164 results about "Calcium nitrite" patented technology

The invention relates to an admixture for high early strength of concrete, characterized in that the admixture is formed by mixing and stirring cement clinkers, industrial residues, early strength agents, plaster, water reducing agents and excitants. The parts by weight of the components are as follows: 100 parts of cement clinkers, 500-2000 parts of industrial residues, 0.2-3 parts of early strength agents, 1-3 parts of plaster, 0.2-2 parts of water reducing agents and 1-5 parts of excitants. The excitant is the mixture of aluminum hydroxide, calcium nitrite and calcium nitrate; wherein, the aluminum hydroxide accounts for 50% of the mixture while the calcium nitrite and the calcium nitrate are in any proportion; the early strength agent is the mixture of trolamine, lithium carbonate and calcium formate, wherein, the trolamine accounts for 50% of the mixture while the lithium carbonate and the calcium formate are in any proportion. The admixture for concrete provided by the invention has high activity index and low content of harmful ions. Adding the admixture can obviously improve the demoulding strength, long-term mechanical property and durability of the concrete.

The invention provides a red-emitting phosphor. The chemical structural formula of the phosphor material is Ca₃(VO₄)₂:Eu³⁺. A preparation method of the phosphor is that calcium nitrite, europium nitrate, and citric acid with the mole ratio of 94:6:167-233 are dissolved in deionized water and mixture solution is obtained. Then ammonium metavanadate with proper quantity is added into the mixture and is heated and stirred for a certain time to get viscogel. In the end the hot viscogel is grinded and the product is made. The invention uses a citric acid sol-gel combustion method to prepare the nano Ca₃(VO₄)₂:Eu³⁺ phosphor. The phosphor is uniform comparatively and has good chemical stability and luminescence with high efficiency. The cost is low. The preparation technology is simple and safe with low production temperature and can save energy.

The invention discloses an ultralow-temperature high-performance concrete for railway construction in severe cold regions and a preparation technique thereof. The concrete is prepared by evenly mixing cementing material, sand, gravel, high-efficiency water reducing agent, composite antifreezing agent and water, wherein the cementing material is prepared by evenly mixing cement and mineral admixture in a weight ratio of (15-20):(85-80); the water reducing rate of the high-efficiency water reducing agent is not less than 25%; the composite antifreezing agent comprises 30-35 wt% of nitrate, 30-33 wt% of organic compound, 0.5-1 wt% of calcium formate and the balance of water; the nitrate is calcium nitrate or calcium nitrite; and the organic compound is methanol or ethanol. The preparation technique comprises the following steps: 1. preparing the composite antifreezing agent; and 2. evenly mixing to obtain the ultralow-temperature high-performance concrete. The preparation technique disclosed by the invention is simple to operate and has the advantages of simple steps and favorable use effect; and the workability of concrete, and the mechanical properties and endurability after curingcan satisfy the design requirements.

A disclosed environment-friendly waterproof dry-mixed mortar is prepared from the following raw materials in parts by weight: 20-45 parts of Portland cement, 7-16 parts of quartz sand, 11-16 parts of gypsum, 4-8 parts of latex powder, 4-7 parts of wood fiber, 2-6 parts of cellulose ether, 6-10 parts of nanometer silicon dioxide powder, 6-9 parts of hollow alloy bead, 5-9 parts of PP fiber, 10-20 parts of fly ash, 3-7 parts of barium sulfate, 5-8 parts of polymer glue, 15-25 parts of high alumina cement and 3-7 parts of calcium nitrite. The provided environment-friendly waterproof dry-mixed mortar is large in tensile strength, low in cost, thermal-insulating, energy-saving, waterproof, seepage-resisting, reduced in hollow, foaming and cracking phenomena, and strong in adhesive force.

The invention relates to a road concrete additive of improving folding strength, prepared of benzene solfonic acid formaldehyde condensation compound, lignin calcium sulfonate, sugar calcium, sodium calcium sulphate, ferrous sulphate, calcium nitrite and powder coal ashes. It can reduce the water dosage of concrete by above 18%, enhances the early strength of concrete by a large margin and increase the 28 d pressive strength, obviously enhance the folding strength of concrete, thus on condition of less dosage of cement, able to make the folding strength of concrete up to the requirements for above secondary roads (folding strength above 4.5 MPa), and simultaneously able to improve the durability of concrete. It can be widely applied to road concrete and simultaneously applied to the constructions (structures) of reinforced concrete, precast concrete, steam cured concrete, etc.

The invention discloses high-strength impermeable anti-freezing concrete and a preparation method thereof. The high-strength impermeable anti-freezing concrete is prepared from the following raw materials: cement, water, sand, stones, fly ash, an anti-freezing agent, a rust-inhibiting anti-corrosion waterproof agent, waste concrete particles and waste rubber particles. The anti-freezing agent is prepared from the following components in parts by weight: 3.4 to 6.8 parts of modified coal gangue; 1.2 to 2.0 parts of rice hull ash, 1.5 to 3 parts of vinyl acetate-ethylene copolymer latex powder;0.8 to 1.6 parts of silicon powder; 2.4 to 3.8 parts of polypropylene reticular fiber; 0.8 to 1.6 parts of seaweed extract; 0.9 to 1.8 parts of urea; 1.4 to 2.2 parts of calcium nitrite and 10 to 20 parts of water. The high-strength impermeable anti-freezing concrete has the advantages of effective utilization of waste materials, strong freeze-thaw resistance and mechanical properties, reduction of freeze-thaw diseases of concrete in cold regions, and purification of automobile exhaust.

In this invention new chemical reactions, new chemical processes are established, and these chemical reactions and chemical processes can be used with the system designed to produce nitrogen dioxide, nitric oxide, nitric acid as well as metallic ascorbates or alkyl ascorbates, either as main or as secondary products. Ascorbic acid solution is reacted at room temperature or at elevated temperature with either sodium nitrite or potassium nitrite or calcium nitrite or alkyl nitrite such as isobutyl nitrite or barium nitrite or silver nitrite solution. All the second reactants except alkyl nitrites such as isoamyl nitrite or isopropyl nitrite or isobutyl nitrite, as well as the first reactant, ascorbic acid, are in aqueous solutions. The reaction vessel contains the ascorbic acid solution; into this solution, under, certain pressure, is delivered the choosen aqueous nitrite solution. Gas mixture of nitrogen dioxide and nitric oxide is produced by addition of the choosen nitrite solution. The generated and collected gas mixture is then mixed with oxygen, thus the nitric oxide in the gas mixture converts—by reacting with oxygen—into nitrogen dioxide, then this homogeneous gas is dissolved in water, thus giving us nitric acid. In this chemical reaction system two sets of chemical reactions take place; one on the surface of the solution(s) that produces the main part of the gas mixture, and this is the major part of the chemical reaction system. In the liquid phase of the reaction processes form the metallic ascorbates as well as the alkyl ascorbates. All the same can be done with isoascorbic acid; the chemical reactions will go somewhat slower.

The invention relates to a comprehensive utilization method of a cyanamide waste residue. The comprehensive utilization method of the cyanamide waste residue comprises the following steps: firstly, adding an acid into the cyanamide waste residue for reaction, collecting carbon dioxide gas generated in the reaction, and filtering a reacted solution to obtain a filter residue A and a filtrate A; heating the filtrate A to 30-100 DEG C; regulating pH to 7.0-9.0 by using lime milk; filtering again; and evaporating for concentrating, crystallizing and drying an obtained filtrate Bto obtain a calcium salt. Through effective treatment of the cyanamide waste residue, inorganic calcium salts (such as calcium chloride, calcium nitrate and calcium nitrite) or organic calcium salts (such as calcium formate, calcium acetate and amino calcium sulfonate), graphite powder and carbon dioxide can be prepared, thus achieving recycle of industrial wastes; the comprehensive utilization method is simple in whole technical process and low in treatment cost; and the added valve of the product is greatly improved.

The invention relates to a multiple composite corrosion inhibitor and a preparation method thereof.The multiple composite corrosion inhibitor is made from the following materials according to parts by weight: 5-10 parts of polyepoxysuccinic acid, 5-10 parts of calcium gluconate, 5-10 parts of sodium silicate, 1-5 parts of secondary alkane sodium sulfonate, 0.5-2 parts of sodium alginate, 0.5-3 parts of zinc sulfate, 0.5-3 parts of sodium borate, 1-3 parts of sodium citrate, 1-3 parts of octadecanol polyoxyethylene ether, 1-5 parts of dimethylketoxime, 1-5 parts of ethylene glycol ethyl ether, 1-5 parts of ethylenediamine, 0.5-1 parts of tea saponin, 0.5-2 parts of a bactericide, 0.5-2 parts of a chelating agent, 0.1-0.5 part of calcium nitrite, 5-10 parts of glycerol, 5-10 parts of ethyl alcohol, and 20-50 parts of deionized water.The multiple composite corrosion inhibitor is widely applicable to carbon steel, stainless steel, aluminum and copper equipment; the corrosion inhibiting capacity meets the provisions in GB50050-2007 design standard for industrial circulating water, and the inhibitor of the invention has the advantages of no phosphorus, environment friendliness, high oxidation resistance, convenience of use and the like.

The invention relates to an additive in the process of smelting iron and steel, which comprises the following parts: 10%-15% sodium peroxide, 15%-25% sodium per chlorate, 5%-10% calcium chloride, 20%-28% borax, 5%-15% calcium nitrite, 5%-8% sodium methylol fibre, 5%-8% sodium perborate, 10%-20% polyacrylamide. The manufacturing technique comprises the following steps: (1) adding every part sequentially according to the weight and mixing mechanically; (2) mixing and heating; (3) filtering; drying and finishing the product. The invention improves the insufficient places of the original additive product, which develops a new additive; reduces the cost of smelting iron; adds the benefit.

The early setting anchoring mortar consists of cement 20-35 weight portions, quartz sand 35-50 weight portions, latex powder adhesive 2-5 weight portions, waterproof latex powder adhesive 1-2 weight portions, methyl cellulose 0.1-0.8 weight portion, heavy calcium carbonate 8-10 weight portions, calcium sulphoaluminate 1.5-3 weight portions, calcium chloride 0-2 weight portions, calcium sulfate 0-3 weight portions, early strength air entraining agent 0-0.3 weight portion, lignin 0-0.5 weight portion, and calcium nitrite 0-1.5 weight portions except essential water. It is applied for adhering heat insulating material to wall firmly.

The invention relates to a low-temperature fume oxidizing and denitration method and system. The method is characterized in that chlorine dioxide and low-temperature fume to be purified are subjected to gas-gas mixing in a fume channel and then are fed into an oxidizing tower; NO is oxidized into NO2 and NaO3 by chlorine dioxide in the oxidizing tower, and the reaction is performed under a temperature of 50 to 80 DEG C; the oxidizing and denitration are performed in the oxidizing tower, and the oxidizing reaction costs 1 to 2 seconds; the oxidized fume enters a spraying absorbing section and then is sprayed with a calcium oxide liquid at a mass concentration being 5 to 8%, and calcium nitrate and calcium nitrite liquids are generated after spraying and absorbing; and the calcium nitrite liquid is saturated and then is sequentially processed by impurity removing, evaporating, concentrating, crystallizing and purifying to obtain calcium nitrite. According to the low-temperature fume oxidizing and denitration method, ClO2 is selected and fully mixed with the fume to achieve denitration under a low temperature of 50 to 80 DEG C, and therefore, the problem of wastewater treatment can be solved; and meanwhile, the resource can be recycled; the denitration efficiency is up to more than 85%.

The invention belongs to the technical field of solid waste treatment, and particularly relates to a process method for converting dry-method desulfurized fly ash into desulfurized gypsum. The processmethod comprises the following steps: step 1, adding water and dry-method desulfurized fly ash into an oxidation tower, and stirring to obtain a dry-method desulfurized fly ash solution; step 2, introducing the dry-method desulfurized fly ash solution into sintering machine flue gas under a stirring condition for reaction; 3, after the reaction is completed, carrying out solid-liquid separation on the solution; step 4, returning the solution prepared by solid-liquid separation to an oxidation tower, and feeding a separated solid into a distillation device; step 5, carrying out solid-liquid separation in a distillation device, returning distilled water vapor to the oxidation tower, and taking the left solid as desulfurized gypsum; a precipitation method can be adopted to remove calcium chloride and calcium nitrite in the solution prepared through solid-liquid separation further. According to the method, the temperature of the flue gas of a sintering machine head and the sulfur dioxidemedium in the flue gas are fully utilized to realize conversion of calcium sulfite in the dry-method desulfurization fly ash, and meanwhile, the problem of secondary pollution caused by calcium chloride and calcium nitrite is solved.

The invention discloses a freeze-thaw resistant cement hollow brick and a preparation method thereof. The brick of the invention is prepared from the following raw materials (by weight): 42-54 parts of ordinary Portland cement, 22-28 parts of construction waste residue, 16-22 parts of mountain sand, 8-14 parts of sulfur fixation ash, 5-10 parts of hornblende, 10-15 parts of silica powder, 3-6 parts of barium carbonate, 8-12 parts of halloysite slag, 4-8 parts of copper ore tailings, 7-11 parts of coal gangue, 9-14 parts of electrolytic manganese residue, 5-10 parts of boric sludge, 6-12 parts of loess, 2-4 parts of calcium nitrite, 3-5 parts of urea, 2-3 parts of sodium acetate, 1-2 parts of 1,3-propylene glycol, 4-8 parts of calcium hydrophosphate, 6-9 parts of hydroxypropyl methyl cellulose and a proper amount of water. By compounding of raw materials including calcium nitrite, urea, sodium acetate, 1,3-propylene glycol and the like, freeze-thaw resistance of the cement hollow brick is enhanced, and the brick will not crack after 50 times of frozen-thaw cycles in an environment of minus 45 DEG C.

The invention discloses a modified hydraulic lime based material and a preparation method thereof and belongs to the technical field of building materials. The modified hydraulic lime based material comprises components of raw materials in percentage by weight as follows: 40%-80% of hydraulic lime, 5%-50% of ground mineral powder (S95level), 1%-5% of calcium nitrite, 1%-3% of lithium carbonate, 0.5%-2% of sodium gluconate, 0.5%-2% of a viscous resisting agent, 0.5%-2% of an adhesion resisting agent, 1%-3% of a thixotropy resisting agent, 1%-3% of an anti-crack resisting agent and 0.5%-1.5% of a water reducer, wherein the water reducer is an ShiJiXingYuan XY-4 type Qingdao naphthalene water reducer. The preparation method comprises steps as follows: the components are uniformly mixed in proportion and put in a grinding machine to be ground, and a mixture is obtained. The raw materials are easy to obtain, a preparation process is simple, and the modified hydraulic lime based material is simple to cure; compared with ordinary hydraulic lime, the hydraulic lime has higher crush resistance, fracture resistance and adhesion strength, has good water resistance, acid resistance, alkali resistance and ultraviolet resistance and can be well used for repairing work of antiques.

The invention relates to a seawater and sea sand-based anticorrosive additive for producing marine high-performance concrete. The anticorrosive additive is prepared from the following components by mass percent: 10 to 20 percent of calcium nitrite, 3 to 5 percent of sodium carbonate, 3 to 5 percent of sodium sulfate, 1 to 5 percent of chitosan, 0.6 to 1.0 percent of alcohol-amine compounds, 20 to 40 percent of coal ash hollow microbeads, 5 to 10 percent of zeolite molecular sieves, 3 to 5 percent of nanoscale silicon dioxide powder, and the balance of metakaolin, wherein the molar ratio of SiO2/Al2O3 in the zeolite molecular sieve is 25 to 30. Accordingto the seawater and sea sand-based anticorrosive additive for producing themarine high-performance concrete,the durability of the concrete is improved by the synergistic effect of various ways, and the content of water-soluble chlorine ions in the marine high-performance concrete is gradually decreased in 7 days, 28 to 90 days and is stable for a long term after 90 days, so that the structural safety and durability of marine reinforced concrete is guaranteed.

The invention discloses a quenching phosphorated fluid for metal comprehensive processing, which is prepared by the following raw materials in percentage by weight: 5 percent of sodium silicate, 5 percent of zinc nitrate, 5 percent of H3PO4, 1 percent of acid manganous phosphate, 1 percent of calcium sulphate, 1 percent of ammonium molybdate, 1 percent of calcium nitrite, 1 percent of magnesium chloride, 1 percent of surface active agent and the balance of water. The quenching phosphorated fluid is used for carrying out deoiling, derusting and phosphorating processing on the surface of metal simultaneously, has non-poisonous processing fluid and no metal pollution and is comprehensive processing fluid with favorable economic benefits.

The invention discloses a concrete anticorrosive rust inhibitor for cast-in-place piles. The concrete anticorrosive rust inhibitor is formed by mixing and stirring the following components by mass: 20-30% of calcium nitrite, 20-30% of silica fume, 30-40% of fly ash, 8-10% of finely ground expansive clinker, 1-1.5% of a powder plasticizer and 0.2-0.8% of an air entraining agent. The concrete anticorrosive rust inhibitor has no significant effect on working performance of concrete under appropriate dosage, improves age strength of the concrete, increases compactness of the concrete by certain self-expansion, forms a dense protective layer on a surface of a reinforcing bar, and effectively improves sulfate corrosion resistance of the concrete and erosion resistance of the reinforcing bar.

The invention discloses a polyacrylic acid type calcium nitrite corrosion inhibitor and a preparation method thereof. The polyacrylic acid calcium nitrite corrosion inhibitor has a capsule form, the capsule comprises a core and a coating, the core comprises calcium nitrite, a microcrystalline cellulose and tween 80, and the coating comprises a polyacrylic resin, talc, and hydroxypropyl methyl cellulose. The polyacrylic resin wrapped calcium nitrite corrosion inhibitor of the invention has a good stability, and the release rate of the microcapsule can be controllably optimized by changing the mass ratio between the core material and the coating material, so defects of easy loss and easy oxidation of the calcium nitrite corrosion inhibitor are effectively solved; and the polyacrylic acid type calcium nitrite corrosion inhibitor of the invention has the advantages of long valid period, good corrosion inhibition effect, and environmental protection.

The invention provides a method for improving methane purity in a sludge anaerobic digestion generated biogas. The method comprises the following steps: concentrating organic sludge till a solid content is 20-40g/L; adding an additive, and controlling a pH value to 4.0-6.0, and carrying out a hydrolytic acidification reaction at 35-39 DEG C; adjusting the pH value of the sludge after hydrolytic acidification to 6.0-6.5, carrying out an anaerobic digestion reaction, and collecting a biogas. By adopting the method, calcium nitrite is adopted as the additive, so that sludge lysis and hydrolysis acidification can be improved, the anaerobic acid generation velocity of the sludge is greatly increased, furthermore, the sludge anaerobic digestion efficiency is improved; due to the addition of thecalcium nitrite, a function of blocking carbon is also achieved, the concentration of carbon dioxide in the biogas is also reduced, and the purity of methane is improved; as the pH value is adjusted twice, both acidic hydrolysis of the sludge under the action of the calcium nitrite is improved, and growth of hydrogen type methanogens in an anaerobic methanogenesis period is facilitated, the potential that the carbon dioxide is in reaction with hydrogen to generate the methane is improved, and the purity of the methane in the biogas is further improved.