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86results about How to "Less process equipment" patented technology

Hydrocyanation process with reduced yield losses

ActiveUS20080015381A1Investment exemptionSelective and efficient and stableOrganic compound preparationPreparation by hydrogen cyanide additionNitriteHydrogen
The invention provides a hydrocyanation process for the production of adiponitrile and other dinitriles having six carbon atoms, the process comprising:
    • a) forming a reaction mixture in the presence of at least one Lewis acid, said reaction mixture comprising ethylenically unsaturated nitrites having five carbon atoms, hydrogen cyanide, and a catalyst precursor composition, by continuously feeding ethylenically unsaturated nitrites, hydrogen cyanide, and a catalyst precursor composition;
    • b) controlling X and Z, wherein X is the overall feed molar ratio of 2-pentenenitriles to all unsaturated nitriles and Z is the overall feed molar ratio of hydrogen cyanide to all unsaturated nitrites, by selecting a value for X in the range from about 0.001 to about 0.5, and a value for Z in the range from about 0.5/1 to about 0.99/1, such that the value of quotient Q, wherein
Q=X[(moles3PN+4PNinthefeed)(molesallunsaturatednitrilesinthefeed)]-Z
is in the range from about 0.2 to about 10, wherein 3PN is 3-pentenenitriles and 4PN is 4-pentenenitrile; and
    • c) withdrawing a reaction product mixture comprising adiponitrile;
    • wherein the ratio of the concentration of 2-pentenenitriles to the concentration of 3-pentenenitriles in the reaction mixture is from about 0.2/1 to about 10/1;
    • wherein the catalyst precursor composition comprises a zero-valent nickel and at least one bidentate phosphite ligand; and
wherein the bidentate phosphite ligand is selected from a member of the group represented by Formulas I and 11 as described herein.
Owner:INV NYLON CHEM AMERICAS LLC

Process for preparing potassium nitrate by double decomposition method

The invention provides a metathesis method for preparation of potassium nitrate. After raw potassium chloride, ammonium nitrate and craft water finish their preparation at a certain ratio, they are input into vacuum cooling crystallizer. Then potassium nitrate is separated by crystallization and grows up. The crystallized liquid thickens by the thickening apparatus and continuously separates potassium nitrate as aim products by centrifugal machine. After the separated mother liquid exchanges heat with the reacting liquid, it is input into natural circulation evaporator to concentrate, adopting backward feed and dual effect concentration with constant pressure in the first chamber and negative pressure in the second chamber. Through cooling crystallization, thickening by the thickening apparatus, the concentrated liquid continuously separates ammonium chloride as by-products. The gained secondary mother liquid returns to preparation groove. Repeating this cyclic process, we could sequentially get solid potassium nitrate and ammonium chloride.The invention has improved production stability and product quality a lot and reduced raw material consumption and energy consumption, with simple and serial flow process. The invention has realized the mass production.
Owner:EAST CHINA ENG SCI & TECH

Hydrocyanation process with reduced yield losses

ActiveUS20080015382A1Investment exemptionSelective and efficient and stableOrganic compound preparationPreparation by hydrogen cyanide additionHydrogenPhosphite ester
The invention provides a hydrocyanation process for the production of adiponitrile and other dinitriles having six carbon atoms, the process comprising:
    • a) forming a reaction mixture in the presence of at least one Lewis acid, said reaction mixture comprising ethylenically unsaturated nitriles having five carbon atoms, hydrogen cyanide, and a catalyst precursor composition, by continuously feeding ethylenically unsaturated nitriles, hydrogen cyanide, and a catalyst precursor composition;
    • b) controlling X and Z, wherein X is the overall feed molar ratio of 2-pentenenitriles to all unsaturated nitriles and Z is the overall feed molar ratio of hydrogen cyanide to all unsaturated nitriles, by selecting a value for X in the range from about 0.001 to about 0.5, and a value for Z in the range from about 0.5/1 to about 0.99/1, such that the value of quotient Q, wherein
Q=X[(moles3PN+4PNinthefeed)/(molesallunsaturatednitrilesinthefeed)]-Z
is in the range from about 0.2 to about 10, wherein 3PN is 3-pentenenitriles and 4PN is 4-pentenenitrile; and
    • c) withdrawing a reaction product mixture comprising adiponitrile;
    • wherein the ratio of the concentration of 2-pentenenitriles to the concentration of 3-pentenenitriles in the reaction mixture is from about 0.2/1 to about 10/1;
    • wherein the catalyst precursor composition comprises a zero-valent nickel and at least one multidentate phosphorus-containing ligand;
    • wherein the multidentate phosphorus-containing ligand is selected from the group consisting of a phosphite, a phosphonite, a phosphinite, a phosphine, and a mixed phosphorus-containing ligand or a combination of such members; and
    • wherein the multidentate phosphorus-containing ligand gives acceptable results according to at least one protocol of the 2-Pentenenitrile Hydrocyanation Test Method.
Owner:INV NYLON CHEM AMERICAS LLC

Method for preparing sulphoaluminate cement and coproducing sulfuric acid by reducing gypsum with sulfur gas

ActiveCN111559879AImprove decomposition rateFast and efficient decomposition reactionSulfur compoundsEnergy inputGypsumAluminate
The invention relates to a method for preparing sulphoaluminate cement and coproducing sulfuric acid by reducing gypsum with sulfur gas. The method comprises the following steps: A, preparing gaseoussulfur; B, burdening: preparing dehydrated gypsum, bauxite, a siliceous correction material and an iron correction material into a raw material with uniform components; C, preheating and pre-reducing:preheating the raw material, feeding the preheated raw material into a reduction furnace, performing reduction reaction on the preheated raw material and the gaseous sulfur, performing gas-solid separation, feeding flue gas into a multistage suspension preheating system, and feeding the pre-reduced raw material into a rotary kiln; D, carrying out deep reduction and clinker sintering: performing adeep reduction reaction on the reduced raw material in the rotary kiln, and then performing high-temperature sintering to form sulphoaluminate cement clinker; and E, cooling the clinker, recycling heat, purifying to prepare sulfuric acid, adding gypsum and a combined material into the cement clinker, and processing to obtain sulphoaluminate cement products with different performance requirements.Compared with the prior art, the method has the following advantages: a large amount of industrial waste residues such as industrial gypsum can be consumed, limestone and natural gypsum resources canbe saved, and meanwhile, high-quality sulphoaluminate cement and industrial sulfuric acid products can be obtained.
Owner:上海三夫工程技术有限公司 +1

Preparation method of lithium ion phosphate/carbon composite material for high-rate-capability lithium ion battery

The invention discloses a preparation method of a lithium ion phosphate/carbon composite material for a high-rate-capability lithium ion battery. The preparation method comprises the following steps: analyzing the iron content and the phosphorus content of a precursor ferrous phosphate powder; adding into mixed slurry of a lithium source, a ferrous phosphate precursor and a phosphorus source according to the molar ratio of Li:Fe:P=(1.02-1):(0.98-1):1, adding a proper amount of a liquid phase reducing agent and a conductive additive, performing reflux reaction at the boiling point temperature of the reducing agent, distilling under reduced pressure and recovering a reducing solvent to obtain a lithium ion phosphate precursor; and calcining under the protection of inert gas to obtain a LiFePO4/C composite anode material. Compared with other methods, the preparation method has the advantages of simple flow, short reaction time, simple process equipment, fine synthesis product particles, uniform particle size distribution, good high-rate electrochemical performance and excellent circulating stability, and besides, the discharging specific capacity is up to 100 mAh/g at 10 C,. The synthesis reaction process does not need a high-pressure container and only needs short high-temperature calcining time, so the reducing solvent is easy to recover, energy consumption is greatly reduced; the industrial popularization is facilitated.
Owner:CHENGDU SCI & TECH DEV CENT CHINA ACAD OF ENG PHYSICS

Grate-kiln SNCR/SCR (selective non-catalytic reduction/selective catalytic reduction) denitration and active coke desulfurization combined system and grate-kiln SNCR/SCR denitration and active coke desulfurization combined process

The invention belongs to the technical field of industrial waste gas control, and relates to a grate-kiln SNCR/SCR (selective non-catalytic reduction/selective catalytic reduction) denitration and active coke desulfurization combined system. A denitration reductant injector of an SNCR system is communicated with one side, close to a rotary kiln, of a preheating section II; the preheating section II is communicated with an SCR system, and the SCR system is communicated with a drying section II; the drying section II and a preheating section I are communicated with an active coke desulfurizationand adsorption tower. The invention also provides a grate-kiln SNCR/SCR denitration and active coke desulfurization combined process. Flue gases of the rotary kiln enter the preheating section II, and the SNCR system sprays ammonia water into the flue gas inlet side of the preheating section II for denitration; the flue gases enter the SCR system for denitration, and then enter the drying sectionII to be mixed with the flue gases of the drying section I; the mixed gases enter the active coke desulfurization and adsorption tower for desulfurization after passing through an electric dust remover, a main exhaust fan and a flue gas heat exchanger. The grate-kiln SNCR/SCR denitration and active coke desulfurization combined system and the grate-kiln SNCR/SCR denitration and active coke desulfurization combined process have the advantages of improved denitration efficiency, reduced cost, high desulfurization and dust removal efficiency, and capability of meeting ultra-clean requirements.
Owner:CHINA CITY ENVIRONMENT PROTECTION ENGINEERING LIMITED COMPANY

Microorganism detoxification, and solidification and hazard-free treatment method for metal substrate sludge

The invention relates to a microorganism detoxification, and solidification and hazard-free treatment method for metal substrate sludge. The method comprises the following steps of: lowering the pH value of the substrate sludge to be 2.5 to 3.0 under the action that sulfuric acid is generated by microbial oxidation of acidithiobacillus spp.; dissolving toxic metal from a solid phase of the substrate sludge into a liquid phase; and performing solid-liquid separation to obtain acid toxic metal waste solution and solid-phase acid substrate sludge which hardly contains toxic metal, and in the liquid-phase part, reacting microbial reduction product H2S of acid-resisting sulfate reducing bacteria with toxic metal ions to obtain metal sulfide deposit to realize standard emission; and performing solidification treatment on the solid-phase part by using caustic sludge as a modifier and using cement as a curing agent to finally finish full detoxification and hazard-free treatment of the toxic metal substrate sludge, wherein the treated substrate sludge meets the requirements of engineering filling and landfill. The method of the invention has the advantages of full detoxification, no secondary pollution, a few process devices, low energy consumption and suitability for industrial operation.
Owner:OCEAN UNIV OF CHINA

Composite stamping die for supporting seat

The invention discloses a composite stamping die for a supporting seat. A mounting plate is arranged between an upper die base and a lower die base and fixed to the upper die base, and a female die is arranged between the mounting plate and the lower die base and fixed to the lower die base; a side plate is arranged on the female die, and a locating pin is arranged in the side plate and connected with the side plate and the female die at the same time; a fixed wedge plate is arranged between the mounting plate and the lower die base, a movable wedge plate makes contact with the lower die base, and cavities communicated with each other are formed in the fixed wedge plate and the movable wedge plate respectively; a forming male die is arranged in the lower die base and the fixed wedge plate, and second springs are arranged between the forming male die and the movable wedge plate; a material pressing plate is arranged in one cavity, pull rods are arranged in the material pressing plate and arranged on the upper die base, and each pull rod is sleeved with a first spring; a die shank is arranged in the upper die base, and a punching male die is fixed to the die shank and arranged in the forming male die. One set of die is adopted for the stamping die to complete blanking, forming and punching of the supporting seat, and production efficiency is high.
Owner:CHENGDU HENGTONG ZHAOYE PRECISION MACHINERY

Method for preparing tea saponin/copper compound antibacterial agent

The invention discloses a method for preparing a tea saponin/copper compound antibacterial agent, and the preparing steps include:adding natural product tea saponin and copper ions by mass ratio of (0.1-2) : 1 with stirring, keeping stirring for 2 hours to 6 hours, drying by a spray drier and then obtaining the tea saponin/ copper compound antibacterial agent. The purity of the tea saponin is above 70%. The copper ions are a mixture prepared from one or more than two of solid copper sulfate, cupric nitrate and copper chloride in an arbitrary proportion. The compound antibacterial agent has an excellent broad-spectrum antibacterial property and obvious inhibiting effect for various pathogenic bacteria such as Escherichia coil, staphylococcus aureus and the like. Compared with the bacteriostatic activity of using tea saponin or a metal new antibacterial agent alone, the bacteriostatic activity of the compound antibacterial agent is remarkably enhanced, and the compound antibacterial agent is widely used in the fields of daily chemicals, textile and food and the like, and has a good harmony and a high security with the environment. According to the method for preparing the tea saponin/copper compound antibacterial agent, the antibacterial agent has the advantages of simple technology, low cost, easiness in industrialization and stable quality and the like.
Owner:FUJIAN SHENGHUA AGRI SCI & TECH DEV

Integrated life sewage nitrogen and phosphorus removal apparatus

The invention discloses an integrated life sewage nitrogen and phosphorus removal apparatus, which can be widely used for nitrogen and phosphorus removal treatment of the life sewage, and comprises a cylindrical pool body and a mud-water separation device. A water inlet and a water outlet are provided on the sidewall of the pool body. A through-hole aerated tube is arranged on the bottom of the pool body. The mud-water separation device is fixed in the pool body by a metal support, and is divided into to two grades, and a physical phosphorus removal area and an electrochemistry nitrogen removal area are arranged in a two grades mud-water seperator. A cover plate is provided with the pool body, an air exhaust opening is provided on the cover plate, and an electrical cabinet is provided, an air pump, a time switch and a current stabilization transformer are arranged in the electrical cabinet, and the electrical cabinet is connected to a solar energy power device. By aiming the characteristics of life sewage, the apparatus has the advantages of compact structure and simple management, the integrated design is capable of substantially reducing the land occupation, no sludge backflow system is provided, the cost of investment and operation is low, thereby the integrated life sewage nitrogen and phosphorus removal apparatus is a bioelectrochemical sewage treatment device with the characteristics of no power consumption and economical and practical effects.
Owner:杭州净洋环保科技有限公司

Method for preparing paper making antibacterial agents by using oil-tea camellia shells as carriers

The invention relates to a method for preparing paper making antibacterial agents by using oil-tea camellia shells as carriers. The method is characterized in that 10 weight parts of oil-tea camellia shells particles are added into 25 to 30 weight parts of glutaraldehyde water solution, 350 to 400 weight parts of concentrated hydrochloric acid is added in a stirring way, and the reaction lasts 4 hours at 60 to 75 DEG C; 0.5 to 5 weight parts of sliver, zinc or copper metal compound solid is added, and the materials are continuously stirred for 4 to 12 hours after the dissolution; filtering, washing slag filtering are carried out until the materials to neutral, 5 weight parts of alkali liquor or reducing agents are added into the filter slag, and the materials are stirred at 40 to 80 DEG C for reaction for 0.5 to 3 hours; after the filtering is filtered slag and washed to the neutral state, and the filter slag is dried at 40 to 80 DEG C to obtain oil-tea camellia shell base paper making antibacterial agents. The antibacterial agents have the advantages that the oil-tea camellia shells are used as preparation raw materials, the resources are wide, the price is low, and the waste discharge is reduced; the preparation process is simple, the cost is lower, and high remaining rate is realized in pulp; and the preparation conditions are mild and can be easily controlled, the process equipment is less, and the operation is easy.
Owner:FUJIAN NORMAL UNIV
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