310 results about "Nano tio2" patented technology

The invention discloses ultra-high performance concrete and a preparation method thereof. The ultra-high performance concrete comprises the following components in percentage by mass: 15%-25% of cement, 3%-6% of nano SiO2, 30%-35% of fly ash or steel slag powder, 35%-40% of recycled aggregate, 1%-4% of fiber, 0.5% of a microbial remediation agent and 1%-3% of nano TiO2. The preparation method comprises the following steps: S1, pretreating the recycled aggregate; and S2, packaging the microbial remediation agent: mixing the bacillus pasteurii spores with calcium lactate, and wrapping the mixture in calcium phosphate microspheres. S3, step-by-step stirring; S3.1, dry mixing: uniformly stirring the cement, the fly ash, the nano SiO2, the nano TiO2 and the recycled aggregate; s3.2, wet mixing is carried out, water solution fibers containing the polycarboxylic acid water reducing agent are added, uniform stirring is carried out, and the water-binder ratio of the water solution containing the polycarboxylic acid water reducing agent is 0.18; s3.3, final mixing: adding the packaged microbial remediation agent, and uniformly stirring; and S4, directional curing: performing steam curing at 80 DEG C for 48 hours, performing ultraviolet irradiation, and performing constant-temperature and constant-humidity curing for 7 days. The ultra-high performance concrete has the effects of low cost, low carbon emission, multi-function integration and repeatable crack self-repairing.

The invention belongs to the technical field of building materials, and discloses a preparation method of reflective heat-insulation waterproof real stone paint, which comprises the following three process stages: core layer synthesis, shell layer loading and real stone paint integration: coating a continuous SiO layer on the surface of nano TiO in situ to form TiO-coated SiO particles; graphene quantum dots and a hindered amine light stabilizer are loaded on the surfaces of TiOatSiO particles to form a composite functional filler; adding the composite functional filler into the acrylic emulsion base material in batches at a low speed, and adjusting the rheological property with the aid to obtain a finished product. The preparation process disclosed by the invention is completely compatible with an existing real stone paint industrial production line, does not need to add special equipment, and has excellent reflective heat insulation, heat preservation, water resistance, weather resistance and aging resistance and large-scale industrial feasibility; the technical problems of resin oxidative degradation caused by TiO photocatalytic activity, rapid attenuation of solar radiation reflectivity, failure of waterproof and hydrophobic performance and easiness in damage and stripping of a coating structure of the existing nano TiO-based reflective heat-insulation real stone paint are solved.

The invention relates to a honeycomb catalyst for CO and NOx synergistic coupling removal and a preparation method, the catalyst takes nano TiO2-CeO2 as a carrier, and the surface of the carrier is loaded with an active component; the active component comprises a main catalyst and an auxiliary catalyst, the main catalyst is LaCuOx active powder, and the auxiliary catalyst is SmFeOx active powder. According to the present invention, the active material of the conventional catalyst is changed, and the carrier performance of the conventional catalyst is modified, such that the catalyst has good chemical activity and good thermal stability so as to achieve the purpose of stable and synergistic CO removal and NOx removal; meanwhile, the catalyst material is high in mechanical strength and long in chemical life, and the water resistance and the sulfur resistance of the catalyst material are also verified.

The invention relates to the technical field of sewage treatment, in particular to an electrostatic spinning PVDF nanofiber membrane for sewage treatment and a preparation method and application of the electrostatic spinning PVDF nanofiber membrane. The preparation method comprises the following steps: dissolving PVDF (Polyvinylidene Fluoride) particles in a mixed solvent of DMF (Dimethyl Formamide) and acetone, adding nano TiO2 particles subjected to APTES (Aminopropyltriethoxysilane) surface modification, and adding PVP (Polyvinyl Pyrrolidone) into the solution to obtain a uniform spinning solution; spinning by adopting electrostatic spinning equipment to obtain a PVDF / TiO2 / PVP nanofiber membrane; the nanofiber membrane is soaked in a sodium hydroxide solution, then the membrane is soaked in a Tris-HCl buffer solution containing dopamine, and the final electrostatic spinning PVDF nanofiber membrane is obtained. The average diameter of nanofibers of the nanofiber membrane is 200-300nm, the porosity of the membrane is 70-80%, and the water contact angle is less than 60 degrees; when the nanofiber membrane is used for treating sewage containing organic pollutants and heavy metal ions, the removal rate of the nanofiber membrane on methyl orange can reach 95% or above; the rejection rate of copper ions can reach 90% or above; the removal efficiency of organic pollutants and heavy metal ions is obviously improved.

The invention discloses a high-transparency PVB intermediate film and a production process and application thereof, and relates to the technical field of PVB intermediate films, the high-transparency PVB intermediate film comprises the following raw materials by weight: 100 parts of PVB resin, 20-30 parts of a composite plasticizer, 0.5-0.9 part of an LDH-based composite antioxidant, 0.5-1 part of an ultraviolet light absorber, 0.1-1.5 parts of nano lanthanum hexaboride, 0.1-1.5 parts of porous hollow nano copper sulphide, and 0.1-2 parts of nano TiO2 / SiO2 core-shell particles. The PVB intermediate film provided by the invention is relatively high in light transmittance, low in haze value, and excellent in oxidation resistance, weather resistance and mechanical strength.

The invention discloses sulfate-erosion-resistant metakaolin-slag-based geopolymer concrete, belongs to the technical field of concrete, and aims to solve the problems that the corrosion resistance of traditional silicate concrete is ineffective and the adaptability of conventional alkali-activated concrete is insufficient in a special environment. The concrete comprises the following components in parts by weight: 60-90 parts of a cementing material, 120-170 parts of aggregate, 15-30 parts of a composite activator, 2-8 parts of a function regulator and the like, the cementing material is prepared from nano TiO2 / KH-550 composite modified metakaolin, slag and silica fume-coal gangue powder-HAP composite powder; the aggregate comprises modified limestone macadam (soaked and dried by a sodium dihydrogen phosphate solution) and river sand; the composite exciting agent comprises water glass, sodium hydroxide, sodium pyrophosphate, propylene glycol and the like; the function regulator comprises superfine fly ash, a naphthalene water reducer, HPMC (Hydroxy Propyl Methyl Cellulose) and boric acid. Through the synergistic effect of the components, the sulfate corrosion resistance, the mechanical property and the environmental adaptation performance of the concrete are improved, and the concrete is suitable for engineering construction under the service environment of high-concentration sulfate and the like.

The invention provides a heat insulation and energy storage polylactic acid-based composite material, the polylactic acid-based composite material is a three-layer composite material, and comprises a surface layer, an energy storage layer and a heat conduction buffer layer, the surface layer comprises high-crystallinity polylactic acid, mesoporous SiO2, micron hollow glass beads, nano TiO2, nano ZnO and an antioxidant 1010, the energy storage layer comprises low-crystallinity polylactic acid and phase change microcapsules, and the heat conduction buffer layer comprises a heat conduction buffer layer. The composite material comprises polylactic acid, hydroxylated carbon nanotubes, polycaprolactone, tributyl citrate and an antioxidant 1010, and the composite material comprises medium-crystallinity polylactic acid, hydroxylated carbon nanotubes and polycaprolactone. The polylactic acid-based composite material prepared by the preparation method disclosed by the invention realizes the balance of heat insulation, energy storage and mechanical properties.

The invention relates to the technical field of dielectric ceramic powder preparation processes, in particular to a multilayer ceramic capacitor, high-activity nano barium titanate powder for the multilayer ceramic capacitor and a preparation method of the high-activity nano barium titanate powder, and the method comprises the following steps: (1) reacting soluble barium salt with a precipitator to obtain barium carbonate precursor particles with high specific surface area; (2) uniformly coating the surfaces of the barium carbonate precursor particles with nano titanium dioxide particles by using a supercritical fluid flash evaporation technology to form a composite precursor; and (3) carrying out solid-phase synthesis reaction on the composite precursor, and sintering to obtain the nano barium titanate powder. Through the synergistic effect of two means of high-activity precursor preparation and nanoscale uniform coating, the composite precursor with extremely high specific surface area, surface energy and microcosmic uniformity is prepared, the thermal sintering temperature is effectively reduced, abnormal growth of crystal grains and lattice distortion are restrained, and the preparation method has the advantages that the preparation process is simple, and the preparation cost is low. The tetragonality of the nano barium titanate powder is obviously improved.

The invention discloses organic silicon modified acrylic resin antifouling paint and a preparation method thereof, and particularly relates to the field of chemical paint. The antifouling paint is prepared from the following components in parts by mass: 8 to 12 parts of adamantane acrylate, 5 to 8 parts of trifluoroethyl acrylate, 2 to 3 parts of 2-hydroxyethyl acrylic phosphate, 0.8 to 1.2 parts of tert-butyl peroxypivalate, 4 to 6 parts of tridecafluorooctyltrimethoxysilane, 1 to 2 parts of isophorone diisocyanate, 3 to 6 parts of fluorosilane modified nano TiO2 and 1 to 2 parts of graphene oxide. 20-30 parts of deionized water, 0.5-1 part of a polyether modified polysiloxane defoaming agent, and 0.3-0.5 part of an ultraviolet light absorber UV-327 can be additionally added. The preparation method comprises the following steps: S1, preparing isocyanate modified fluorine-containing organic silicon; s2, preparing a ternary copolymer prepolymer; s3, preparing a modified resin matrix; s4, preparing a fluorosilane modified nano TiO2 / graphene oxide composite filler dispersion liquid; and S5, mixing the resin matrix and the dispersion liquid, and performing stirring and vacuum desolventizing to obtain a finished product. The coating has the characteristics of super-hydrophobicity, high hardness, strong adhesion, long-acting antifouling property, aging resistance and environmental protection.

The invention relates to a protective material for building decorative boards, which comprises 55-60% of a main film-forming system, 8-10% of a nanometer functional filler, 12-15% of a functional auxiliary agent, and 15-35% of a carrier and a conditioning agent, and the construction steps of the protective material for building decorative boards comprise base material pretreatment, coating construction, curing and quality inspection. According to the protective material for the building decorative plate and the construction method, the fluorocarbon modified acrylic resin and the organic silicon-acrylic hybrid emulsion are adopted for upgrading a base material, the nano titanium dioxide is added to realize ultraviolet shielding, the graphene is added to realize crack propagation resistance, the weather resistance of the material is improved, the deionized water is used for replacing a traditional solvent, and the cost is reduced. The self-cleaning capacity can be improved by adding hydrophobic nano silicon dioxide, silicon dioxide is added into an intumescent flame-retardant system to serve as a physical anchoring point, and the flame-retardant property of the material is further improved.

The invention relates to the technical field of ceramic-based composite material preparation, in particular to an aluminum oxide-based refractory ceramic composite material and a preparation method thereof.The aluminum oxide-based refractory ceramic composite material is prepared from, by mass, 80-90 parts of modified aluminum oxide, 5-10 parts of modified nano zirconium oxide suspension liquid and 3-5 parts of nano titanium dioxide sol, according to the invention, material component modification, interface structure design and gradient protection technology are optimized, compatibility of a matrix and a reinforced phase is cooperatively regulated and controlled, and low-temperature presintering and surface functionalization treatment technologies are improved, so that thermal shock resistance stability, high-temperature strength retention rate and chemical erosion resistance of the material are improved; the refractory material has excellent durability, provides a new solution for high-performance and engineering application of the refractory material, and has a wide application prospect.

The invention discloses a self-repairing graphene-based wind driven generator blade protection film and a preparation method thereof, and relates to the technical field of wind power generation equipment protection. The protection film adopts a gradient structure of a bonding buffer layer, a self-repairing functional layer and a multifunctional protection layer; the self-repairing functional layer comprises a hybrid network formed by hydroxylated functionalized graphene and elastomer particles and bionic packaging microcapsules, inner layer capsules containing graphene quantum dot reinforced resin and a latent catalyst curing agent are packaged in the microcapsules, multiple times of repairing of the same damaged area can be achieved, and the repairing strength is high; the multifunctional protective layer endows the coating with super-hydrophobic, anti-icing and ultraviolet-resistant functions through fluorinated graphene and nano TiO2 (at) ZnO composite particles; the preparation process is mature, the comprehensive protection performance is excellent, and the coating is suitable for wind driven generator blade protection in the severe environment.

The invention discloses a circulating water purification treatment process for heat exchange equipment, and relates to the technical field of circulating water purification treatment, and the circulating water purification treatment process comprises the following steps: preparing a polyaspartic acid-silane functionalized grafting intermediate; selecting a porous zeolite matrix, and performing acid activation treatment; the preparation method comprises the following steps: preparing a zeolite matrix, soaking the zeolite matrix in sol, standing, defoaming, heating and calcining to obtain a nano TiO2 coated zeolite matrix of which the surface is coated with nano titanium dioxide; immersing the nano TiO2 coated zeolite matrix into the solution, adjusting the pH value of the solution, and stirring for reaction to obtain a PASP functionalized zeolite filter material; and immersing the PASP functionalized zeolite filter material into a silver nitrate solution, carrying out photocatalytic reduction, and carrying out in-situ reduction and deposition on silver ions to obtain the silver / titanium dioxide-polyaspartic acid synergistic functionalized composite filter material. The composite filter material with synergistic functions realizes efficient scale inhibition and sterilization and rapid purification, shows excellent stability and durability under severe working conditions of high temperature, long period and the like, and is environment-friendly and low in maintenance cost.

The invention discloses an aluminum anodic oxidation electrolyte for improving the adhesion density of an electrode foil oxidation film, and relates to the technical field of anodic oxidation, the electrolyte comprises 3%-10% of ammonium dihydrogen phosphate, 0.5%-3% of sulfuric acid, 0.01%-0.2% of nano titanium dioxide or nano aluminum oxide, 0.05%-0.5% of an organic buffer agent, and the balance deionized water; the organic buffering agent is used for stabilizing the pH value in a range of 4.5-6.0; nano titanium dioxide or nano aluminum oxide is used as an oxidation film nucleation center to promote directional crystallization of gamma '-Al2O3; the sulfuric acid component improves the conductivity of the electrolyte; ammonium dihydrogen phosphate generates an aluminum phosphate barrier layer on the surface layer of the oxidation film to enhance the waterproof performance of the film layer; according to the electrolyte, the adhesion density and crystallinity of an oxidation film can be remarkably improved, the uniformity and waterproof performance of a film layer are improved, the specific volume stability and the formation efficiency are improved, and the electrolyte is suitable for continuous production of the high-performance aluminum electrolytic capacitor.

The invention discloses a non-oriented silicon steel composite material and a preparation method thereof.The method comprises the steps that powder of Ce, La and Y elements is subjected to ball milling, and ground powder with the particle size smaller than or equal to 8 micrometers is obtained; adding 0.5-1.2 wt% of nano TiO2 as a modifier into the ground powder, and uniformly depositing a rare earth composite layer on the surface of a non-oriented silicon steel substrate by adopting a magnetron sputtering method to obtain a silicon steel plate; stacking the multiple layers of silicon steel plates to form a laminated layer; zirconia sol is coated on interlayer contact surfaces of the multiple layers of silicon steel plates; standing at a preset temperature for a preset period of time, so that gelation-dehydration-inorganic conversion of the zirconium oxide sol layer is completed, and an assembled silicon steel plate is obtained; and carrying out post-treatment on the assembled silicon steel plate to obtain the non-oriented silicon steel composite material. The magnetic performance, the mechanical toughness and the low-temperature service reliability of the non-oriented silicon steel material are improved.

The invention relates to the technical field of polymer composite materials, in particular to a cable polymer composite material for a wind turbine blade, which is prepared from the following raw materials in parts by weight: a polymer base material; a reinforcing material; a polymer modified material; a functional additive; a performance modifier; the functional additive is prepared from an anti-ultraviolet agent, an antioxidant, a silane coupling agent and nano titanium dioxide. According to the invention, the epoxy modified polyether-ether-ketone and bisphenol A epoxy resin compounded base material is matched with a continuous glass fiber, carbon fiber chopped strand and nano silicon nitride multi-element reinforcing system, so that the core short board of insufficient mechanical properties of the traditional material is thoroughly solved, and a magnesium hydroxide, aluminum hydroxide, expanded graphite and nano montmorillonite compounded flame-retardant system is also selected, so that the flame-retardant performance of the material is greatly improved. The flame-retardant cable material is high in flame retardance, free of toxic gas release, capable of meeting the environment-friendly requirement, capable of improving the material interface bonding force and long-term service reliability and capable of meeting the requirement for the service life of 20 years or above of wind power blade cables.

The invention relates to the technical field of fiber reinforced resin-based composite materials, and discloses a basalt fiber epoxy resin composite material as well as a preparation method and application thereof. Comprising the following steps: carrying out oxygen plasma treatment and dopamine bionic liquid deposition treatment on basalt fibers, dipping the basalt fibers in a mixed coupling agent solution, and coating the basalt fibers with nano TiO2 sol to obtain nano roughened basalt fibers; mixing bisphenol A epoxy resin, hydrogenated bisphenol A epoxy resin, hyperbranched polyesteramine and ionic liquid modified boron nitride nanosheets to obtain resin A; mixing an epoxy curing agent with a curing accelerator to obtain resin B; and mixing the resin A and the resin B to obtain a mixed material, and infiltrating the nano roughened basalt fibers in the mixed material to obtain the basalt fiber epoxy resin composite material. After the basalt fiber is subjected to bionic multi-stage interface treatment, the basalt fiber is matched with the modified epoxy resin, so that the interface strength, the mechanical property and the weather resistance of the composite material are remarkably improved, and the composite material has a relatively good application scene.

The invention discloses a flue gas wet desulphurization composite nano synergist and a preparation method thereof, the flue gas wet desulphurization composite nano synergist comprises the following components by mass: 60-70 parts of organic acid, 10-20 parts of a nano metal oxide compound, 5-10 parts of a surfactant, 3-8 parts of a pH value regulator, and 3-8 parts of a dispersant; the organic acid is a mixture of adipic acid and glutaric acid; the nano metal oxide compound is a mixture of nano titanium dioxide, nano zinc oxide and nano copper oxide, and the mass ratio of the nano titanium dioxide to the nano zinc oxide to the nano copper oxide is (2-5): (1-4): 1. The problems that in an existing desulfurization process, the desulfurization efficiency is low, the limestone utilization rate is not high, equipment is prone to scaling and corrosion, and desulfurization by-products are poor in quality are solved. The desulfurization synergist can significantly improve the desulfurization efficiency, reduce the operation cost, reduce the damage to equipment, and improve the overall performance and stability of a desulfurization system.

The invention provides antibacterial and antifogging glasses wiping cloth and a preparation method thereof, and relates to the technical field of glasses cleaning. Comprising a base material layer, the base material layer is a fiber fabric internally provided with a micropore structure, the fiber fabric is formed by blending sea-island fibers and bamboo charcoal fibers, an antibacterial layer is arranged on the surface of the base material layer, an anti-fog layer is sprayed on the surface of the base material layer, and the antibacterial layer is formed after the base material layer is soaked in composite antibacterial liquid and cured. The composite antibacterial liquid comprises quaternary ammonium salt modified chitosan and polyhexamethylene biguanide, the quaternary ammonium salt modified chitosan is covalently bonded with the fiber surface through an epoxy group cross-linking agent, the polyhexamethylene biguanide is dispersed in the microporous structure, and the anti-fog layer is formed by a sulfobetaine methacrylate polymer grafted on the surface of the base material layer. And a modified nano TiO2-SiO2 core-shell structure is embedded in the zwitterionic polymer. The 24-hour antibacterial rate of the glasses wiping cloth is greater than 99%; after 50 times of standard washing, the antibacterial rate is still greater than or equal to 95%; the antifogging duration is longer than or equal to 33 days and far exceeds that of a temporary coating.

The invention discloses a preparation method of a copper-palladium alloy loaded nano titanium dioxide semiconductor material as a catalyst for a carbon dioxide reduction reaction. Firstly, alloy nanoparticles are generated through a sol-gel method, the morphology of the nanoparticles is controlled and agglomeration is prevented through oleylamine and oleic acid, and borane-tert-butylamine is added at the temperature of 170 DEG C to regulate and control the sizes of the generated alloy nanoparticles. A series of characterizations prove that the catalyst has a very good particle loading condition, uniform particle distribution and increased reaction active sites, and shows excellent activity when being applied to a carbon dioxide reduction reaction, when the loading capacities of copper and palladium are respectively 1%, the activity of the obtained catalyst is the highest, the methane generation rate can reach 20.23 mol / g / h, and the methane generation rate can reach 20.23 mol / g / h. The selectivity of methane reaches 100%.

The invention discloses a white UV coating easy to deeply cure and application of the white UV coating in a calcium silicate board coating. The white UV coating easy to deeply cure is prepared from the following components in parts by weight: 30 to 40 parts of polyurethane acrylate, 5 to 25 parts of reactive diluent, 10 to 20 parts of silane modified acrylic resin, 20 to 30 parts of nano TiO2 coated SiO2 with a core-shell structure and 3 to 5 parts of free radical photoinitiator. The white UV coating easy to deeply cure, which is prepared by mixing the raw materials, can form a high-strength, high-curing-rate and whiteness-adjustable UV curing coating on the surface of a calcium silicate board, can solve the industrial problem that the surface of a thick coating on the surface of the calcium silicate board is dry and the inside of the thick coating is not dry, and has a good application prospect in the field of building materials.

The application provides a foamed alkali-activated cementitious material, which is composed of an intermediate layer and surface layers covering the upper and lower surfaces of the intermediate layer, and the intermediate layer and the surface layers comprise the following raw materials: 30-50 parts by mass of blast furnace slag, 12-18 parts by mass of low-calcium fly ash, 9-15 parts by mass of alkaline magnesium slag, 10-15 parts by mass of alkali activator, 6-8 parts by mass of foaming agent and 3-5 parts by mass of foam stabilizer; the surface layer further comprises 1.5-5 parts by mass of functional catalyst, and the functional catalyst is gel-like micro-nano TiO2 particles. The application utilizes fly ash, magnesium slag and slag and other types of solid waste to prepare building materials with the ability to degrade formaldehyde. Compared with traditional porous foamed materials, the foamed alkali-activated cementitious material prepared by using aluminum powder as a foaming agent has the advantage of utilizing industrial by-products, and the excess aluminum powder not only produces a dense and uniform pore structure, but also is conducive to the adsorption of formaldehyde gas and the improvement of mechanical strength.

The invention discloses nanoscale Ti2O3, a preparation method and application of the nanoscale Ti2O3 as a catalyst carrier, and belongs to the technical field of nano material preparation. According to the invention, a solid-phase synthesis method is utilized, nano titanium powder and nano titanium dioxide are used as raw materials, and the nano-scale Ti2O3 brownish black powder with uniform particle size distribution is controllably synthesized. Meanwhile, a series of noble metal supported catalysts are synthesized by taking the catalyst as a catalyst carrier. According to the invention, rapid synthesis of nanoscale Ti2O3 is realized, and the particle size of the prepared sample is uniform and is about 300nm. The preparation method has the characteristics of high efficiency, rapidness, low equipment requirement, simplicity, easiness in repetition, high product purity and capability of realizing large-scale synthesis. Meanwhile, the prepared nanoscale Ti2O3 is small in size and uniform, so that a catalyst prepared by taking the nanoscale Ti2O3 as a carrier has relatively good dispersity, shows excellent electrocatalytic activity, can be prepared into catalyst slurry with relatively high uniformity, and is suitable for the fields of electrochemical catalysis and energy conversion.

The invention relates to the technical field of wire and cable manufacturing, in particular to an anti-corrosion cable and a preparation method thereof, and the anti-corrosion cable comprises a conductor, an anti-corrosion isolating layer, an insulating layer, an armor layer and an outer sheath from inside to outside. The surface of the conductor is plated with an aminated graphene-nickel-phosphorus composite plating layer; the anti-corrosion isolating layer contains 30-40 parts of fluorine rubber, 10-15 parts of nano boron nitride-silicon dioxide core-shell particles and the like; the insulating layer contains 45-55 parts of crosslinked polyethylene, 8-12 parts of montmorillonite-carbon nanotube-graphene composite powder and the like; the armor layer is formed by compounding a basalt fiber-glass fiber composite filament woven mesh and a polyether-ether-ketone-polyimide composite film; and the outer sheath contains 25-35 parts of chlorinated polyethylene, 5-8 parts of nano titanium dioxide-cerium oxide composite powder and the like. The corrosion-resistant cable has the advantages of corrosion resistance, strong weather resistance, excellent electrical and mechanical properties, long service life and low maintenance cost, can stably operate for a long time in severe environments such as high salinity and high humidity, and is suitable for multi-corrosion scenes.

The application discloses a circulating water purification treatment process for heat exchange equipment and relates to the technical field of circulating water purification treatment, and comprises the following steps: preparing a polyaspartic acid-silane functionalized graft intermediate; selecting a porous zeolite matrix and performing acid activation treatment; immersing the matrix in sol, standing for defoaming, and performing temperature rising calcination to obtain a nano TiO2-coated zeolite matrix coated with nano titanium dioxide on the surface; immersing the nano TiO2-coated zeolite matrix in a solution, stirring and reacting after adjusting the pH value of the solution to obtain PASP functionalized zeolite filter material; immersing the PASP functionalized zeolite filter material in a silver nitrate solution, performing photocatalytic reduction, reducing and depositing silver ions in situ, and obtaining silver / titanium dioxide-polyaspartic acid synergistic functionalized composite filter material. Through the synergistic composite filter material, efficient scale inhibition and sterilization and rapid purification are realized, excellent stability and durability are exhibited under harsh working conditions such as high temperature and long period, the application is environment-friendly, and the maintenance cost is low.

The present application relates to a kind of high adhesive composite material for rubber dam and its preparation method, it is related to rubber dam technical field, wherein the high adhesive composite material for rubber dam includes the weatherproof layer of outer layer, the reinforcing layer of middle, inner layer self-repairing layer, by mass fraction, the weatherproof layer includes 90-110 parts high saturated nitrile rubber, 23-28 parts carbon black N550, 3-8 parts nano TiO2, 1-3 parts antioxidant 1010, 2-3 parts of dicumyl peroxide, the reinforcing layer includes 60-80 parts of ethylene-propylene-diene rubber, 25-35 parts of butadiene-styrene rubber, 13-15 parts, nylon fiber, 10-12 parts aramid fiber, 12-15 parts carbon black, 0.5-1.5 parts graphene, 1-2 parts of sulfur, 0.5-1.5 parts of accelerator CZ, the self-repairing layer includes 90-100 parts of silicone rubber, 5-10 parts nano SiO2, 5-8 parts self-repairing agent, 0.1-0.3 parts dispersant.The high adhesive composite material for rubber dam of the present application has good adhesion, can repair small crack in time, prevent the further expansion of crack.

The preparation method comprises the following steps: reacting hemp fibers with a quaternary ammonium salt cationic etherifying agent under an alkaline condition to prepare a cationic hemp fiber adsorbent, and reacting the cationic hemp fiber adsorbent as a carrier with a titanate precursor under a closed hydrothermal condition to prepare the TiO2-cationic hemp fiber composite photocatalytic material. The nano TiO2 grows in situ and is loaded on the surface and in pores of the adsorbent, so that the composite photocatalytic material with efficient adsorption and photocatalytic degradation functions is formed. The composite photocatalytic material disclosed by the invention is mild in preparation process, simple and convenient to operate and green and renewable in raw material, is particularly suitable for efficient purification and circular treatment of high-concentration and high-chroma anionic dye wastewater, and has a good practical application prospect.

The invention relates to the technical field of ceramic material processing, in particular to low-temperature crystallized SiBCN ceramic and a preparation method thereof. The SiBCN ceramic materials with different components, different crystallinity degrees and microstructures are prepared by adding an auxiliary agent, namely nano Ti or nano TiO2, into PBSZ powder and adopting a ball-milling blending method and changing the doped auxiliary agent, the mass ratio of the doped auxiliary agent and the heat treatment temperature of the doped auxiliary agent. According to the material, low-temperature crystallization is maintained, and meanwhile, the problem that the dielectric property of pure SiBCN ceramic is poor is greatly solved. The method has the advantages that the process is simple, the reaction is controllable, the SiBCN ceramic with a large number of crystals is obtained after heat treatment at low temperature (less than or equal to 1400 DEG C), and the SiBCN ceramic has good electromagnetic wave loss performance.

This invention discloses a synchronously degradable gravure ink for biodegradable plastic films and its preparation method, relating to the field of environmentally friendly inks. It comprises the following components: 35-55 parts of a biocompatible binder resin, 12-18 parts of organic pigment, 30-40 parts of a bio-based solvent, 0.5-1.5 parts of nano-titanium dioxide, and 1-2 parts of a dispersant. The biocompatible binder resin is a ternary block copolymer of PLA, PCL, and PBAT, with PBAT having a molecular weight of 3000-5000 g / mol. The bio-based solvent is a composite solvent of ethyl lactate and γ-valerol, with a mass ratio of ethyl lactate to γ-valerol of 1:0.5-2. The ink prepared by this invention exhibits excellent adhesion and maintains its integrity under bending and stretching of the substrate. It shows no sedimentation after 30 days of storage and maintains stable viscosity; its gloss reaches 85%. Furthermore, at test points of 30 and 60 days, the ink of this invention exhibits highly synchronous degradation behavior on both PLA and PBAT substrates.

The invention belongs to the technical field of nano materials, and particularly discloses a magnetic nano titanium dioxide composite material as well as a preparation method and application thereof. The preparation method comprises the following steps: (1) mixing a Fe < 2 + > / Fe < 3 + > mixed solution with a titanium source to form a uniform mixed solution; (2) dropwise adding a dispersing agent into the mixed solution, and stirring and mixing to obtain a reaction system; (3) carrying out heating and ultrasonic treatment on the system, adding an alkali source to adjust the pH value of the reaction system, and continuing the reaction; (4) after the reaction is finished, separating magnetic particles by adopting an external magnetic field, washing, and carrying out vacuum drying to obtain a Fe3O4 / TiO2 composite material; and the dispersing agent is a cocamidopropyl betaine or polyaspartic acid aqueous solution. The particle size of the prepared particles can be as low as 130 nm, PDIlt; 0.3 part; the saturation magnetization is greater than or equal to 40 emu / g, and the magnetic recovery efficiency within 30 seconds is greater than or equal to 90%; the degradation rate of visible light to organic pollutants within 50 minutes is greater than or equal to 57.8%, and the particle size change 1t within 72 hours under the condition that the pH value is 7-11; 15%; the magnetic nano titanium dioxide composite material disclosed by the invention has important application potential in the fields of photocatalysis and industrial wastewater treatment.