This invention relates to the field of
metal surface treatment technology. The method first involves
anodizing an aluminum
alloy sheet in a
sulfuric acid electrolyte to obtain a
porous oxide film. Then, using this film as the
cathode, ultrasonic pulse electrochemical sealing is performed in a colloidal sealing solution containing an oxidant,
organic fuel, and a
boron source. Utilizing the
ultrasonic cavitation effect and the relaxation characteristics of the pulsed
electric field, directional deposition of colloidal particles deep within the micropores is achieved. Finally, gradient heat treatment completes low-temperature
drying, liquid-phase pre-melting, self-propagating reaction
initiation, and densification
sintering. This method optimizes
mass transfer and buffers thermal stress through a
boron-source molten liquid-phase medium. It utilizes an in-situ self-propagating
exothermic reaction to create localized high temperatures, promoting the transformation of the pore filler into a chemically
inert, dense
ceramic phase. This solves the problems of high-temperature
cracking in traditional hydrated sealing
layers and air pockets at the bottom of conventional physical filling pores, improving the high-
temperature resistance,
thermal shock resistance, and long-term
chemical corrosion resistance of high-strength aluminum
alloy sheets such as 6061 and 7075.