The invention relates to a polarization modified biological carrier and a preparation method thereof. The preparation method includes mixing and stirring polyether, alkyltin oxidant, N,N-
dimethyl formamide,
isocyanate and water according to the proportion; then adding nanometer palygouskite when the mixtures are in the foaming stage; stirring the mixtures for 15 minutes, adding dimethyl
silicone oil for defoaming, and blending polarization iron powders and modified iron powders so as to change inner molecular bond of materials, enhance
anode and
cathode of a
redox reaction and produce compounds with a high adsorbing ability in the interior; adding dibutylated hydroxytoluene to increase the stability and surface activity of materials after the mixtures react for 3 hours at a temperature of 25 DEG C when the materials are in the process of condensing; and finally,
cutting the condensed materials into blocks after solidifying and molding. According to the polarization modified biological carrier and the preparation method thereof, by means of the polarization modified materials, the surface activity of the biological carrier is greatly improved, and
sewage treatment effects are good.