42results about "Magnesium compounds" patented technology

The present invention provides a pre-sodium treated positive electrode material for copper-zinc-based sodium ion battery and method of preparing the same. The method comprises obtaining a mixed solution containing copper-zinc-based elements through wet pre-sodium first, then conducting spray drying of the mixed solution containing copper-zinc-based elements to obtain precursor powder of positive electrode material for copper-zinc-based sodium ion battery, and then mixing the precursor powder with a sodium source for sintering, coating and crushing to obtain positive electrode material for copper-zinc-based sodium ion battery. The pre-sodium treated positive electrode material for copper-zinc-based sodium ion battery provided by the present invention introduces weakly oxidizing zinc and nickel elements on the basis of the copper-based material, reducing the use of highly oxidizing copper and iron elements. After being prepared into a battery, the oxidation of metal ions in the electrochemical environment is reduced overall, greatly reducing the oxidation of copper ions to the electrolyte, reducing the CO2 gas generated by oxidation and decomposition of the electrolyte, stabilizing the electrochemical environment, and improving the electrical performance of the battery.

A method for the processing a mixed particulate evaporite minerals with particles of size at least 0.25 mm where the minerals comprise a first evaporite with a first metal contaminant and a second eva

This application discloses hexafluorophosphate, phosphorus pentafluoride, and its preparation method and use. This application does not use phosphorus pentafluoride as raw material to prepare hexafluorophosphate, and does not use hydrogen fluoride as raw material to produce phosphorus pentafluoride, reducing the safety risk of production, and uses chemical reagents such as diphosphorus pentaoxide and sulfur trioxide, which have a wide supply source, as raw materials, reducing raw material costs and favoring industrial large-scale production. [Means] The method for preparing the hexafluorophosphate comprises mixing a phosphoric acid solution of diphosphorus pentoxide with sulfur trioxide and a fluoride in an inert gas atmosphere, and after the reaction, sequentially carrying out evaporation concentration, dissolution, filtration and drying to obtain the hexafluorophosphate. The method for preparing the phosphorus pentafluoride using the hexafluorophosphate obtained by the preparation method of the present application comprises mixing the hexafluorophosphate with a catalyst solution, and after the catalytic reaction, sequentially carrying out condensation, pressurization liquefaction and removal of impurities by adsorption to obtain the phosphorus pentafluoride.

The present invention provides a negative electrode material comprising a Mg(O) / C composite, which is a carbide of Mg-MOF-74 (magnesium-based metal-organic framework-74), wherein O is present or absent, a negative electrode comprising the negative electrode material, a lithium-ion secondary battery comprising the negative electrode, and a method for producing the Mg(O) / C composite.

The application discloses a sodium-ion layered positive electrode material, a preparation method and a positive electrode sheet. + , H + , F ‑ of a lithium-ion battery core recovery liquid; a sodium source and the lithium-ion battery core recovery liquid are prepared into a solution; (2) a sodium-ion layered positive electrode material is mixed into the solution to prepare a mixed slurry; (3) the mixed slurry is subjected to suction filtration and drying to obtain a precursor powder; and (4) the precursor powder is sintered to obtain the sodium-ion layered positive electrode material. The application overcomes the defects of poor cycle performance and unstable surface of the sodium-ion layered positive electrode material.

A cathode composition for a battery has the general formula Mg1+xMn1-xO2; wherein the value of x is greater than 0 and less than 1. Preferably, x ≤ 0.3, and most preferably the composition comprises M

This invention relates to a method for the processing of evaporite minerals, in particular for the manufacture of potash (KCl). Mixed evaporite minerals containing first and second metal contaminants are subjected to selective dissolution / decomposition, thereby facilitating the separation of the metal contaminants into separate by-product streams. The invention further provides a method for the processing of the separate by-product streams to obtain useful products based on each of the first and second metal contaminants.

A system for the synthesis of magnetoelectronically tunable spinel ferrite nanoparticles, comprising: a) a precursor preparation unit for the preparation of a homogeneous nitrate precursor solution, wherein the precursor preparation unit facilitates the dissolution of stoichiometric amounts of magnesium nitrate hexahydrate, nickel nitrate hexahydrate, iron(III) nitrate nonahydrate and chromium(III) nitrate nonahydrate in deionized water; b) a fuel mixing unit configured to introduce a binary mixture of urea and glucose into the dissolved homogeneous nitrate solution in a fuel-oxidant ratio that achieves fuel equivalence; c) a gel formation unit configured to maintain the temperature at 70-80 °C under continuous stirring to convert the fuel mixture into a viscous gel; d) a combustion unit comprising a preheated muffle furnace maintained at 450 ± 10 °C and enabling the initiation of a self-propagating combustion reaction; and e) a calcination plant configured for the thermal treatment of crushed precursor ash at 600 °C for 2 hours and subsequently at 750 °C for 2 hours to produce phase-pure cubic spinel Mg 1-x Ni x To produce FeCrO4 nanoparticles.

A structure (1) comprises a base material (10) that contains a continuous phase (11) of a polycrystalline body of a complex fluoride containing an alkali metal. The structure (1) contains at least 85 mass% of an inorganic substance, and the structure (1) contains at least 50 mass% polycrystalline body of a complex fluoride. The porosity of the structure (1) is 30% or less, the median value of the pore diameter of the structure (1) is 500 nm or less, and the thickness of the structure (1) is 10 μm or thicker.

To provide a manufacturing method of a positive electrode active material of a lithium ion secondary battery.SOLUTION: A method for manufacturing a positive electrode active material includes a first step of placing a first container containing a mixture of a lithium oxide, a fluoride, and a magnesium compound in a heating furnace, a second step of making the inside of the heating furnace an atmosphere containing oxygen, and a third step of heating the inside of the heating furnace, in which the third step is performed after the first step and the second step are performed. Before the inside of the heating furnace is heated, the atmosphere in the heating furnace is preferably made to contain oxygen. More preferably, the fluoride is lithium fluoride and the magnesium compound is magnesium fluoride.SELECTED DRAWING: Figure 1

To provide a pre-sodium treated positive electrode material for a copper-zinc-based sodium ion battery and a method of preparing the same.SOLUTION: A method includes: obtaining a mixed solution containing copper-zinc-based elements through wet pre-sodium treatment; then conducting spray drying of the mixed solution containing copper-zinc-based elements to obtain precursor powder of a positive electrode material for a copper-zinc-based sodium ion battery; and then mixing the precursor powder with a sodium source for sintering, coating and crushing to obtain a positive electrode material for a copper-zinc-based sodium ion battery. A positive electrode material for a battery of the present invention introduces weakly oxidizing zinc and nickel elements based on a copper-based material, and reduces the use of highly oxidizing copper and iron elements. After the material is prepared into a battery, the oxidation of metal ions in an electrochemical environment is reduced overall, so that the oxidation of copper ions to an electrolyte is greatly reduced, CO2 gas generated by oxidation and decomposition of the electrolyte is reduced, the electrochemical environment is stabilized, and the electrical performance of the battery is improved.SELECTED DRAWING: Figure 1

The present invention discloses a highly selective magnesium-lithium separation nanofiltration membrane based on a polyolefin-based membrane, its preparation method and application. The preparation method is as follows: The polyolefin substrate membrane is brought into single-sided contact with an organic phase monomer solution containing isophthaloyl chloride or terephthaloyl chloride monomers. The excess solution is poured out. The side of the obtained membrane that has been in contact with the organic phase monomer solution is then brought into contact with an aqueous phase monomer solution containing polyethyleneimine, and an interfacial polymerization reaction occurs. The obtained membrane is placed in an oven for heat treatment, and then the membrane is soaked in an organic solution for activation, thus obtaining a polyvinyl composite nanofiltration membrane. The nanofiltration membrane of the present invention has high magnesium ion retention and high magnesium-lithium separation selectivity in a mixed solution with a high magnesium-lithium ratio. The preparation process is simple, the conditions are mild, it is easy to scale up and realize industrial production, and it has good long-term operation stability.

To create a fire protection material with improved cooling properties, easier handling and processing, and more cost-effective production, magnesium phosphate hydrate, such as magnesium phosphate octahydrate, is used as an ablative fire protection material (20) or in an ablative fire protection material (20) for fire protection purposes according to the invention. In one embodiment, a composition for forming an ablative fire protection material (20) containing 55 wt% to 80 wt% magnesium phosphate hydrate (12), 20 wt.% to 40 wt.% carrier material (10), and 1 wt.% to 20 wt.% of a crust-forming material (14). in an extruder (16) to form a flexible strand of ablative fire protection material (20), in particular to form a flexible sheet (22).

Provided are a method for producing porous magnesium having a simple solution process of adding a magnesium precursor to a reductant solution and reacting, porous magnesium produced by the method, and hydrogen storage material containing hydrogen supported in the porous magnesium.

The application belongs to the field of water treatment equipment and application technology, and particularly relates to a selective electrodialysis device and application thereof. The selective electrodialysis device comprises an electrodialysis cell, an anode and a cathode arranged on the two sides of the electrodialysis cell, and a cation exchange membrane and an anion exchange membrane arranged between the anode and the cathode in sequence. The cation exchange membrane is made of sulfonated polybenzimidazole as a base material, and the surface of the cation exchange membrane is coated with polystyrene sodium sulfonate containing porous micro-nano materials. A protective layer containing polydiphenylpiperidine is coated on the side of the cation exchange membrane facing the anode. The anion exchange membrane is made of quaternary amine polyfluorosulfone or polyether sulfone as a base material, and the surface of the anion exchange membrane is coated with polydimethyl diallyl ammonium chloride. The device can efficiently separate monovalent ions and polyvalent ions, the functionalization of the ion exchange membrane increases the membrane charge density, promotes the rapid migration of ions under the action of an electric field, and improves the ion transfer rate. The device is stable in operation, has a high separation rate and a high current efficiency.

Provided is a structure (1), including: a base material (10) that includes a continuous phase (11) of a polycrystalline substance of a complex fluoride including an alkali metal, wherein the structure (1) includes an inorganic substance in an amount of 85% by mass or more, the structure (1) includes the polycrystalline substance of the complex fluoride in an amount of 50% by mass or more, the structure (1) has a porosity of 30% or less, the structure (1) has a median pore size of 500 nm or less, and the structure has a thickness of 10 µm or more.

To provide a method for manufacturing a positive electrode active material of a lithium ion secondary battery.SOLUTION: A method for manufacturing a positive electrode active material includes: a first step of placing in a heating furnace, a first container in which a mixture of a lithium oxide, a fluoride and a magnesium compound is put; a second step of bringing the inside of the heating furnace into an oxygen containing atmosphere; and a third step of heating the inside of the heating furnace. The first step and the second step are executed and then, the third step is executed. It is preferable that the inside of the heating furnace is brought into the oxygen containing atmosphere before heating the inside of the heating furnace. It is more preferable that the fluoride is lithium fluoride and the magnesium compound is magnesium fluoride.SELECTED DRAWING: Figure 1

This apparatus for producing complex fluoride particles comprises: a mixer for mixing a first solution in which a first compound that is an alkali metal fluoride is dissolved, a second solution in which a second compound having a metal element different from the alkali metal element contained in the alkali metal fluoride is dissolved, and a third solution in which a third compound that reacts with hydroxide ions to produce water is dissolved, thereby producing a mixed solution containing the complex fluoride particles; a pH detection unit for measuring the pH value of the mixed solution, which changes as water is produced; and an estimation unit for estimating the particle size of the complex fluoride particles according to the pH value.

A method for forming a positive electrode active material of a lithium ion secondary battery is provided. The method for forming a positive electrode active material includes a first step of placing a first container in which a mixture of a lithium oxide, a fluoride, and a magnesium compound are put, in a heating furnace, a second step of providing an atmosphere including oxygen in an inside of the heating furnace, and a third step of heating the inside of the heating furnace. The third step is performed after the first step and the second step are performed. Preferably, an atmosphere including oxygen is provided in the heating furnace before the inside of the heating furnace is heated. More preferably, the fluoride is lithium fluoride and the magnesium compound is magnesium fluoride.

To provide a method for manufacturing a positive electrode active material of a lithium ion secondary battery.SOLUTION: A method for manufacturing a positive electrode active material includes: a first step of placing in a heating furnace, a first container in which a mixture of a lithium oxide, a fluoride and a magnesium compound is put; a second step of bringing the inside of the heating furnace into an oxygen containing atmosphere; and a third step of heating the inside of the heating furnace. The first step and the second step are executed and then, the third step is executed. It is preferable that the inside of the heating furnace is brought into the oxygen containing atmosphere before heating the inside of the heating furnace. It is more preferable that the fluoride is lithium fluoride and the magnesium compound is magnesium fluoride.SELECTED DRAWING: Figure 1

A positive electrode active material comprises secondary particles, wherein each of the secondary particles includes primary particles, and each of the primary particles includes an olivine-type phosphate compound and lithium zirconate.

A pre-sodium treated positive electrode material for copper-zinc-based sodium ion battery and method of preparing the same are provided. The method includes the steps of obtaining a mixed solution containing copper-zinc-based elements through wet pre-sodium first, then conducting spray drying of the mixed solution containing copper-zinc-based elements to obtain precursor powder of positive electrode material for copper-zinc-based sodium ion battery, and then mixing the precursor powder with a sodium source for sintering, coating and crushing to obtain positive electrode material for copper-zinc-based sodium ion battery. The pre-sodium treated positive electrode material for copper-zinc-based sodium ion battery thus prepared introduces weakly oxidizing zinc and nickel elements on the basis of the copper-based material, reducing the use of highly oxidizing copper and iron elements. After being prepared into a battery, the oxidation of metal ions in the electrochemical environment is reduced overall.

The invention belongs to the technical field of nanofiltration membranes, and particularly relates to a high-performance phospholipid interlayer lithium-magnesium separation membrane as well as a preparation method and application thereof. The high-performance phospholipid interlayer lithium-magnesium separation membrane is prepared according to the following method: taking a polyethersulfone ultrafiltration membrane as a substrate, introducing a phospholipid interlayer, then performing interfacial polymerization through polyethyleneimine and trimesoyl chloride to form a polyamide separation layer, and finally performing heat treatment to obtain the high-performance phospholipid interlayer lithium-magnesium separation membrane. The phospholipid middle layer is a positively charged phospholipid double-layer membrane formed by spreading phospholipid vesicles on the surface of the polyethersulfone supporting layer. The phospholipid in the phospholipid vesicles is one of dioleoyl phosphatidylcholine, dioleoyl phosphatidyl ethanolamine and 1, 2-dioleoyl-3-trimethylamine propane hydrochloride. The transmittance of the lithium-magnesium separation membrane with the phospholipid interlayer is higher than 11L. M <-2 >. H <-1 >. Bar <-1 >, and the separation factor is greater than or equal to 29.5.

Provided is a structure (1), including: a base material (10) that includes a continuous phase (11) of a polycrystalline substance of a complex fluoride including an alkali metal, wherein the structure (1) includes an inorganic substance in an amount of 85% by mass or more, the structure (1) includes the polycrystalline substance of the complex fluoride in an amount of 50% by mass or more, the structure (1) has a porosity of 30% or less, the structure (1) has a median pore size of 500 nm or less, and the structure has a thickness of 10 µm or more.

The invention discloses a method for recycling magnesium in a rare earth element leaching process, which comprises the following steps of: 1) mixing and leaching minerals after the rare earth ores are subjected to sulfation decomposition with water to obtain primary leachate and primary leaching residues; (2) mixing the primary leachate with a magnesium neutralizer, and carrying out neutralization reaction to obtain primary purified liquid and neutralized slag; 3) adding a magnesium precipitant into the primary purified liquid, and carrying out precipitation reaction to obtain a primary magnesium sulfate solution and a rare earth precipitate; (4) the primary magnesium sulfate solution and the primary leaching residues are leached, and secondary leaching liquid and secondary leaching residues are obtained; and (5) returning the secondary leaching solution to the step (2) to serve as the primary leaching solution in the step (2), and repeating the steps (2)-(3) to obtain a secondary magnesium sulfate solution, rare earth precipitates and neutralization residues. According to the method, cyclic utilization of the magnesium element is achieved, and the leaching rate of rare earth elements is increased while transformation wastewater discharge is reduced.

The present invention discloses a positively charged nanofiltration membrane based on a quaternized monomer and a preparation method and application thereof, belonging to the technical field of nanofiltration membrane preparation and ion separation. The method comprises the following steps: providing a quaternized 1,4-diazabicyclo[2.2.2]octane dissolved in water to obtain an aqueous phase monomer solution; and an organic phase monomer solution containing trimesoyl chloride and n-hexane; immersing a porous base nanofiltration membrane in the aqueous phase monomer solution, taking out and removing the residual solution on the membrane surface, immersing it in the organic phase monomer solution to undergo interfacial polymerization to form a polyamide layer, then heat-treating it, and cooling it to obtain the positively charged nanofiltration membrane. The present invention can effectively regulate the thickness of the polyamide layer of the nanofiltration membrane according to the monomer concentration and the condensation time, and prepare a positively charged nanofiltration membrane, which can improve water flux and lithium / magnesium selectivity.

The present invention relates to poly(melamine-silicate) derivatives as biocidal disinfection and decontamination agents, and to methods for their production and use. More specifically, the invention relates to halogenated adducts of poly(melamine- silicate) with metal oxides.

The present invention belongs to the field of resource recycling technology and discloses a process for simultaneously processing lithium-ion battery electrode powder and nickel-cobalt intermediates. The process comprises the following steps: leaching the electrode powder to obtain leachate I and leachate residue I; removing copper, iron, aluminum, calcium, and magnesium from leachate I to obtain calcium-magnesium slag and a solution after the removal of calcium and magnesium; leaching the nickel-cobalt intermediate to obtain leachate II and leachate residue II; removing iron and aluminum from leachate II and then extracting and removing zinc to obtain raffinate II; using raffinate II to leach the calcium-magnesium slag to obtain leachate III and leachate residue III; treating the leached residue III with sulfuric acid and roasting to obtain calcium-magnesium sulfate and tail gas HF; absorbing the tail gas HF with liquid caustic soda, and returning the evaporated and concentrated product to the step of removing calcium and magnesium. The present invention transforms F into valuables, realizing the resource utilization of F without the need to treat F-containing wastewater; and achieving the enrichment of valuable metals in lithium-ion battery electrode powder and nickel-cobalt intermediates, as well as the effective integration of process flows, which is beneficial to the extraction of valuable metals and can eliminate the need for a concentration process.

To create a fire protection material with improved cooling properties, easier handling and processing, and more cost-effective production, magnesium phosphate hydrate, such as magnesium phosphate octahydrate, is used as an ablative fire protection material (20) or in an ablative fire protection material (20) for fire protection purposes according to the invention. In one embodiment, a composition for forming an ablative fire protection material (20) containing 50 wt% to 80 wt% magnesium phosphate hydrate (12), 20 wt.% to 40 wt.% carrier material (10), and 1 wt.% to 20 wt.% of a crust-forming material (14) is extruded in an extruder (16) to a flexible strand of ablative fire protection material (20), in particular to a flexible sheet (22).

The invention discloses preparation and application of an anionic covalent organic framework film material, and belongs to the field of preparation of environment-friendly separation materials. Comprising the following steps: 1, soaking an AAO support body in deionized water for 1 hour at room temperature; 2, taking out the soaked AAO support body, and airing; 3, accurately weighing two construction monomers, namely 2, 5-diaminobenzene sulfonic acid and 2, 4, 6-trihydroxy-1, 3, 5-benzenetricarboxaldehyde, adding a mixed solvent, namely dimethyl sulfoxide and N-methyl pyrrolidone, and carrying out ultrasonic treatment for 15 minutes, so that the two monomer powders are completely dissolved to form a homogeneous solution; 4, placing an AAO substrate at the bottom of the reaction solution, and carrying out a hydrothermal reaction; 5, fishing out the AAO substrate to obtain a COF film with complete morphology; 6, acetone and absolute ethyl alcohol are sequentially used for washing, standing is conducted at the room temperature, and the TpPa-SO3H / AAO nano-porous membrane is obtained. The thin film material provided by the invention has high crystallinity and good stability, and shows efficient metal ion selectivity, and the separation factor of Li < + > / Mg < 2 + > is as high as 15 in a two-component mixed system of LiCl and MgCl2.