The present invention is use of chiral oxazolinyl. The complex comprising 1-[2-(4S)-4-R-4.5-dihydro-2- oxazolinyl-ethyl]piperidine or 1-[2-(4S)-4-isopropyl-4.5- dihydro-2-oxazolinyl-ethyl] tetrahydropyrrole, and the chloride or diethylate of bivalent metal Zn, Cu, La or Sm is used as the chiral catalyst for the addition reaction between aromatic aldehyde, substituted aromatic aldehyde or butyl aldehyde and cyanide or nitrile to prepare chiral target product. In the addition reaction of para aromatic aldehyde, R-form as main target product may be obtained in the conversion rate higher than 80 %, and ee % greater than 97 %; and in other addition reaction, S-form as main target product may be obtained in the conversion rate higher than 80 %, and ee % greater than 99 %.