89results about "Cellulose material pulping" patented technology

The invention relates to the technical field of bamboo pulp bleaching, and particularly discloses a method for preparing all-chlorine-free bleached bamboo pulp and application. The method adopts a three-section enhanced bleaching process and comprises the following steps: firstly, decomposing lignin under an alkaline condition of 100-115 DEG C through oxygen delignification (Op section); removing transition metal ions by using sulfuric acid and a metal chelating agent with a specific structure by adopting acid pickling chelation (AQ section); and finally, deeply oxidizing the residual lignin in a high-pressure oxygen environment through oxygen enhanced bleaching (Po section). In each stage, hydrogen peroxide is used as a main bleaching agent, sodium hydroxide, sodium silicate and other assistants are matched, and ineffective decomposition of hydrogen peroxide is effectively inhibited through staged pH regulation and a metal chelation technology. The whiteness of the obtained bamboo pulp is larger than or equal to 83% ISO, the kappa number is smaller than or equal to 3.0, and the requirements of high-grade paper products are completely met.

The invention provides a method for separating three major components of wood fiber biomass in one step by using a carbon dioxide-assisted two-phase solvent, and belongs to the technical field of lignocellulose treatment. The method comprises the following steps: placing an extraction solvent at the bottom of a reactor, and fixing a wood fiber biomass raw material at the upper part of the reactor; introducing carbon dioxide into the reactor, extracting under a closed condition, and introducing a cooling medium to adjust the temperature in the extraction process to obtain a solid-phase material, an organic phase and a water phase; the solid-phase material contains coarse cellulose, the organic phase contains lignin, and the water phase contains hemicellulose. The CO2 adopted by the method is non-corrosive, the aqueous solution of the CO2 is acidic, the generated H < + > can effectively promote the separation of wood fiber biomass components, and the CO2 can be recycled through pressure reduction and is circularly used for wood fiber raw material treatment.

The present invention relates to a method for preparing lignocellulose nanofibril and a lignocellulose nanofibril prepared by the method. The present invention also relates to a method for preparing a lignocellulose nanofibri reinforced composite material, and a lignocellulose nanofibri reinforced composite material prepared by the method.

The invention belongs to the technical field of mineral flotation, and particularly relates to a cellulose-based coal slime collecting agent and a preparation method and application thereof. The method comprises the following steps: performing wet grinding on recycled waste paper to obtain a paper pulp solution, stirring until paper pulp fibers are uniformly dispersed, adding excessive lithium chloride and sodium periodate, performing stirring reaction, cleaning and centrifuging to obtain precursor cellulose, performing amino alkylation modification to obtain amino alkyl cellulose, preparing the amino alkyl cellulose into a 20 g / L solution, and performing vacuum drying to obtain the lithium ion battery cathode material. And then uniformly mixing with non-polar hydrocarbon oil according to the volume ratio of 1: 2 to obtain the coal slime collecting agent. The prepared coal slime collecting agent contains the hydrophobic nanocellulose with the large length-diameter ratio, in the flotation process, adhesion of bubbles and minerals can be promoted, diffusion of the bubbles is promoted, and the flotation efficiency and the recovery rate are improved.

A low-cost process is provided to render lignocellulosic biomass accessible to cellulase enzymes, to produce fermentable sugars. Some variations provide a process to produce ethanol from lignocellulosic biomass (such as sugarcane bagasse or corn stover), comprising introducing a lignocellulosic biomass feedstock to a single-stage digestor; exposing the feedstock to a reaction solution comprising steam or liquid hot water within the digestor, to solubilize the hemicellulose in a liquid phase and to provide a cellulose-rich solid phase; refining the cellulose-rich solid phase, together with the liquid phase, in a mechanical refiner, thereby providing a mixture of refined cellulose-rich solids and the liquid phase; enzymatically hydrolyzing the mixture in a hydrolysis reactor with cellulase enzymes, to generate fermentable sugars; and fermenting the fermentable sugars to produce ethanol. Many alternative process configurations are described. The disclosed processes may be employed for other fermentation products.

A blow valve 15 and a biomass processing system 1 comprising such a blow valve Said blow valve 15 being connectable in a blow line 7 which is connecting two differently pressurized vessels 3, 5 of the biomass processing system 1. Said blow valve 15 is configured for controlling the flow of biomass material and fluid in the blow line 7, wherein said blow valve 15 comprises a shutter valve 31 with a central opening 33 of controllable size, said shutter valve 31 comprising a number of valve plates 35 which are disposed in an annular pattern surrounding the central opening 33 of the shutter valve 31 and wherein said valve plates 35 are movable in relation to each other whereby the size of the central opening 33 is controlled by moving the valve plates 35.

The present invention relates to a preparation method for a bamboo fiber for filter paper, filter paper containing the bamboo fiber, and a preparation method for the filter paper. The preparation method for a bamboo fiber for filter paper of the present invention comprises the following steps: (1) material selection: selecting bamboo; (2) chemical treatment: using a chemical agent to perform chemical treatment on the bamboo selected in step (1); (3) defibering: defibering the material obtained by means of the chemical treatment in step (2), to obtain coarse pulp; and (4) screening: screening the coarse pulp obtained in step (3) to obtain the bamboo fiber. The bamboo fiber prepared in the present invention has the mechanical property of a high elastic modulus, and the air filter paper manufactured using the bamboo fiber has the properties of high air permeability, high stiffness and high bulk.

An article including a first fiber derived from a first natural source and a second fiber derived from a fruit. A method of manufacturing an article may include combining a first and second fiber to form a fiber mixture, where the first and second fibers are obtained from discrete materials, and where at least one of the fibers is derived from an edible fruit of a plant. The article may be formed from the fiber mixture.

The present invention provides a porous paper-based decorative material and a preparation method thereof. The preparation method comprises: S100, separately preparing a porous paper base, an anti-mildew coating, and a decorative coating; S200, applying the anti-mildew coating to the paper base and performing a first heat treatment to form an anti-mildew layer on the porous paper base; S300, applying the decorative coating to the anti-mildew layer and performing a second heat treatment to form a decorative layer on the anti-mildew layer, thereby obtaining the porous paper-based decorative material. The porous paper base comprises hollow silica particles, the anti-mildew coating comprises chitosan, and the decorative coating comprises sodium alginate. The temperature of the first heat treatment is 80°C to 90°C, and the temperature of the second heat treatment is 100°C to 110°C. The present invention can produce a porous paper-based decorative material with good mechanical strength and resistance to mildew.

Feedstock including an amphiphilic lignocellulosic biomass can be processed using enzymes prior to pulping. The enzymes break down the biomass by disrupting the surface or cell walls or by reducing wax or other components. Such enzymes include cellulases, hemicellulases, laccases, peroxidases, and pectinases. Suitable enzymes can be obtained from secretions of microbes in soil organic matter from soil in which the feedstock was grown. If the pulping process includes steam explosion, such enzy matic processing of a biomass prior to steam explosion will increase absorption of water by the processed feedstock. In steam explosion, due to the increased ability of the processed feedstock to absorb water, steam explosion is more effective in breaking apart the processed feedstock. For other pulping processes, such enzymatic treatments break down the biomass, enabling extraction of the desired components from the processed feedstock through subsequent processing using less energy and fewer chemicals.

The present invention relates to a method for preparing monomers via depolymerisation from lignocellulose-containing biomass.

The application discloses a food-grade high-strength and high-toughness paper pulp, paper products and a preparation method thereof, and belongs to the technical field of papermaking. The food-grade high-strength and high-toughness paper pulp comprises 100 parts of virgin wood pulp, 1-3 parts of alginic fiber, and 0.3-1.5 parts of a wet strength agent, and the wet strength agent is a random copolymer of methyl acrylate, glycidyl ether-based polyethylene glycol monoallyl ether, dihydro-jasmine acid methyl acryloyl oxy hydroxypropyl ester and acrylamide propyl trimethyl ammonium chloride. The alginic fiber and the wet strength agent are added into the virgin wood pulp, so that the strength and toughness of the paper products are improved.

The invention relates to a process for producing a wood fibre material, comprising the steps of: heating wood chips (18) in a pre-cooker (16) by means of water or steam (26), then cooking the wood chips (18) by means of steam (26) in a cooker (14), then fibrising the wood chips (18) in a refiner (32) such that fibre material (34) is produced, wherein some of the steam branches off after fibrising and is used to heat the wood chips (18) in the pre-cooker (16), and also comprising the step of introducing an oxidisation agent (56) into the branched-off steam (26) such that volatile organic substances contained in the steam (26) are oxidised and purified steam (68) is produced, wherein the purified steam (68) is at least partially used to heat the wood chips (18).

The application provides a whole-stalk kenaf APMP pulp and a preparation method thereof, and the specific steps comprise the following steps: S1, cutting the air-dried whole-stalk kenaf into strips, washing and removing impurities to obtain material a; S2, pre-steaming the material a, and extruding and defibrating the steamed material to obtain material b; S3, impregnating the material b in a pre-impregnation liquid to form pulp, and centrifugally dewatering the pulp to a concentration of 20-30 wt% to obtain pulp a; S4, grinding the pulp a to form high-concentration ground pulp, adding the high-concentration ground pulp into an adjusting liquid a to bleach, and centrifugally dewatering the high-concentration ground pulp to a concentration of 20-30 wt% to obtain pulp b; S5, adding the pulp b into an adjusting liquid b to perform two-stage bleaching, centrifugally dewatering the pulp b to a concentration of 20-30 wt% to form pulp c, diluting the pulp c, grinding the pulp c, washing and screening after the grinding is completed, and obtaining the whole-stalk kenaf APMP pulp. The whole-stalk kenaf APMP pulp has good pulp properties, breaks the dependence of traditional APMP pulping on wood, and alleviates the shortage of domestic pulping wood resources.

The invention relates to a plant (100) for pulp preparation and supply of pulp of production quality (160) to at least one fiber forming plant (200), wherein the plant is built in scalable modular form, as well as a fiber forming plant (200) with such a plant (100) and a method (300) for building such a plant (100) and a method (400) for extending such a plant (100).The system (100) comprises at least one supply module (110) and one or more process modules (120), wherein the supply module (110) and the process modules (120) are equipped with a multitude of coordinated interfaces (150) to connect the supply and process modules (110, 120) to each other, to ensure the infrastructure supply of the process modules (120), and to receive the pulp or its components and starting materials via at least one input (130) and transport it between the process modules (120), and to offer the pulp with production quality (160) via an output (140) for use by at least one fiber forming system (200).

In general, present invention concerns an integrated lignocellulose-to-chemicals biorefinery, enabling production of renewable n-propylbenzene, phenolic oligomers, and carbohydrate pulp from lignocellulosic biomass. And it concerns an integrated biorefinery, enabling production of renewable n-propylbenzene, phenolic oligomers, and carbohydrate pulp from lignocellulosic biomass.

Sustainable paper-based packaging materials, e.g., paper-based food packaging materials, are described. The packaging materials are based on paper formed from fiber derived from waste biomass, such as hemp hurds, mixes containing hemp hurds and hemp bast fibers, bagasse, and cocoa pod husks. Also described are methods of making the packaging materials. The methods can include environmentally friendly pulping and / or bleaching processes.

The present application discloses a method for preparing pulp by dissociating straw fibers catalyzed by iron-manganese oxide cerium / carbon nanodots, the pulp and its application; the pulping method includes: S1: obtaining straw bundles by splitting straw; S2: dispersing iron-manganese oxide cerium / carbon nanodots in ethanol, adding water, then spraying the surface of the straw bundles, impregnating and catalyzing the reaction for 24 to 48 h to obtain dissociated straw products, adding sodium hydroxide, steaming at 120 to 160 °C for 15 to 30 min, and then performing straw homogenization treatment to obtain fibrillated fiber pulp; this method can effectively weaken the rigid strength of straw fiber polymers, enhance the bond breaking and plasticity of the macromolecular chains of straw fibers, reduce the energy consumption of mechanical disk milling and homogenization dissociation pulping of straw fibers, has high environmental safety, and the obtained pulp can be applied to the preparation of straw products such as straw substrate blocks, straw mulch films, straw seedling containers, and straw trays.

The present invention relates to the technical field of pulp preparation, specifically a pure physical pulping process for coniferous forest and Tencel, and a mixing device for mixed pulping, comprising a mixing box, the upper surface of which is fixedly connected to two left-right symmetrical loading buckets, the upper surfaces of the two loading buckets are jointly provided with a first driving mechanism, the bottom ends of the loading buckets are rotatably connected to a double-headed crushing blade shaft, and the coniferous forest fibers or Tencel fibers are synchronously separated and crushed and broken up by the double-headed crushing blade shaft and the first driving mechanism, and qualified coniferous forest fibers or Tencel fibers are transported to the interior of the mixing box through filtration of the loading buckets for mixed pulping by the double-headed crushing blade shaft, so that the crushing and breaking up and mixed pulping can be carried out synchronously, and the time difference between the crushing and breaking up can be used to timely remove the mixed pulp before the next input of new coniferous forest fibers or Tencel fibers into the mixing box, thereby ensuring the continuity of the entire mixed pulping process.

Methods and compositions for inhibiting scale in papermaking processes are provided. The methods may include adding an effective amount of a terpolymer composition to an aqueous medium in the papermaking process. The terpolymer may include various monomers, such as maleic anhydride, acrylic acid, and methacrylic acid. As an illustrative, non-limiting example, the weight average molecular weight of the terpolymer may be from about 5,000 Da to about 20,000 Da.

The application belongs to the technical field of resource utilization of medicinal residue, and particularly relates to a method for selectively extracting cellulose from medicinal residue by oxidation. The method for selectively extracting cellulose from medicinal residue by oxidation provided in the application can efficiently extract cellulose from medicinal residue waste in one step, and realize harmless disposal and resource utilization of medicinal residue waste. The application uses medicinal residue waste as raw material, does not need any pretreatment, removes non-cellulose plant components based on one-step oxidation of potassium peroxydisulfate, efficiently and selectively extracts cellulose, and the purity of the extracted cellulose is as high as 95%. In the application, potassium peroxydisulfate as a strong oxidant degrades the amorphous region of medicinal residue waste, avoiding the removal of non-cellulose plant components by pretreatment. The method provided in the application does not involve toxic or costly chemical reagents, is simple in steps, short in time consumption, low in energy consumption, small in wastewater production, low in COD value, and realizes the recycling of cellulose.

Methods, systems, and apparatus, including computer programs encoded on a computer storage medium, that adjust a high-pressure feeder of a feed system used in pulp production based on the fluid leakage through a low-pressure outlet of a high-pressure feeder. Methods can include obtaining multiple flow values, including (1) a make-up liquor flow value, (2) a black liquor flow value, (3) a white liquor flow value, (4) a chip chute circulation flow value, and (5) a high pressure feeder purge flow value. Methods can include determining a chip flow value specifying a flow of chips provided to the high-pressure feeder. Based on the flow values, methods can determine a fluid leakage value specifying an amount of fluid leakage through a gap between a pocket rotor and the housing of the high pressure feeder. Methods can adjust an annular gap based on the fluid leakage value satisfies a threshold leakage value.

Disclosed herein are systems and methods for concentrating a black liquor solution using a pressure driven filtration process. The systems and methods described herein integrate multiple unit operations with a graphene oxide membrane filtration apparatus to achieve concentration of a black liquor stream. These systems and methods provide a lower energy, more economical solution than currently employed thermal evaporation techniques.

The invention relates to a process for producing a wood fibre material, comprising the steps of: heating wood chips (18) in a pre-cooker (16) by means of water or steam (26), then cooking the wood chips (18) by means of steam (26) in a cooker (14), then fibrising the wood chips (18) in a refiner (32) such that fibre material (34) is produced, wherein some of the steam branches off after fibrising and is used to heat the wood chips (18) in the pre-cooker (16), and also comprising the step of introducing an oxidisation agent (56) into the branched-off steam (26) such that volatile organic substances contained in the steam (26) are oxidised and purified steam (68) is produced, wherein the purified steam (68) is at least partially used to heat the wood chips (18).

A method for isolating lignin and synthesizing nanocellulose from lignocellulosic materials is provided. The method describes crushing and grinding the lignocellulosic material under pressure with a solid acid catalyst to induce a solid-solid chemical reaction to depolymerize the lignocellulosic materials into a first product, hydrolyzing the first product into a second product, dissolving the second product in water to form a third product, reslurrying a solid mixture using a flotation reactor, collecting a froth at the top of the reactor and drying the froth to yield lignan. A system is also provided for isolating lignin and synthesizing nanocellulose.

The present application provides a preparation method of lignin-containing cellulose nanospheres, comprising the following steps: (1) crushing lignocellulosic biomass raw materials to a particle size of 20-100 mesh to obtain crushed lignocellulosic biomass; (2) mixing the crushed lignocellulosic biomass obtained in step (1) with a ternary eutectic solvent at a mass ratio of 1:10-1:20, stirring and reacting at a temperature of 80-160°C for 4-10 hours; (3) adding a mixture of organic solvent and water to step (2) to terminate the reaction, standing and cooling to room temperature, and then separating the cellulose-rich precipitate; (4) washing the precipitate obtained in step (3) to neutral, mixing with water at a mass ratio of 1:100-1:200, and then repeatedly passing through high-pressure homogenization for several times to obtain lignin-containing nanocellulose spheres. The present application fully combines the pretreatment methods of eutectic solvent and high-pressure homogenization, and has the advantages of mild conditions, simple operation, low cost, small pollution and stable product performance.

A method, system, and apparatus, including a computer program encoded on a computer storage medium, for adjusting a high-pressure feeder of a feeding system used in pulp production based on fluid leakage from a low-pressure outlet of the high-pressure feeder. The method includes obtaining a plurality of flow rates, including (1) a make-up liquor flow rate value, (2) a black liquor flow rate value, (3) a white liquor flow rate value, (4) a chip chute circulation flow rate value, and (5) a high-pressure feeder purge flow rate value. The method can include determining a chip flow rate value that specifies the flow of chips fed to the high-pressure feeder. Based on the flow rate values, the method can determine a fluid leakage value that specifies the amount of fluid leakage through a gap between a pocket rotor and a housing of the high-pressure feeder. The method can adjust the annular gap based on the fluid leakage value satisfying a leakage threshold.