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Integrated recovery process for aromatic hydrocarbon in hydrogen peroxide oxidation tail gas

The invention relates to an integrated recovery process of aromatic hydrocarbons in hydrogen peroxide oxidation tail gas, which specifically comprises the following steps: preheating the oxidation tail gas to 95-115 DEG C, introducing the oxidation tail gas into an adiabatic expansion machine for adiabatic expansion, reducing the pressure to 0.1-0.15 MPa, suddenly reducing the temperature to 3-7 DEG C, realizing energy recovery and power generation by using the Joule-Thomson effect, and condensing and separating out most aromatic hydrocarbons; and the condensed tail gas enters the activated carbon adsorption tower for deep adsorption, so that the aromatic hydrocarbon content in the finally discharged tail gas is less than or equal to 70mg / m. Through cooperation of process units, efficient recovery of aromatic hydrocarbons (the total recovery rate is greater than or equal to 95%), self-sufficiency of energy and even negative energy consumption operation (the unit tail gas treatment energy consumption is-5-0 kW.h / 1000 m) are realized, the stability and economical efficiency of an adsorption system are remarkably improved, and the technical problems of high energy consumption, low recovery rate and poor adsorption stability of a traditional cooling and adsorption process are solved.
Owner:SHANGHAI LIBERT ENG TECH CO LTD