The application relates to the technical field of all-
solid-state battery negative
electrode materials, in particular to a high-entropy
alloy negative
electrode material and a preparation method and application thereof. The application provides a high-entropy
alloy negative
electrode material which comprises base elements and additive elements; the base elements comprise P and Ge, and a
solid solution is formed between the P and the Ge; the additive elements comprise Zn and Al, and further comprise two or more than two of Si, Sn, Sb and Cu. The high-entropy
alloy negative
electrode material has high specific capacity, rate performance and long cycle stability.