0.1-2 parts of nano TiO2 / SiO2 core-shell particles. The PVB intermediate film provided by the invention is relatively high in light transmittance, low in haze value, and excellent in oxidation resistance, weather resistance and mechanical strength.

The invention discloses an interface enhancement gradient design method of an anti-impact aviation glass laminated structure, and relates to the technical field of composite material design, the method comprises the steps of glass material preparation, interface enhancement gradient design, lamination compounding, quality detection and performance testing, the glass material comprises a glass layer material, a middle layer material and a transition layer material, the laminated composite process comprises the steps of pre-strain treatment, pre-pressing treatment, hot-pressing combination and cooling demolding, and has the advantages that by arranging the transition layers with components and performance in gradient change, the content of reinforcing materials such as nanometer titanium dioxide particles and graphene nanosheets in each transition layer is gradually increased; and compared with a traditional uniform or simple layered structure, the gradient design has the advantage that the phenomenon of interface stress concentration caused by performance difference between the glass layer and the polymer intermediate layer is remarkably reduced.

The invention relates to the technical field of basalt scales, and discloses a modified basalt scale material. The invention discloses a modified basalt flake material, which comprises 70-85% of basalt flake, 5-8% of amino silane, 3-5% of nanometer titanium dioxide, 0.5-2% of self-repairing monomer, 3-5% of microcapsule material, 2-4% of environmental response material, 1-2% of nanometer silicon particle and 1-4% of chemical sensing molecule, and the invention also provides a preparation method of the modified basalt flake material. The preparation method comprises the following steps: S1, carrying out high-temperature melting treatment on basalt scales, wherein the melting temperature is 1350-1450 DEG C; through the composite coating of the microcapsule material and the epoxy acrylate, the coating can be automatically repaired after being damaged. Compared with a traditional coating self-repairing capability scheme, the material provided by the invention can quickly activate a repairing monomer when cracks occur, has a quick and continuous self-repairing function, and effectively avoids the problems that the coating repairing process is slow and the effect is short.

The invention provides a nitrogen-doped porous carbon-TiO2 composite carrier and a preparation method thereof and a low-temperature denitration catalyst.The nitrogen-doped porous carbon-TiO2 composite carrier comprises nitrogen-doped porous carbon and nano TiO2, the nitrogen-doped porous carbon is of a two-dimensional carbon sheet layered structure, contains open micropores and mesopores at the same time and is of a hierarchical pore structure, and the diameter of the nitrogen-doped porous carbon is larger than that of the nano TiO2. The nano TiO2 is uniformly dispersed on the surface of the two-dimensional carbon sheet layered structure; the content of the nano TiO2 is 75-90wt% by taking the total weight of the composite carrier as 100%. The nitrogen-doped porous carbon-TiO2 composite carrier has excellent specific surface area, porosity and titanium dioxide dispersibility, can realize complementary advantages of nitrogen-doped porous carbon and TiO2 carriers when being used as a low-temperature denitration catalyst loading substrate, and ensures effective combination of active components and good mass transfer and adsorption of reactants in a denitration reaction process; the adsorption performance, the low-temperature denitration performance and the stability of the catalyst are potentially improved.

The invention belongs to the technical field of granary building coatings, and provides a composite aerogel granary heat preservation and insulation coating as well as a preparation method and a use method thereof. The coating comprises a reflective coating, a heat-insulating coating and a weather-resistant coating, the reflective coating is prepared from water-based acrylic resin, rutile type nano titanium dioxide, hydrophobic silicon dioxide aerogel, an auxiliary agent and water; the heat insulation coating comprises hollow ceramic microbeads, epoxy resin, a polyamide curing agent, nano diatomite, hydrophobic aerogel powder and polyether modified silicone oil; the weather-resistant coating is prepared from organosilicone acrylic resin, nano aluminum oxide, an ultraviolet light absorber and a water-based flatting agent. Through the gradient design of the reflecting layer (visible light reflection), the thermal insulating layer (infrared barrier) and the weather-proof layer (environmental protection), the unification of spectrum selective regulation and control and long-acting protection is realized; the thermal insulation coating is easy to construct, and the construction viscosity is adjusted by adjusting the use amount of water, so that the thermal insulation coating adapts to different construction conditions and process requirements.

The invention discloses sulfate-erosion-resistant metakaolin-slag-based geopolymer concrete, belongs to the technical field of concrete, and aims to solve the problems that the corrosion resistance of traditional silicate concrete is ineffective and the adaptability of conventional alkali-activated concrete is insufficient in a special environment. The concrete comprises the following components in parts by weight: 60-90 parts of a cementing material, 120-170 parts of aggregate, 15-30 parts of a composite activator, 2-8 parts of a function regulator and the like, the cementing material is prepared from nano TiO2 / KH-550 composite modified metakaolin, slag and silica fume-coal gangue powder-HAP composite powder; the aggregate comprises modified limestone macadam (soaked and dried by a sodium dihydrogen phosphate solution) and river sand; the composite exciting agent comprises water glass, sodium hydroxide, sodium pyrophosphate, propylene glycol and the like; the function regulator comprises superfine fly ash, a naphthalene water reducer, HPMC (Hydroxy Propyl Methyl Cellulose) and boric acid. Through the synergistic effect of the components, the sulfate corrosion resistance, the mechanical property and the environmental adaptation performance of the concrete are improved, and the concrete is suitable for engineering construction under the service environment of high-concentration sulfate and the like.

The invention relates to the technical field of card protection films, and discloses an anti-ultraviolet card protection film and a preparation process. Nano titanium dioxide is used as an ultraviolet shielding agent to effectively reflect and absorb ultraviolet rays. The isocyanate group on the surface of TDI-modified silicon dioxide can produce a chemical bonding effect with a hydroxyl group of a hydroxyl-containing copolyester, and the bonding force is relatively strong, thereby improving the interface compatibility between the nano titanium dioxide and a substrate, and the ultraviolet transmittance is relatively low, so that ultraviolet light in the medium-wave region and the long-wave region can be better absorbed. The modified polyethylene terephthalate contains units similar to the structure of the card protection film substrate, thereby improving the dispersibility of the nano titanium dioxide in the substrate and weakening the damage of ultraviolet light to polyethylene terephthalate molecules. At the same time, the molecular chain contains a biphenyl aromatic structure, which increases the rigidity of the molecular chain, helps to improve the heat resistance of the polyester, and further prolongs the service life of the card protection film.

The invention relates to the field of adhesives, and discloses an environmentally friendly urea-formaldehyde resin adhesive and a preparation method thereof. The environmentally friendly urea-formaldehyde resin adhesive comprises the following components in parts by weight: 45-60 parts of urea, 50-80 parts of formaldehyde solution, 10-25 parts of a modified additive, and 5-15 parts of modified polyvinyl alcohol; the modified additive is a modified additive prepared by grafting isophorone diisocyanate onto multi-walled carbon nanotubes loaded with nano-titanium dioxide and further sealing isocyanate with sodium bisulfite; the modified polyvinyl alcohol is modified polyvinyl alcohol grafted with sodium methyl silicate. The invention reduces the free formaldehyde content in the prepared urea-formaldehyde resin adhesive by adding the modified additive and the modified polyvinyl alcohol, and the prepared plywood has low formaldehyde release, is safe and environmentally friendly, and has excellent bonding strength and water resistance.

The invention relates to the technical field of aramid fibers, in particular to a high-strength modified meta-aramid fiber and a preparation method thereof. The meta-position aramid fiber overcomes the problem that the meta-position aramid fiber is poor in mechanical property and ultraviolet resistance. The preparation method comprises the following steps: taking MPD and DDS as diamine solids to react with IPC in a polymerization solvent to generate PMIA; the preparation method comprises the following steps: carrying out surface activation treatment on BNNS to prepare f-BNNS; the preparation method comprises the following steps: carrying out surface grafting and activating treatment on TiO2 to prepare ultraviolet-resistant nano TiO2; pMIA, the composite nano suspension and DDSM are mixed in NMP and defoamed to prepare a modified polymer spinning solution, and the high-strength modified meta-aramid fiber with good mechanical properties and ultraviolet resistance is obtained through dry spraying-wet spinning, gradient cleaning, three-stage hot stretching, heat setting, hot drying and rolling.

The invention relates to the technical field of photoetching, in particular to an anti-HF photoresist-removing alkali-soluble photoresist and a preparation method thereof. The problems that in the prior art, photoresist is poor in hydrofluoric acid resistance effect, and alkali is difficult to dissolve in the photoresist removing process are solved; the preparation method comprises the following steps: introducing a silicon-oxygen bond to obtain modified phenolic resin, adding a fluorine-containing acrylate monomer to obtain modified acrylate, stirring, dispersing, filtering and removing impurities from the modified phenolic resin, the modified acrylate, propylene glycol methyl ether acetate, a photosensitive substance and an auxiliary agent to obtain a photoresist colloid; stirring and dispersing the photoresist colloid and the modified nano titanium dioxide, and removing impurities to obtain the hydrofluoric acid-resistant degumming alkali-soluble photoresist; rigid silica groups and rigid fluorine-containing groups are introduced, modified nano titanium dioxide is cooperatively used for filling gaps of photoresist resin, the hydrofluoric acid resistance of the photoresist is improved, meanwhile, after acid etching, the resin gaps are used for improving the alkali dissolution rate, and pollutant generation and organic solvent use in the photoresist removing process are reduced.

The invention relates to the technical field of recycling of waste textiles, in particular to a method for accelerating degradation of waste polyester, which comprises the following steps: S1, adding crushed polyester materials into organic alcohol, and then adding organic alkali and a photodegradation catalyst to obtain a degradation system; and S2, carrying out a degradation reaction in the degradation system under illumination and heating conditions, and after the reaction is finished, carrying out constant-temperature solid-liquid separation, cooling crystallization, washing and drying to obtain the terephthalic acid glycol ester. The photodegradation catalyst is at least one of nano ZnO and nano TiO2. According to the method disclosed by the invention, low-temperature and rapid degradation can be realized to obtain the terephthalic acid glycol ester, the energy consumption of polyester degradation is effectively reduced, the yield of polyester recovery is improved, and the recycling of polyester fabrics is realized.

The invention relates to the technical field of coating processing, in particular to a high-heat-insulation nanometer silicon heat preservation coating and a preparation method thereof.The high-heat-insulation nanometer silicon heat preservation coating is specifically prepared from, by weight, 15-23 parts of silicone acrylic emulsion, 12-15 parts of nanometer titanium dioxide, 2-5 parts of auxiliaries, 15-23 parts of heat insulation aerogel, 50-58 parts of functional filler and 3-4 parts of propylene glycol. According to the invention, the specially prepared heat insulation aerogel is introduced into the nano silicon coating, so that the heat insulation performance of the coating can be effectively improved, the resistance of the coating to stress can be improved, the cracking phenomenon of the coating can be effectively reduced, the service life of the coating can be prolonged, and meanwhile, the surface roughness of the coating can be remarkably improved; the contact area between the coating and the three-dimensional pattern playing a role in beautifying on the surface of the water cup is increased, so that the bonding strength between the coating and the three-dimensional pattern is improved, the three-dimensional pattern can be kept on the water cup for a long time, and the use experience is improved.

The invention provides a heat insulation and energy storage polylactic acid-based composite material, the polylactic acid-based composite material is a three-layer composite material, and comprises a surface layer, an energy storage layer and a heat conduction buffer layer, the surface layer comprises high-crystallinity polylactic acid, mesoporous SiO2, micron hollow glass beads, nano TiO2, nano ZnO and an antioxidant 1010, the energy storage layer comprises low-crystallinity polylactic acid and phase change microcapsules, and the heat conduction buffer layer comprises a heat conduction buffer layer. The composite material comprises polylactic acid, hydroxylated carbon nanotubes, polycaprolactone, tributyl citrate and an antioxidant 1010, and the composite material comprises medium-crystallinity polylactic acid, hydroxylated carbon nanotubes and polycaprolactone. The polylactic acid-based composite material prepared by the preparation method disclosed by the invention realizes the balance of heat insulation, energy storage and mechanical properties.

The invention discloses a PP (polypropylene) anti-UV (ultraviolet) anti-aging master batch which comprises the following components: an ultraviolet light absorber, an inorganic nano material, an antioxidant, a cross-functional additive with flame retardance and ultraviolet resistance and polypropylene carrier resin, and relates to the technical field of anti-aging master batches. By adding the ultraviolet light absorber, the inorganic nano-material, the antioxidant, the cross-functional additive, the carbon black and other anti-aging auxiliaries into the PP material, the anti-UV anti-aging performance and mechanical performance of the PP material are remarkably improved, by adding the ultraviolet light absorber, the prepared master batch can effectively absorb ultraviolet light and convert the ultraviolet light into heat energy, and the anti-aging performance of the PP material is improved. The anti-ultraviolet PP material has the advantages that the anti-ultraviolet property of the material is further enhanced by combining the anti-ultraviolet PP material with the inorganic nano material nano TiO2, the mechanical property of the material is also obviously enhanced by the inorganic nano material nano TiO2, and the oxidation reaction of the PP material is effectively prevented by adding the antioxidant.

The invention relates to the technical field of dielectric ceramic powder preparation processes, in particular to a multilayer ceramic capacitor, high-activity nano barium titanate powder for the multilayer ceramic capacitor and a preparation method of the high-activity nano barium titanate powder, and the method comprises the following steps: (1) reacting soluble barium salt with a precipitator to obtain barium carbonate precursor particles with high specific surface area; (2) uniformly coating the surfaces of the barium carbonate precursor particles with nano titanium dioxide particles by using a supercritical fluid flash evaporation technology to form a composite precursor; and (3) carrying out solid-phase synthesis reaction on the composite precursor, and sintering to obtain the nano barium titanate powder. Through the synergistic effect of two means of high-activity precursor preparation and nanoscale uniform coating, the composite precursor with extremely high specific surface area, surface energy and microcosmic uniformity is prepared, the thermal sintering temperature is effectively reduced, abnormal growth of crystal grains and lattice distortion are restrained, and the preparation method has the advantages that the preparation process is simple, and the preparation cost is low. The tetragonality of the nano barium titanate powder is obviously improved.

The invention provides a magnesium alloy surface high-wear-resistance micro-arc oxidation film layer and a preparation method thereof. The preparation method comprises the following steps: S1, pretreatment of a magnesium alloy matrix: grinding and polishing the magnesium alloy matrix, and then cleaning and drying the magnesium alloy matrix; s2, preparing a silicate alkaline electrolyte: dissolving Na2SiO3, KF and NaOH in deionized water at room temperature, performing ultrasonic treatment until the Na2SiO3, the KF and the NaOH are completely dissolved, then adding the TiO2 nano-particles, and continuing ultrasonic treatment until the TiO2 nano-particles are uniformly dispersed in the deionized water to obtain the silicate alkaline electrolyte; and S3, micro-arc oxidation treatment is conducted, specifically, stainless steel serves as a cathode, the pretreated magnesium alloy matrix serves as an anode, the cathode and the anode are put into a silicate alkaline electrolyte, flushing and drying are conducted after micro-arc oxidation treatment, and then the high-abrasion-resistance micro-arc oxidation film layer is formed on the magnesium alloy sample. The structure, the structure and the performance of the magnesium alloy micro-arc oxidation film layer are improved by adding the nano TiO2 particles into the electrolyte, so that the wear resistance of the film layer is improved.