275 results about "Barium fluoride" patented technology

A compact includes a mixture of a solid binder and at least one nanopowder phosphor chosen from yttrium oxide, yttrium tantalate, barium fluoride, cesium fluoride, bismuth germanate, zinc gallate, calcium magnesium pyrosilicate, calcium molybdate, calcium chlorovanadate, barium titanium pyrophosphate, a metal tungstate, a cerium doped nanophosphor, a bismuth doped nanophosphor, a lead doped nanophosphor, a thallium doped sodium iodide, a doped cesium iodide, a rare earth doped pyrosilicate, or a lanthanide halide. The compact can be used in a radiation detector for detecting ionizing radiation.

The invention discloses a high-entropy alloy self-lubricating composite material. According to the high-entropy alloy self-lubricating composite material, four-element high-entropy alloy CoCrFeNi serves as a matrix, and silver, graphite, molybdenum disulfide, calcium fluoride, barium fluoride and cerium oxide serve as a lubrication phase; the silver element content is 2%-15%, the sum of the content of the graphite and the content of the molybdenum disulfide is 5%-10%, and the content of the graphite is equal to that of the molybdenum disulfide; the sum of the content of the calcium fluoride and the content of the barium fluoride is 5%-10%, and the ratio of the content of the calcium fluoride to the content of the barium fluoride is 4:6; the content of the cerium oxide is 3%-8%; the balance is the four-element high-entropy alloy CoCrFeNi; and all the contents are expressed by mass percent. The invention further discloses a preparation method of the composite material. The composite material provided by the invention has good self-lubricating performance and meanwhile has excellent strength and toughness within the wide temperature region (the room temperature to 800 DEG C).

Synthesis of yttrium aluminum garnet luminescent material for white light LED is carried out by proportioning by chemical component formula (Y1-x-yMyCex) 3Al5O12, weighing raw material, mixing with flux additive, putting into corundum crucible, firing in oxidation atmosphere furnace, crushing, mesh screening, acid washing by dilute nitric acid solution to indifference, extraction filtering, drying powders, firing the powder at reduction atmosphere, and screen grading to obtain the final product. It uses two kinds or above of boric acid, barium fluoride, strontium fluoride, lithium chloride or lithium fluoride as composite flux and mixes with other rare earth or metal oxide. It has excellent single crystal particular growth, powder fluidity, better brightness and low decrement.

The invention relates to the technical field of welding materials, in particular to a nickel-based welding rod for AC welding, the welding rod adopts a high-nickel alloy welding wire which is in line with the requirements of GB/T13814-2008 on ENi1008 ingredients as a welding core, and a drug paper comprises the following components: 40-50% of marble, 2-5% of potassium titanate, 20-28% of fluorite, 2-7% of barium fluoride, 1.5-3% of bentonite, 1-3% of zircon sand, 1-2% of soda ash, 1-3% of metal manganese, 3-7% of ferrosilicon containing 43.0-47.0% of Si, 1-3% of magnesium alloy containing 47-53% of Al and 7-10% of barium carbonate. When in welding, the welding rod can realize stable arc, almost no spatter, good slag detachability and excellent operating performance of the welding rod; and the shape of a weld seam is beautiful, and a wetting angle of the weld seam is moderate.

The invention introduces a nickel base welding rod of a Ni-Cr-Mo alloy system. The nickel base welding rod comprises a core wire and a coating and is characterized in that the core wire is an ERNiCrMo-3 core wire; and the coating comprises 20-40% of marble, 25-35% of fluorite, 2-5% of bentonite, 1-4% of ferrosilicon, 1-4% of manganese metal, 0-2% of sodium carbonate, 1-3% of quartz, 1-3% of strontium carbonate, 2-5% of barium fluoride, 5-10% of barium carbonate, 2-6% of potassium titanate, 2-5% of ferrotitanium, 3-6% of niobium powder and 1-4% of chromium metal. The nickel base welding rod produced by the invention is relatively high in strength, has deposited metal tensile strength which is up to more than 760MPa, is better in low-temperature impact toughness, has an impact powder average value of more than 40J at minus 196 DEG C, and is favorable in welding technological efficiency, stable in arcing during welding, easy in operation, good in formation of welding seams, convenient in deslagging, simple in production process and lower in cost.

The invention discloses a two-phase stainless steel electrode, which comprises a core wire and a coating, wherein the coating is coated on the outer wall of the core wire and accounts for 0.4 to 0.5 percent of the total weight of the electrode. The core wire comprises the following components in percentage by weight: 0.005 to 0.030 percent of C, 0.01 to 0.20 percent of Si, 1.50 to 2.50 percent ofMn, 0 to 0.025 percent of P, 19.0 to 22.0 percent of Cr, 9.0 to 11.0 percent of Ni, 2.5 to 3.5 percent of Mo and the balance of Fe. The coating comprises the following components in percentage by weight: 8 to 20 percent of calcium carbonate, 2 to 15 percent of barium carbonate, 5 to 15 percent of calcium fluoride, 6 to 17 percent of strontium fluoride, 4 to 16 percent of barium fluoride, 9 to 18 percent of cryolite, 4 to 10 percent of rutile, 1 to 5 percent of titanium white, 2 to 8 percent of silicon dioxide, 3 to 9 percent of chromium powder, 1 to 1.5 percent of molybdenum powder, 0.1 to 4 percent of magnesium powder and 5 to 13 percent of iron powder. After the coating components are uniformly mixed, an adhesion agent is added into the mixture. The two-phase stainless steel electrode has high strength, high tenacity and intercrystalline corrosion resistance; and during welding, an electric arc is stable, splashing phenomena is reduced, a welding seam is well molded, slag is easy toremove, and the electrode has high operability.

The invention discloses a method for preparing chain-shaped barium fluoride nano-ball adopting DNA as the template, and belongs to the technical field of the nano materials, which comprises the following steps: Ba(NO3)2 ultra-saturated solution is added into the DNA system, and is mixed with the DNA system in whirl way for 3 to 8 minutes; under the conditions of 20 to 30 DEG C and 50 to 150 r/min, the mixture is shaken for 2 to 4 hours; NH4F ultra-saturated solution is added in the mixed system, and is mixed in whirl way for 5 to 20 seconds, and is shaken for 3 to 5 hours under the conditions of 20 to 30 DEG C and 50 to 150 r/min. The entire system is kept quietly at the temperature of 4 to 8 DEG C to get the chain-shaped barium fluoride nano-ball adopting DNA as the template. The invention can directly adopt the biological nano structure existing in the nature as the template to synthesize the chain-shaped nano-ball structure that is different from the original methods for preparing BaF2, thereby not only preventing the complicate preparation craftwork of the conventional template, but also being completed under the moderate conditions of the normal temperature and the normal atmosphere; moreover, the method has simple craftwork, low cost, easy controlled reaction and high productivity.

The invention relates to the Cr13 series build-up self-shielded welding wire aiming to solve the wastes of material, low production efficiency, complex equipment and high cost of existing build-up welding material. It features in the mass percentage of calcium fluoride 10-20%, barium fluoride 10-20%, soda 1-2%, chrome metal 30-40%, metal powder 3-10%, manganese metal 3-5%, high carbon ferro-chrome 0-6%, Al-Mg alloy 8-14%, potassium titanate 3-7%, magnesia 2-5%. It has stable electric arc, good welding seam, easy for slag peeling clinker coating, with good self-shield effect in the welding process.

The invention provides a self-shielded flux-cored wire for X80 pipeline steel. The self-shielded flux-cored wire comprises wire skin made of mild-carbon steel strips and a flux core, and is characterized in that a formula of powder of the flux core comprises components in percentage by mass as follows: 40%-50% of barium fluoride, 10%-20% of calcium fluoride, 5%-10% of lithium fluoride, 2%-5% of barium carbonate, 1%-5% of cerium fluoride, 1%-2% of ferric oxide, 0%-2% of zirconium oxide, 0%-4% of titanium dioxide, 5%-8% of magnesium powder, 5%-10% of powdered aluminium, 6%-8% of low-carbon ferromanganese, 6%-8% of metallic nickel, 5%-10% of aluminium-zirconium alloy, 1%-5% of quartz and 0%-5% of iron powder. The self-shielded flux-cored wire is suitable for all-position welding of pipelines and good in welding processing property, wire deposited metal has good mechanical properties, impact absorbing energy of a V-shaped notch at the temperature of subzero 40 DEG C of the wire deposited metal reaches 100 J or higher, and the requirement of welding seam toughness is met.

The invention provides an environment-friendly copper-plating-free solid welding wire surface nano composite coating and belongs to the field of welding wires. The coating is prepared from nano solid powder, anti-rust oil and arc stabilizing agent at a mass ratio of (0.5-1.5): (0.2-1.0): (1.2-2.0); the nano solid powder consists of nano graphite fluoride powder, nano molybdenum powder, nano molybdenum disulfide, nano tungsten disulfide or nano ferroferric oxide, micron calcium fluoride or micron barium fluoride, and micron PTFE powder; the anti-rust oil is prepared from perfluoropolyether synthetic oil, rapeseed oil, sorbitan monooleate, petroleum sodium sulfonate, lanolin, nano serpentine, calcium naphthenate, polyisobutylene-bis-succinimide, zinc dialkyl dithiophosphate and molybdenum dialkyldithiocarbamate; the arc stabilizing agent is composed of one or more of alkali metal compounds. The prepared coating is good in wear resistance and rust resistance, stable in electric arc during welding and less in conductive nozzle wear and meanwhile has less pollution to the environment.

The invention relates to a cerium, gadolinium activated yttrium aluminium garnet fluorescent powder and preparation method, wherein the fluorescent powder is prepared from yttrium oxide, aluminium oxide, cerium oxide, gadolinium oxide, boric acid, barium fluoride, carbon powder, anhydrous alcohol as raw material, cerium oxide, gadolinium oxide and water as activating agent, boric acid and barium fluoride as fluxing agent, anhydrous alcohol as ball grinding medium, carbon powder as reducing agent through raw material mixing, grinding, ball grinding, calcining in high temperature pipe heater, cooling down, grinding, sieving, detecting, packaging and storing.

The invention provides a middle-infrared band ultrathin slab lens based on meta-material. The middle-infrared band ultrathin slab lens comprises a circular barium fluoride slab substrate. V-shaped metal bar structures are etched on the circular barium fluoride slab substrate. A gold film is coated on the V-shaped metal bar structures. On the V-shaped metal bar structures, different phases phi of V-shaped metal bar structures are arranged at positions of different radiuses r. Different V-shaped metal bar structures are arranged along a radial direction so that concentric rings are formed. The V-shaped metal bar structures arranged on each concentric ring are identical. A method of utilizing 16 groups of V-shaped metal bar structures to continuously adjust and control the phase is firstly put forward, and the middle-infrared band slab lens is processed by utilizingcombination of photo-etching and film coating methods. Compared with a conventional convex lens, a conventional curved surface Fourier transform function is substituted by phase adjustment and control through the V-shaped metal bar structures. The lens has ultrathin and slab characteristics so that weight and size are greatly reduced.

The invention discloses a high-carbon high-chrome high-vanadium wearable surfacing self-shielded flux-cored wire. According to the flux-cored wire, the core is prepared from the following components in mass percentage: 5-25% of high carbon ferro-chrome, 30-60% of chromium carbide, 15-35% of ferrovanadium, 0.5-5% of ferromolybdenum, 1-4% of electrolytic manganese, 1-4% of ferrosilicon, 1-4% of ferroboron, 1-5% of graphite, 1-5% of aluminium magnesium, 0-3% of zircon sand, 0-4% of marble, 0-3% of barium fluoride, 0-5% of barium carbonate, 0-3% of sodium fluosilicate, and 0-5% of fluorite; the skin of the flux-cored wire is a mild-carbon steel strip, the diameter is 1.6-4.0mm, and the counterweight ratio is 44-53%. According to the flux-cored wire disclosed by the invention, the rigidity and wearability of surfacing alloy can be greatly improved and the toughness of the surfacing alloy cannot be reduced; and the prepared surfacing alloy can be widely applied to surfacing repair of parts with severe low and intermediate stress abrasion at low temperature, intermediate temperature and high temperature and manufacture of new parts.

The invention relates to a basic flux-cored wire of heat-resistant steel with good slag detachability, belonging to the welding field of material processing technology. The invention solves the problem that the prior basic flux-cored wire of heat-resistant steel sticks slag seriously. The invention is characterized in that components of added flux-core are 25-37% of barium fluoride, 12-14% of metal chromium, 5-20% of Fe powder, 5-10% of silicon iron, 2-6% of Al-Mg alloy powder, 5-8% of marble, 2-4% of zirconium oxide, 7-12% of Ti, 10-11% of ferromolybdenum, 1-4% of Na2CO3 and 3-4% of manganese. The invention is provided with easy slag detachability, stable electrical arc, very small and thin splashing particle, beautiful welding line formation and good welding process performance.

The invention discloses a self-protecting flux-cored wire for composite manufacturing (remanufacturing) of continuous casting rolls and a process. The flux-cored wire comprises, by weight, 20%-60% ofmicro-carbon ferrochrome, 8%-14% of nickel, 1%-6% of molybdenum, 2%-5% of 75 ferrosilicon, 4%-6% of manganese, 0.5%-2% of rare earth oxide, 1%-3% of ferrotitanium, 1%-5% of aluminium magnesium alloy,5%-16% of rutile, 0.5%-2% of potash feldspar, 0.5%-2% of alumina and magnesia, 1%-5% of fluorite, 0.2%-3% of sodium fluoride, 0-10% of high nitrogen ferrochrome, 0-8% of high carbon ferrochrome, 0-1.2% of graphite, 0-25% of chromium powder, 0-3% of ferrovanadium and ferroniobium, 0-2% of barium fluoride, 0-3% of sodium fluosilicate, 0-3% of lithium fluoride, 0-1% lithium carbonate and the balanceiron powder. A large welding height single-layer surfacing forming process is adopted, and good process performance, high efficiency and high cost performance are achieved.

The invention discloses a spectral selective radiation infrared stealth material which sequentially comprises a substrate, an aluminum nitride layer and a dielectric layer, the dielectric layer is composed of a plurality of dielectric layers A and dielectric layers B which are arranged alternately; the dielectric layer A is made of any one of germanium, tellurium and silicon, and the dielectric layer B is made of any one of zinc sulfide, zinc selenide, magnesium fluoride, barium fluoride and calcium fluoride. The preparation method of the material comprises the following steps: (1) cleaning and drying the substrate; (2) preparing an aluminum nitride layer on the surface of the substrate by adopting a magnetron sputtering or tape casting method; and (3) adopting magnetron sputtering or electron beam evaporation, depositing a dielectric layer A on the aluminum nitride layer firstly, then depositing a dielectric layer B on the aluminum nitride layer, depositing the dielectric layer A andthe dielectric layer B repeatedly and alternately until the designed number of layers is reached, and completing preparation of the infrared stealth material. The spectral selective radiation infraredstealth material disclosed by the invention considers the requirements of low emissivity and radiation heat dissipation, and has important significance for better realizing infrared stealth.

The invention provides a surface carboxylic acid functionalized water-soluble rare earth doped barium fluoride chloride nano-luminescent material and a preparation method thereof, and relates to the preparation of a surface-functionalized water-soluble nano-luminescent material. The composition of the barium fluoride chloride nano-luminescent material prepared by the present invention is: XLn3+-(1-x)BaFCl (Ln=Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb ; x=0-60mol%). Using PAA as a surfactant, a water-soluble rare earth-doped barium fluoride chloride nanoluminescent material with surface carboxylic acid functionalization was prepared by one-step reaction. Through transmission electron microscope, infrared absorption spectrum, thermogravimetric curve and other test methods, it is proved that PAA is effectively coated on the surface of nanoparticles. The obtained nanopowder has good water solubility, and the carboxylic acid groups on its surface lay the foundation for the next step of binding biomolecules. By doping with different rare earth ions, the material can realize strong fluorescence emission of rare earth ions from the visible to the infrared range.

The invention belongs to the technical field of welding materials, and particularly relates to a small-sized self-shielded flux-cored wire suitable for all-position welding. The small-sized self-shielded flux-cored wire suitable for all-position welding comprises a carbon steel skin and a flux core filled in the carbon steel skin, wherein the flux core comprises the following the components according to the total mass percent of the flux core: 25-30% of barium fluoride, 4-7% of lithium fluoride, 2-3% of rare earth fluoride, 14-16% of magnesium powder, 8-12% of aluminum powder, 1-2% of graphite, 4-7% of manganese metal and the balance being iron powder. The invention also provides application of the small-sized self-shielded flux-cored wire suitable for all-position welding. The small-sizedself-shielded flux-cored wire is used for the welding of a light steel structure. When the flux-cored wire provided by the invention is used for welding, gas protection is not needed, and the weldingprocess is protected only by slagging, gas-making and strong reducing substances in the flux core components during welding; the small-sized self-shielded flux-cored wire has strong anti-wind capability and high deposition efficiency and meets E71T-11 related requirements in American Standard AWS 5.20.

The invention relates to a special self-protection flux-cored wire for resurfacing a rail, which is manufactured by using cold-rolled low-carbon steel strip as a raw material and adopting a conventional flux-cored transition alloy mode , a universal powder specification and a flux-cored wire production process. The flux-cored wire comprises the following components of 12-15 percent of calcium fluoride, 10-20 percent of barium fluoride, 4-5 percent of aluminium oxide, 10-20 percent of aluminium magnesium alloy, 3-5 percent of iron powder, 5-6 percent of high carbon ferromanganese, 8-10 percent of metallic nickel, 3-5 percent of chrome, 1-3 percent of molybdenum and the balance of calcium carbonate. The flux-cored wire is used for semi-automatic welding or fully-automatic welding, can be continuously conveyed without gas shielding, and has the advantages of strong wind resistance, low cost, good welding quality, easy operation, excellent process and mechanical properties, stable electric arc, small sputtering and attractive formation.