The invention discloses a supported
ruthenium complex catalyst. The supported
ruthenium complex catalyst comprises a porous
solid carrier, and a
ruthenium complex, a
metal assistant and a
nonmetal assistant which are supported on the surface of the carrier, and the ruthenium complex is one or more of a polypyridine ruthenium complex, a ruthenium
porphyrin ruthenium complex, an aromatic hydrocarbonruthenium complex, a cyclic
metal ruthenium complex, a DMSO ruthenium complex, an amine ruthenium complex and an
imine ruthenium complex; the
metal assistant is salt of one or more of In, Bi, Ba, Sr,Fe, Mn, Zn, Cs, Ca and Sn; the
nonmetal assistant is an
ionic liquid; and a ratio of the
mass of the porous
solid carrier to the theoretic
mass of ruthenium in the ruthenium complex to the
mass of the metal in the metal assistant to the mass of the
nonmetal assistant is 100:(0.01-2):(0.01-3):(1-30). The catalyst has a very high stability in an
acetylene hydrochlorination reaction, no obvious lossof the ruthenium is detected after the catalyst runs for 8000 h, the highest
acetylene conversion rate reaches 99.95% or more, and the highest
vinyl chloride selectivity reaches 99.95% or more.