The combustion catalyst for carbon-base fuel is prepared through compounding the main material and the auxiliary material into matrix, and dissolving the matrix in solvent. The main material includes alkyl alcohol ether, alkyl ester, olefin and aromatic compound; and the auxiliary material includes phosphate ester, chlorohydrocarbon, alkyl alcohol amide, metal compound and small amount of nitrogen, silicon and oxygen containing organic compound. When it is used, the combustion catalyst is mixed with carbon-base fuel through spraying or stirring. It promotes combustion by means of increasing the free radicals in the system, and can raise the combustion strength and efficiency and reach the aims of saving energy, raising efficiency, reducing pollution, etc.