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60 results about "Nickel fluoride" patented technology

Method for preparing battery-grade nickel sulfate and cobalt sulfate from mixed nickel cobalt hydroxide

The invention discloses a method for preparing battery-grade nickel sulfate and cobalt sulfate from mixed nickel cobalt hydroxide, and belongs to the technical field of nickel cobalt hydrometallurgy.The method comprises the following steps that the mixed nickel cobalt hydroxide is leached by using sulfuric acid, iron and aluminum in the solution are removed by using a nickel/cobalt/manganese-based neutralizer, liquid-solid separation is carried out to obtain iron-removed slag, nickel and cobalt are recycled through acid dissolution, a precipitator (one or more of nickel fluoride, and cobalt fluoride and manganese fluoride) is added into iron-removed liquid to remove calcium and magnesium ions in the system. Impurities such as Mn, Cu and Zn are removed from the calcium and magnesium removed liquid by using a saponified P204 extractant, nickel and cobalt are separated from the P204 raffinate by using a saponified P507 extractant to obtain battery-grade nickel sulfate and a cobalt sulfate solution, and evaporative crystallization is carried out to obtain a product. According to the method, the use amount of calcium oxide is greatly reduced, the amount of calcium ions introduced intothe system and the corresponding nickel-cobalt loss are greatly reduced, the influence of calcium sulfate crystallization on extraction is avoided, the P507 extraction operation amount is reduced, andthe purification cost is reduced.
Owner:BEIJING MINING & METALLURGICAL TECH GRP CO LTD

High electric insulation sealing method for anodized aluminum film

The invention relates to a a high electric insulation sealing method for anode oxide aluminum film, which includes [the] steps: the preparation of a sealing liquid, which includes the preparations of a normal-temperature nickel fluoride system sealing liquid and a high-temperature sealing liquid; normal-temperature sealing process, which is to put[puts] an anodized aluminum material into the normal-temperature sealing liquid for 10-15 minutes; a high-temperature process, which puts the aluminum material processed by the normal-temperature sealing liquid into the high-temperature sealing liquid for 3-5 minutes; and drying process, which gets the aluminum material out from the sealing liquid for natural drying. The invention has the advantages that compounds produced by the normal-temperature sealing and high-temperature sealing seal the micro-porous of the oxide film, especially the volume of the Al2O3.3H2O produced by the high temperature sealing increases enormously, the situation that the Ni(OH)2 becomes more and more porous with the increase of in the amount of sediment at room temperature is eliminated, and the invention has excellent sealing effect, stable film quality, good toughness, smooth surface of the film after sealed, high breakdown voltage, and good insulation. The total sealing time is short, the method not only improves productivity, but also saves energy and reduces cost.
Owner:JIANGSU UNIV

Method of directly electrodepositing zinc-nickel alloy on magnesium alloy surface

The present invention relates to a process for direct electrodeposition of zincium nickel alloy at electron alloys surfaces. According to the process, an electroplating method is adopted, electron alloys is selected as cathode, zincium nickel alloy containing nickel of 8-12% therein is selected as anode, the electric current density during electric plating is controlled at 1-2 A / dm2, and the electric plating time is 1 hour; finally, the electron alloys suffering an electrodeposition of zincium nickel alloy is put to a heat treatment furnace for a heat treating at the temperature of 150-200 DEG C and for 1 hours; the electrolysing solution adopted uses deionized water as solvent, wherein the components and their concentrations are as follows: ZnF2 8-12 g / L, NiF2, 15-25 g / L, ammonium citrate 80-120 g / L, potassium sodium 50-70 g / L, EDTA 8-12 g / L, hexamethylenetetramine 1-2 g / L, all the solutes are stirred to being entirety dissolved and into clear solution , in which the mole ratio of zincium ion to ion is controlled within 1:2-3. Said process for electrodeposition of zincium nickel alloy at electron alloys surfaces by adopting electric plating method is not dependant on the grade of electron alloys, in other words, surfaces of electron alloys of any grades can be electrodeposited with zincium. On one hand, the cost for electron alloys mat-forming treatment is reduced; on the other hand, the electroplating method is easy to realize industrialisation production. The fluorinion in zinc fluoride (nickel fluoride) plating solution exhibits an inactivating sheltering effect of the electron alloys, preventing the electron alloys being eroded in the solution. And the zinc fluoride (nickel fluoride) plating solution is of periodic duty and will not pollute the environment.
Owner:JIANGSU XINYE HEAVY IND

Catalyst for synthesizing trifluoroethylene and preparation method thereof

The invention provides a catalyst for synthesizing trifluoroethylene and a preparation method thereof. The main active component of the catalyst is a mixture of single element Ni (nickel), NiF2 (nickel fluoride), AlF3 (aluminum fluoride), C (carbon) and additives M (Ce (cerium) and Pd (palladium)). The preparation method of the catalyst comprises the following steps of mixing an aluminum-containing compound, a nickel-containing compound and an M-containing compound, dissolving into water, and adding ammonia water until completely precipitating, so as to obtain a mixture of Al(OH)3 (aluminum hydroxide), Ni(OH)2 (nickel hydroxide) and M(OH)n; adding polyols into the mixture of Al(OH)3, Ni(OH)2 and M(OH)n, mixing, drying, and roasting under the inert atmosphere, so as to obtain a carbon-containing composite oxide; reducing the carbon-containing composite oxide by hydrogen-containing mixed gas, and treating by hydrogen fluoride-containing mixed gas, so as to obtain the catalyst. The prepared catalyst has the advantages that the activity is high, the service life is long, the anti-coking ability is strong, and the like; the catalyst is especially suitable for 1,1,1,2-tetrafluoroethane to remove hydrogen fluoride to synthesize the trifluoroethylene.
Owner:SHANGHAI 3F NEW MATERIAL TECH CO LTD +1

Treatment method of fluorine-containing nickel slag generated in nitrogen trifluoride preparation process

The invention relates to a treatment method of fluorine-containing nickel slag generated in a nitrogen trifluoride preparation process, and belongs to the technical field of harmless treatment of nickel-containing hazardous wastes. The method comprises the following steps: (1) crushing the fluorine-containing nickel slag into solid powder; (2) dissolving the fluorine-containing nickel slag solid powder by using a hydrofluoric acid solution, performing stirring at 30-60 DEG C, and adding an oxidizing substance in the stirring dissolution process until the fluorine-containing nickel slag is completely dissolved to obtain a mixed solution a; (3) adjusting the pH value of the mixed solution a to 3.5-4.5 by using ammonia water, and performing filtering to obtain ferric hydroxide precipitate and a mixed solution b; and (4) continuing to adjust the pH value of the mixed solution b to 6.5-7.5 with the ammonia water, performing filtering to obtain nickel fluoride and a mixed solution c, heating and concentrating the mixed solution c, and performing cooling crystallizing to obtain ammonium fluoride and a mixed solution d. The method realizes recovery and cyclic utilization of nickel metal resources and ammonium fluoride, and can significantly reduce the production cost of nitrogen trifluoride.
Owner:PERIC SPECIAL GASES CO LTD

High-wear resistance material for metal surface treatment

The invention discloses a high-wear resistance material which comprises 3-7 parts of zinc, 2-4 parts of manganese, 5-9 parts of niobium, 1-5 parts of nickel, 7-11 parts of carbon, 2-8 parts of copper,11-15 parts of iron, 23-25 parts of silicon, 12-16 parts of epoxy resin, 3-8 parts of tungsten metal powder, 4-6 parts of titanium carbide, 7-9 parts of copper metal powder, 2-8 parts of phenolic resin, 3-5 parts of titanium oxide, 6 to 9 parts of silicon oxide, 2-7 parts of chromium oxide, 3-8 parts of quartz sand, 7 to 9 parts of ferrotitanium, 3 to 8 parts of ferrovanadium, 3-8 parts of silicon carbide crystal grains, 7-12 parts of molybdenum disulfide, 3-7 parts of magnesium oxide, 2-4 parts of nickel fluoride, 3-6 parts of organic amine substances, 1-3 parts of fibers, 2-6 parts of ferroboron, 3-6 parts of bauxite, 2-6 parts of silicon-calcium-barium, 4-7 parts of mineral filler, 3-5 parts of tungsten slag iron alloy, 4-8 parts of corrosion-resistant resin, 3-9 parts of alumina tabular and 5-11 parts of flake corundum. According to the present invention, the high-wear resistance material has the good wear resistance and corrosion resistance, the very strong adhesion and the higher mechanical strength and physical performance after surface treatment, is simple in formule, effectively reduces the maintenance cost, and can effectively prolong the service life of the metals afterthe material is used.
Owner:马鞍山海华耐磨材料科技有限公司

Optical reflectivity surface treatment method

The invention discloses an optical reflectivity surface treatment method. The optical reflectivity surface treatment method comprises the following steps that a product is placed on a product fixing frame, product surface oil contamination is removed through degreasing an water washing working procedures, and the product is cleaned; primary anodic oxidation treatment is carried out, and a sulfuricacid solution is adopted for carrying out primary anodic oxidation on the product; water washing is carried out after primary anodic oxidation, an alkaline solution is used for neutralization, and cleaning is carried out through water washing; sealed pretreatment is carried out, an activating agent is adopted for carrying out sealed pretreatment on the product; neutralization and water washing treatment is carried out after sealed pretreatment; secondary anodic oxidation treatment is carried out, and a sulfuric acid solution is adopted for carrying out secondary anodic oxidation on the product; water washing and neutralization are carried out after secondary anodic oxidation treatment, and water washing treatment is carried out; sealing treatment is carried out, and nickel fluoride and activating agent are adopted for carrying out sealing treatment on the product; and after sealing treatment, cleaning, drying and appearance detection are carried out, and the product is packaged. The product surface optical reflectivity is effectively reduced.
Owner:国泰达鸣精密科技集团有限公司

Treatment method for surface of heat-insulation corrosion-resistant aluminum alloy door and window

The invention discloses a treatment method for the surface of a heat-insulating corrosion-resistant aluminum alloy door and window. The treatment method comprises the following steps that the surfaceof a window frame is subjected to cleaning, oil removal, polishing, soaking, air drying, sand blasting treatment, passivation treatment, and is sprayed with a thermal insulation layer formed by a thermal insulation composition, and is sprayed with a corrosion-resistant layer formed by a corrosion-resistant composition, and layer sealing treatment and aging treatment are conducted on the corrosion-resistant layer through a nickel fluoride cold hole sealing agent. According to the method, before the thermal insulation composition and the corrosion-resistant composition are sprayed to form the thermal insulation layer and the corrosion-resistant layer, and the window frame of an aluminum alloy door and window is subjected to a series of treatment, so that the binding force of the thermal insulation layer and the corrosion-resistant layer on the surface of the window frame of the aluminum alloy door and window can be improved, and the thermal insulation layer and the corrosion-resistant layer are not prone to falling off; and the continuity and integrity of a film layer of the corrosion-resistant layer can be improved by carrying out layer sealing and aging treatment after the corrosion-resistant layer forms a film, and the surface quality of the aluminum alloy door and window can be effectively improved.
Owner:ANHUI PROVINCE JINPENG ENERGY SAVING TECH CO LTD

Spraying treatment method of aluminum alloy door and window profiles

The invention discloses a spraying treatment method of aluminum alloy door and window profiles. The spraying treatment method comprises the steps of degreasing; detecting the levelness, and finely polishing; passivating in a passivation solution to form a passivation film; performing hole sealing treatment by using a nickel fluoride hole sealing agent; aging to modify the surface quality; standingin a sealed environment of 150-180 DEG C; chromizing to form a compact chromized film; and spraying a protective coating to form a coating, and then thermally curing the coating in a nitrogen atmosphere. According to the spraying treatment method of the aluminum alloy door and window profiles, the surfaces of the aluminum alloy door and window profiles are subjected to a series of treatments before spraying treatment, so that the stability and the strength of the surface state of the aluminum alloy door and window profiles are effectively improved; by standing the aluminum alloy door and window profiles in a sealed environment of 150-180 DEG C, hydrogen atoms in the aluminum alloy door and window profiles are effectively removed, stress of the aluminum alloy door and window profiles is reduced, and product quality of the aluminum alloy door and window profiles after spraying treatment is effectively improved.
Owner:ANHUI PROVINCE JINPENG ENERGY SAVING TECH CO LTD
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