This invention discloses a method for preparing
potassium perborate from
sodium perborate
mother liquor using modified
potassium-form resin, belonging to the field of resource comprehensive utilization technology. The method includes: pretreating a 732 type strong acid cation exchange resin to convert it to the
potassium form, then modifying it with a 15-
crown ether-5
ethanol solution to obtain a
crown ether-modified potassium-form resin; passing the
sodium perborate
mother liquor through an exchange column packed with this resin, and performing
ion exchange at 20-30℃, utilizing the specific selectivity of the
crown ether for
sodium ions to efficiently replace Na ions in the
mother liquor with K ions in the resin, obtaining a pure potassium perborate solution; cooling the solution at -5~5℃ for
crystallization, separation, and
drying to obtain a high-purity potassium perborate product. This invention directly utilizes waste mother liquor as
raw material, with a mild process, and produces a product with high
active oxygen content (>16%), uniform particles, and good stability. It solves the problems of high cost, heavy
pollution, and poor product quality associated with traditional processes, achieving green and high-value utilization of waste resources.