130 results about "Chromium nitrate" patented technology

The invention discloses an afterglow nanomaterial and a preparation method of a long-afterglow nanomaterial with sizes and spectrum adjusted on basis of ion doping. An expression formula of the nanomaterial is Zn(1+x)Ga(2-2x)GexO4:0.75%Cr, wherein x is larger than or equal to 0 and smaller than or equal to 0.5, and the particle size is 7 nm-80 nm. According to the preparation method, a zinc nitrate solution, a gallium nitrate solution, a sodium germinate solution and a chromium nitrate solution in specific proportions are mixed together, ammonia water is added rapidly while the mixture is stirred, and the pH of the mixed solution is adjusted to 10; then, the mixed solution is transferred to a high-temperature hydrothermal kettle and reacts at the temperature of 120 DEG C, and the afterglow nanomaterial is obtained. The method is simple and easy to implement, severe experiment conditions and complicated large instruments are not required, synthesized nanoparticles are uniform in sizes and have a good water-phase dispersion property and high afterglow strength, the afterglow time can reach 10 h, and accordingly, the synthesized nanoparticles are suitable for improving the physical and chemical properties of the long-afterglow nanomaterial.

The invention discloses a catalyst for synthesizing methanol by direct hydrogenation of carbon dioxide and a preparation method thereof and relates to the catalyst. The invention provides the catalyst for synthesizing the methanol by direct hydrogenation of the carbon dioxide and the preparation method thereof. The catalyst is LaCr1-xCuxO3, wherein x is the relative mole fraction of a main component of Cu, x is equal to 0.1-0.9, and La: Cr: Cu is equal to 1: (1-x): x. The preparation method comprises the steps of preparing copper nitrate, chromium nitrate, lanthanum nitrate and citric acid into water solution, forming a sol under the radiation of an infrared lamp, heating, decomposing nitrogen oxides and organic acids, pre-baking in an atmosphere furnace at the temperature of 350-450 DEG C for 2-4h, baking at the temperature of 700-800 DEG C, and obtaining the catalyst for synthesizing the methanol by direction hydrogenation of the carbon dioxide. The citric acid complexation-rapid combustion method is adopted for overcoming the disadvantages of lower conversion rate, poorer selectivity of the methanol and the like during the catalysis of the carbon dioxide by using the existing catalyst for synthesizing the methanol by hydrogenation of the carbon dioxide, and the prepared catalyst has stable performances.

The invention discloses a metal organic skeleton-graphite oxide nano composite adsorption material and a preparing method thereof. The material is composed of graphite oxide and chromium-based metal organic skeleton. The preparing method of the material comprises the following steps of: dissolving chromium nitrate and terephthalic acid in deionized water, stirring and simultaneously adding hydrofluoric acid dropwise, then adding graphite oxide and uniformly stirring to obtain reaction liquid, and conducting hydro-thermal reaction under program temperature controlling; and after sequentially conducting washing with water and washing with ethanol for the decomposed materials, centrifuging, drying and obtaining the metal organic skeleton-graphite oxide nano composite adsorption material. Theadsorption capacity of the adsorption material for hydrocarbon volatile organic matters is greatly increased, and the adsorption material is easy for desorption and regeneration. The preparing methodhas simple process and low cost.

The invention discloses a preparation method of a hydrophobic MIL-101 chromium organometallic skeleton material. The method comprises the following steps: dissolving chromium nitrate and 1,4-naphthalenedicarboxylic acid in water, adding hydrofluoric acid and acetic acid to stir evenly, performing a hydrothermal reaction at 210-220 DEG C, washing the obtained product with deionized water, dimethylformamide and ethanol in turn, centrifuging, filtering, and drying to prepare the hydrophobic MIL-101 chromium organometallic skeleton material. The hydrophobic MIL-101 chromium organometallic skeleton material has high Langmuir surface area and also has the high specific surface area and micro-mesoporous skeleton of a traditional MIL-101 material; and as a benzene ring is grafted on the organic connector in the skeleton, the material has higher hydrophobicity and the adsorption capacity of the material to nonpolar organic volatile substances can be increased.

The invention provides a six-element high-entropy oxide material for a lithium ion battery and a preparation method, and relates to the technical field of entropy oxide materials. The chemical formulaof the six-element high-entropy oxide powder material is (AlxCoCrFeMnNi)3O4, wherein the value of x ranges between 0.2 and 1. Raw materials comprise aluminum nitrate, cobalt nitrate, chromium nitrate, ferric nitrate, manganese nitrate and nickel nitrate, wherein the molar ratio of aluminum nitrate to the sum of the rest nitrates is (0.2-1):1. The preparation method comprises the steps of dissolving the nitrates, adding a proper amount of fuel, uniformly mixing, and carrying out low-temperature combustion to obtain the six-element spinel type high-specific-surface-area (AlxCoCrFeMnNi)3O4 high-entropy oxide nano-powder material. The six-element high-specific-surface-area (AlxCoCrFeMnNi)3O4 high-entropy oxide nano-powder prepared according to the method is used as a lithium ion battery negative electrode material, has relatively high specific capacity, excellent cycle characteristic, and is simple in preparation method and low in cost.

Disclosed is an aqueous solution of a chromium salt, in which the oxalic acid content is 8% by weight or less relative to chromium. In the aqueous solution of the chromium salt, the total organic carbon content is 4% by weight or less relative to chromium. The chromium salt is preferably a chromium chloride, a chromium phosphate, or a chromium nitrate. The chromium chloride preferably contains a basic chromium chloride represented by the composition formula Cr(OH)_xCl_y (wherein 0<x≦2, 1≦y<3, and x+y=3). The chromium phosphate is preferably one represented by the composition formula Cr(H_3−3/nPO₄)_n (wherein n is a number satisfying 2≦n≦3). The chromium nitrate is preferably a basic chromium nitrate represented by the composition formula Cr(OH)_x(NO₃)_y (wherein 0<x≦2, 1≦y<3, and x+y=3).

The invention discloses perovskite-type substance La<1-x>SrCrO<3>, a heat-engine plant denitration composite catalyst, and preparation methods of the perovskite-type substance La<1-x>SrCrO<3> and the heat-engine plant denitration composite catalyst, and belongs to the technical field of flue gas denitrification catalyst. The preparation method of the perovskite-type substance La<1-x>SrCrO<3> is used for solving a problem that existing preparation method of the perovskite-type substance is complex. According to the preparation method of the perovskite-type substance La<1-x>SrCrO<3>, lanthanum nitrate, strontium nitrate, and chromium nitrate are taken as raw material precursors, and are dissolved in water, and then are subjected to high-temperature roasting so as to obtain finished products. The preparation methods of the heat-engine plant denitration composite catalyst is used for solving a problem of existing denitration catalyst that ammonia is released in denitration processes. According to the preparation methods of the heat-engine plant denitration composite catalyst, a titanium dioxide mixture, an active liquid, water, glycerin, ethylene glycol, glass fiber, and aluminium dihydrogen phosphate are subjected to kneading so as to obtain ceramic clay; the ceramic clay is subjected to vacuum extrusion so as to obtain honeycomb ceramic blank; and the honeycomb ceramic blank is subjected to steam drying and roasting so as to obtain products. The heat-engine plant denitration composite catalyst is high in denitration rate, and is capable of solving a problem of ammonia escaping.

The invention discloses a method for improving the electrochemical performance of a positive material LiNi0.5Mn1.5O4 of a lithium ion battery, and belongs to the field of the positive material of the lithium ion battery. The method reduces the using amount of Cr<3+> for improving the electrochemical performance of LiNi0.5Mn1.5O4 by a conventional bulk phase doping method, reduces the environmental pollution and the human health hazard caused thereby and eliminates the hidden trouble of striping of a covering layer existing in a covering modification method. The method comprises the following steps of: dissolving chromium nitrate in aqueous solution of ethanol; adding LiNi0.5Mn1.5O4 into the solution and dispersing and stirring the mixture until the liquid phase is eliminated; and calcining the mixture and naturally cooling the mixture to obtain the positive material LiNi0.5Mn1.5O4 of the lithium ion battery with high electrochemical performance. The method improves the electrochemical performance of the positive material LiNi0.5Mn1.5O4 of the lithium ion battery, reduces the using amount of the chromium salt, ensures no obvious boundary between the doped Cr<3+> layer and the body of the positive material, reduces the environmental pollution, and also reduces the hazard to the human health.

Disclosed is a method for chemical conversion treatment of the surface of an aluminum material comprising aluminum or an aluminum alloy. The method comprises performing a chemical conversion treatment of the surface of the aluminum material with a treatment solution for 1 to 5 minutes to form a coating film having excellent corrosion resistance and coating film adhesion property, wherein the treatment solution contains a trivalent chromium, and has a chromium nitrate content of 3 to 12 g/L in terms of Cr(NO3)3, a ammonium vanadate content of 0.5 to 7 g/L in terms of NH4VO3, a potassium fluorotitanate content of 0.5 to 3 g/L in terms of K2TiF6, a lithium fluoride content of 0.5 to 3 g/L in terms of LiF, a nitric acid content of 0.5 to 1.8 mL/L in terms of HNO3, and a liquid temperature of 40 to 50 C. Also disclosed is an aluminum material having a coating film formed by the method.

The invention aims to provide a loaded catalyst for propane dehydrogenation to propylene and a preparation method thereof. The catalyst consists of a Cr2O3 active component and a carrier material withhigh temperature sintering resistance, phase change resistance and high specific surface at high temperature. The chemical formula of the catalyst is yCr2O3/MaOb.xAl2O3, y=10-30%, a=1-3, b=1-4; x=4-8, and the carrier material is metal doped aluminum oxide salt MaOb.xAl2O3. Precipitation technique, complexing technique, sol-gel technique or reverse micro-emulsion technique is employed to prepare the carrier material MaOb.xAl2O3 with high temperature sintering resistance, phase change resistance and high specific surface; impregnation process and solid phase ball mill mixing technique are adopted to prepare the yCr2O3/MaOb.xAl2O3 loaded catalyst, y=10-30%, and the Cr2O3 active component precursor material adopts chromium nitrate, chromium acetate, chromium citrate, chromium acetylacetonateand other chromium-containing precursors. The synthesized loaded catalyst shows good catalytic activity in the reaction of direct dehydrogenation of alkane to prepare propylene, especially shows excellent sintering and phase change resistance, thus greatly improving the stability and service life of the catalyst.

A preparation method of nano tungsten powder comprises the following steps: (1) dissolving ammonium metatungstate, chromium nitrate and a water-soluble carbon source substance into in heated deionized water, electrically stirring to sufficiently mix raw materials, and after uniformly mixing the raw materials, performing spray drying to obtain precursor powder, wherein the weight percentage of the water-soluble carbon source substance is 10-30%, the weight percentage of the chromium nitrate is 0.5-2% and the temperature of the deionized water is 70 DEG C; and (2) putting the precursor powder obtained in the step (1) into a tubular atmosphere furnace, performing auxiliary hydrogen reduction, and before discharging the powder out of a furnace, passivating the powder with an inert gas, wherein the temperature is 710-850 DEG C, the heating rate is 10-15 DEG C/ min and the reaction time is 2-5h. The particle size of the prepared tungsten carbide is 40-70nm; after the prepared tungsten carbide is crushed, agglomeration-free nano tungsten powder can be obtained; the environment is polluted; and the development of a nanocrystalline WC-Co hard alloy can be effectively promoted.

The invention discloses preparation and application of a CdS-PAMAM nanocomposite in detecting Cu2+, and belongs to the technical field of composites and ion detection.A polyamidoamine (PAMAM) dendrimer is used as a template, CdS is used a light emitting center (chromic nitrate and sodium sulfide are ion sources for synthesizing CdS), and the molecule CdS-PAMAM nanocomposite of a tree structure is synthesized in situ.According to selective testing of the CdS-PAMAM nanocomposite for metal ions, the result proves that the only the addition of copper ions has the remarkable effect on the fluorescence intensity of the composite (fluorescence of the composite is quenched and reduced from 1678 to 957), and the addition of other metal ions will not greatly change fluorescence of the composite.Accordingly, the CdS-PAMAM nanocomposite can be used for copper ions in the specific selectivity fluorescence detection environment.

The invention relates to a cleaning agent, especially to a kitchen ventilator cleaning agent capable of highly-efficiently decontaminating. The agent is prepared by the following raw materials by weight parts: polyvinyl alcohol, ethylene glycol monomethyl ether, sodium dodecyl benzene sulfonate, urotropine, chromium nitrate, polyethylene glycol, lemon flavor and water with a ratio of 5 to 15 : 10 to 20 : 10 to 30 : 0.5 to 1.5 : 0.03 to 0.1 : 0.01 to 0.08 : 0.01 to 0.1 : 150 to 220. The kitchen ventilator cleaning agent capable of highly-efficiently decontaminating is environmentally-friendly, non-toxic, tasteless, non-stimulating, non-flammable and harmless to the human body and skin, does not damage galvanized coating and paint on surfaces of electric appliances, and can rapidly decompose difficult-to-remove grease and dirt attached to the surfaces of the electric appliances without dismounting the kitchen ventilator; and thus the stubborn oil stain can be easily removes and an effect of shininess as new can be achieved.

The invention discloses a 1-phenethylthiourea modified Cr-Anderson heteropolyacid catalyst, and a preparation method and an application thereof The preparation method comprises the following steps: reacting ammonium molybdate with chromium nitrate to generate a Cr-Anderson heteropolyacid (NH4)3[Cr(OH)6Mo6O18], carrying out a hydrothermal reaction on the Cr-Anderson heteropolyacid (NH4)3[Cr(OH)6Mo6O18] and trihydroxyaminomethane in a hydrothermal kettle to obtain organic one-sided amino group-modified polyoxometallate; synthesizing 1-phenethylisothiocyanic acid; and reacting the organic one-sided amino group-modified polyoxometallate with 1-phenethylisothiocyanic acid to obtain the 1-phenethylthiourea modified Cr-Anderson heteropolyacid catalyst. The preparation method has the advantages of simplicity and environmental protection. The catalyst obtained in the invention can be used in asymmetric dihydroxylation reactions of olefins, and has the advantages of high catalysis activity, recycling realization, and suitableness for industrial production.

The invention relates to a catalyst and a preparation method thereof. The preparation method comprises the following steps of: weighing 1kg of carrier active carbon; removing impurities and dust in clear water; weighing 70g of ferric nitrate, 60g of nickel nitrate, 30g of manganous nitrate, 10g of potassium nitrate, 30g of sodium metavanadate, 30g of cobalt nitrate, 60g of cerous nitrate, 80g of ammonium molybdate, 20g of chromium nitrate, 0.5g of platinum and 0.5g of aurum and mixing and dissolving; then charging the cleaned active carbon into a prepared solution and soaking for 48 hours; fully adsorbing metal salt by the active carbon; after completely soaking, drying in the sun; after drying in the sun, charging the metal salt into an oven for curing at high temperature; after curing, discharging and naturally cooling; and then screening and packaging a finished product for storage. The invention has the advantage of effectively removing heavy metal ions and organic matter enriched in sewage treatment.

The invention provides a preparation method of a CeO2-Cr2O3-Nb2O5 compound oxide catalyst. Chromium nitrate, cerous nitrate and acidic Nb2O5 oxide or niobium oxalate ammonia serve as raw materials, the CeO2-Cr2O3-Nb2O5 compound oxide catalyst is prepared through a precipitation-deposition or co-precipitation method, the molecular ratio of Ce to Cr in the catalyst is 4:1, and the mass ratio of (Cr2O3 + CeO2) to Nb2O5 is 4:1-1:9. The catalyst is simple in preparation technology and low in cost and has good catalytic degradation activity and stability on dichloromethane (DCM), ethylene dichloride (DCE), trichloroethylene (TCE), chlorobenzene and other chlorine-containing organic compounds, CO2 and HCl are high in selectivity, and no polychlorocarbon or other by-products are generated.

The invention discloses a perovskite substance, a thermal power plant denitration compound catalyst and preparation methods thereof and belongs to the technical field of flue gas denitration catalysts. In order to solve the problem that existing perovskite substance preparation processes are complex, the invention provides the preparation method of the perovskite substance. The preparation method of the perovskite substance includes: dissolving lanthanum nitrate, strontium nitrate and chromium nitrate as raw material precursors in water; calcining at high temperature to obtain the perovskite substance. In order to solve the problem that existing denitration catalysts cause ammonia escape during nitration, the invention further provides the preparation method of the thermal power plant denitration compound catalyst. The preparation method of the thermal power plant denitration compound catalyst includes following steps: kneading titanium dioxide mixture, active liquid, water, glycerin, ethylene glycol, glass fiber and aluminum dihydrogen phosphate to obtain ceramic pug; performing vacuum extrusion to obtain a cellular ceramic blank; subjecting the cellular ceramic blank to steam drying and calcining to obtain the thermal power plant denitration compound catalyst. The catalyst is high in nitration efficiency, and the problem of ammonia escape is solved.

The invention belongs to a field of diesel-engined car tail gas cleaning and relates to a method for preparing a catalyst with optimized performance on metal alloy support for selectively reducing nitrogen oxide. The method includes preparing nickel nitrate solution, manganese nitrate solution, copper nitrate solution, cobalt nitrate solution, ferric nitrate solution, cerium nitrate solution and chromium nitrate solution with the distilled water as solvent; selecting 2-4 kinds of solutions from the solutions and mixing with silver nitrate solution or palladium nitrate of equivalent volume to prepare catalyst solution; dip-coating the catalyst solution on a glass ceramic coating of metal alloy support by; air-drying the coated metal carrier at room temperature; drying at 120-180 DEG C; repeating the coating and the drying for 5-8 times; and calcining at 600-1,000 DEG C for 1-5h to activate and mold. The method has the advantages of low cost, good initiation and catalytic characteristic effect.

The invention discloses a sol-gel preparation methd of CuCrO2 powder. The method comprises the following steps: preparing a mixed solution from copper nitrate and chromium nitrate with equal mole number; adding citric acid and ethylene glycol into the mixed solution, and stirring to form a colorless transparent solution; performing water-bath heating at 75-90 DEG C for 4-6h to form thick liquid; cooling to room temperature, adding an aqueous solution of ammonia into the thick liquid, transferring to water-bath at 75-90 DEG C for heating to obtain a thick matter; performing vacuum drying for 18-40h to obtain gray powder; transferring the gray powder into a tubular furnace, and roasting at 300-550 DEG C for 0.5-1.5h; cooling and grinding; roasting in a nitrogen atmosphere at 800-950 DEG C for 1-3h to obtain CuCrO2 powder. The CuCrO2 powder prepared by the method has the advantages of fine particles, high dispersity, high crystal integrity and relatively uniform particle size distribution.

The invention discloses a method for preparing a hydrophobic Cr-Ce-based catalyst through ultrasound-hydrogen reduction. The method comprises the following steps: 1, codissolving chromium nitrate and cerium nitrate in deionized water to prepare a mixed solution of chromium nitrate and cerium nitrate; 2, adding Al2O3 particles to the mixed solution, oscillating and carrying out ultrasonic dipping at a constant temperature, drying, and calcinating to obtain solid particles; and 3, carrying out reduction processing on the solid particles in hydrogen, and calcinating the solid particles in air toprepare the hydrophobic Cr-Ce-based catalyst. The catalyst prepared through the method of the invention is mainly used for catalyzing the combustion of volatile organic compounds containing chlorine,the method which allows noble metals to be replaced with transition metals allows the cost to be reduced and the high activity of the catalyst to be simultaneously maintained, and the catalyst can catalyze the combustion of the volatile organic compounds containing chlorine at a low temperature; and the catalyst which still has a high activity at a high extraneous humidity has a good practical application prospect.

The invention provides a method for regenerating activity of a deactivated ferritic catalyst. The ferritic catalyst is a catalyst for catalyzing 2,6-xylenol to produce polyphenylene oxide and comprises Fe2O3 and In2O3. The method comprises the following steps of: introducing air into a deactivated catalyst; sintering the catalyst at the temperature of between 450 and 500 DEG C to remove coked carbon in the catalyst; crushing; thermally dissolving the crushed catalyst with 10 to 63 percent of nitric acid or a mixed liquor of the nitric acid and hydrochloric acid at the temperature of between 60 and 150 DEG C; detecting the acidulated reactive fluid; calculating according to detection results; and correspondingly adding required chromium nitrate, sodium silicate and indium.

The invention discloses a passivation technology of an aluminum alloy cylinder cover. A passivation liquid used by the passivation technology comprises 4-6g/L of sodium silicate, 13-15g/L of titanium dioxide, 20-23g/L of nitric acid having a concentration of 68%, 15-17g/L of potassium permanganate, 3-5g/L of sodium peroxide, 6-8g/L of ammonium bifluoride, 22-24g/L of ferrous chloride, 5-9g/L of chromium nitrate, 3-5g/L of zirconium nitrate, 14-16g/L of sodium dodecylsulfate and the balance water. The passivation technology comprises the following steps of 1, carrying out alkali washing and carrying out cleaning by clear water, 2, carrying out pickling and carrying out cleaning by clear water, 3, preparing the passivation liquid from the above components, putting the passivation liquid into a passivation tank, diluting the passivation liquid by 4-6 times, controlling a temperature of the passivation liquid in a range of 35-45 DEG C and a pH value in a range of 3-5, putting a supersonic generator at the bottom of the passivation tank, carrying out passivation for 13-17min, then carrying out cleaning by water and carrying out natural drying.