Environment-friendly copper-plating-free solid welding wire surface nano composite coating

A nano-composite coating, solid welding wire technology, applied in welding media, welding equipment, welding/cutting media/materials, etc. Excellent silk performance

Active Publication Date: 2017-06-09
BEIJING UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The traditional gas-shielded solid welding wire mainly uses copper plating as the final post-processing process, so that the surface of the welding wire has good conductivity and rust resistance, and the wear of the contact tip is small. Waste acid waste alkali and other substances that pollute the environment will be produced, and the welding fume contains a large amount of "copper fume", which will seriously damage the health of welders and induce many respiratory diseases
At the same time, the copper layer on the surface of the copper-plated welding wire is easy to peel off, which will block the wire feeding hose and seriously affect the wire feeding performance of the welding wire. Arc breaks and no wire feeding often occur during welding. It is not suitable for continuous robot automatic welding, so it is urgently needed Development of an enviro

Method used

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  • Environment-friendly copper-plating-free solid welding wire surface nano composite coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] A nanocomposite coating on the surface of a copper-free solid welding wire is prepared by mechanical coating, wherein every 10kg of welding wire contains 0.5g of nanometer solid powder, 0.8g of antirust oil, and 1.2g of arc stabilizing agent.

[0018] The nanometer solid powder is mixed by the following substances by weight percentage: 10% nanoscale graphite fluoride powder, 15% nanoscale molybdenum powder, 3.0% nanometer molybdenum disulfide, 0.8% nanometer ferric oxide, 25% Micron-sized calcium fluoride or micron-sized barium fluoride, 46.2% micron-sized PTFE powder.

[0019] Anti-rust oil is made of the following ingredients by weight percentage: perfluoropolyether synthetic oil 80%, rapeseed oil 7%, sorbitan oleate 1.5%, sodium petroleum sulfonate 1.0%, lanolin 0.6%, nano Serpentine 2.0%, calcium naphthenate 0.5%, polyisobutylene bis-succinimide 3.0%, zinc dialkyldithiophosphate 2.2%, molybdenum dialkyldithiocarbamate 2.2%.

[0020] The arc stabilizer consists of s...

Embodiment 2

[0022] A nanocomposite coating on the surface of a non-copper-plated solid welding wire is prepared by mechanical coating, wherein every 10kg of welding wire contains 0.7g of nanometer solid powder, 0.3g of antirust oil, and 1.4g of arc stabilizing agent.

[0023] The nano solid powder is mixed by weight percentage: 12% nano-scale graphite fluoride powder, 14% nano-scale molybdenum powder, 5.0% nano-molybdenum disulfide, 2.2% nano-ferric oxide, 23% Micron-sized calcium fluoride, 43.8% micron-sized PTFE powder.

[0024] The anti-rust oil is made of the following ingredients by weight percentage: perfluoropolyether synthetic oil 77%, rapeseed oil 8%, sorbitan oleate 2.2%, sodium petroleum sulfonate 1.4%, lanolin 0.9%, nano Serpentine 2.2%, calcium naphthenate 0.9%, polyisobutylene bis-succinimide 3.5%, zinc dialkyldithiophosphate 2.5%, molybdenum dialkyldithiocarbamate 1.4%.

[0025] The arc stabilizer consists of potassium carbonate.

Embodiment 3

[0027] A nanocomposite coating on the surface of a copper-free solid welding wire is prepared by mechanical coating, wherein every 10kg of welding wire contains 0.9g of nanometer solid powder, 0.5g of antirust oil, and 1.2g of arc stabilizing agent.

[0028] Nano solid powder is mixed by weight percentage: 14% nano-scale graphite fluoride powder, 13% nano-scale molybdenum powder, 8% nano-tungsten disulfide, 1.4% nano-ferric oxide, 21% Micron-sized calcium fluoride, 42.6% micron-sized PTFE powder.

[0029] The anti-rust oil is made of the following ingredients by weight percentage: perfluoropolyether synthetic oil 75%, rapeseed oil 9%, sorbitan oleate 2.7%, sodium petroleum sulfonate 1.8%, lanolin 1.3%, nano Serpentine 2.5%, calcium naphthenate 0.7%, polyisobutylene bis-succinimide 3.2%, zinc dialkyldithiophosphate 2.3%, molybdenum dialkyldithiocarbamate 1.5%.

[0030] The arc stabilizer consists of cesium carbonate.

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Abstract

The invention provides an environment-friendly copper-plating-free solid welding wire surface nano composite coating and belongs to the field of welding wires. The coating is prepared from nano solid powder, anti-rust oil and arc stabilizing agent at a mass ratio of (0.5-1.5): (0.2-1.0): (1.2-2.0); the nano solid powder consists of nano graphite fluoride powder, nano molybdenum powder, nano molybdenum disulfide, nano tungsten disulfide or nano ferroferric oxide, micron calcium fluoride or micron barium fluoride, and micron PTFE powder; the anti-rust oil is prepared from perfluoropolyether synthetic oil, rapeseed oil, sorbitan monooleate, petroleum sodium sulfonate, lanolin, nano serpentine, calcium naphthenate, polyisobutylene-bis-succinimide, zinc dialkyl dithiophosphate and molybdenum dialkyldithiocarbamate; the arc stabilizing agent is composed of one or more of alkali metal compounds. The prepared coating is good in wear resistance and rust resistance, stable in electric arc during welding and less in conductive nozzle wear and meanwhile has less pollution to the environment.

Description

technical field [0001] The invention relates to an environment-friendly method for preparing a nanocomposite coating on the surface of a copper-free solid welding wire, belonging to the field of welding wires. Background technique [0002] In 2015, the total output of welding materials in my country was about 4.15 million tons, of which solid welding wire accounted for more than 38%, and it has formed two main bodies alongside welding rods. With the continuous improvement of the level of welding automation in my country, the proportion of welding robots used in the production of welding structures is getting higher and higher, the proportion of welding rods will decrease, and the proportion of solid welding wire will increase. It is estimated that by 2025, solid welding wire will become my country's The first major body of welding material. Environmental pollution problems generally exist in the machinery manufacturing industry. With the country's emphasis on environmental p...

Claims

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Application Information

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IPC IPC(8): B23K35/36
Inventor 栗卓新万千张天理
Owner BEIJING UNIV OF TECH
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