The application discloses layered composite lead-free relaxor ferroelectric material and a preparation method thereof, and belongs to the technical field of piezoelectric ceramics, and overcomes the defects that the strain excited by the lead-free relaxor ferroelectric material in the prior art is small under a low driving electric field. The layered composite lead-free relaxor ferroelectric material comprises a first relaxor ferroelectric layer, a ferroelectric layer and a second relaxor ferroelectric layer arranged in sequence; and in the layered composite lead-free relaxor ferroelectric material, 0 < ferroelectric layer mass percentage < 30%. The application provides the layered composite lead-free relaxor ferroelectric material which has low driving electric field and large strain.