The invention relates to a treatment method for multi-crystalline silicon texturization etching waste liquid. The treatment method comprises the following steps: (a) under the stirring condition, adding an alkali metal compound in the waste liquid for reaction till precipitates are not generated any more, and filtering to obtain a first precipitate and first filtrate; (b) under the stirring condition, adding an alkaline earth metal compound in the first filtrate for reaction till precipitates are not generated, and filtering to obtain a second precipitate and second filtrate; (c) conducting condensation crystallization on the second filtrate to obtain a nitrate solid. The treatment method has the advantages that the alkali metal compound is added in the waste liquid for reaction till the precipitates are not generated any more, filtering is conducted, the alkaline earth metal compound is added in the another filtrate, filtering is conducted again, and finally, concentration is conducted, so that fluosilicic acid radical ions and fluorinions in the waste liquid can be removed, a fluosilicate solid, a fluoride salt solid and the nitrate solid can be obtained, and not only can the environment be protected, but also new economic benefits can be generated.