Nontoxic antifouling paint for oceanographic ship and facilities and method for preparing paint

A technology for antifouling coatings and ships, applied in the field of coatings, can solve the problems of poor physical and chemical properties, unclear application prospects, and short effective antifouling period of alkaline silicate antifouling coatings, and achieve high cost performance and antifouling performance significant effect

Active Publication Date: 2011-02-09
CHINA LUCKY FILM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, studies have shown that the effective antifouling period of alkaline silicate antifouling coatings is not long, the physical and chemical properties are poor, and the practical application prospects are not clear

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Add each component into the batching tank of the multifunctional disperser according to the following formula, keep the mixture at 50°C, stir, disperse, and grind at a speed of 2000r / min for 4 hours to prepare 1kg of non-toxic marine antifouling paint finished product.

[0042] The weight of each component in the formula is respectively:

[0043] (1) Acrylic resin 500.00g,

[0044] (2) Zinc oxide 187.43g,

[0045] (3) Iron oxide red 124.95g,

[0046] (4) Talcum powder 62.57g,

[0047] (5) Xylene 124.95g,

[0048] (6) Silver particles 0.10g,

[0049] The average particle diameter of the silver particles is 15 nm.

Embodiment 2

[0051](1) The water-soluble acrylic resin base material is mixed with water to form a water-soluble resin aqueous solution, and then organic silicon coupling agent vinyltriethoxysilane and dimethyl silicone oil additives are added to the water-soluble resin aqueous solution;

[0052] (2) Add ultra-fine silicon dioxide, titanium dioxide, zinc oxide, light magnesium oxide, sodium silicate and antifouling agent into the batching tank of the multifunctional disperser in sequence at 55°C; stir at a speed of 3500r / min , disperse, and grind for 2 hours to prepare 1 kg of non-toxic marine antifouling paint.

[0053] The weight of each component in the formula is respectively:

[0054] (1) 392.04g of water-soluble acrylic resin,

[0055] (2) 417.00g deionized water,

[0056] (3) Vinyltriethoxysilane 6.58g,

[0057] (4) Simethicone oil 16.06g,

[0058] (5) Ultrafine silicon dioxide 22.94g,

[0059] (6) Titanium dioxide 13.28g,

[0060] (7) Zinc oxide 45.96g,

[0061] (8) Light ma...

Embodiment 3

[0066] Add each component into the batching tank of the multifunctional disperser according to the following formula, keep the mixture at room temperature, stir, disperse, and grind at a speed of 1500r / min for 6 hours to obtain 1 kg of non-toxic marine antifouling paint finished product.

[0067] The weight of each component in the formula is respectively:

[0068] (1) Coal tar pitch liquid 90.82g,

[0069] (2) Rosin 208.58g,

[0070] (3) Zinc oxide 159.68g,

[0071] (4) Red clay 211.58g,

[0072] (5) Talcum powder 93.81g,

[0073] (6) Heavy benzene 233.53g,

[0074] (7) Silver particles 2.00g,

[0075] The average particle diameter of the silver particles is 22 nm.

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Abstract

The invention discloses a nontoxic antifouling paint for an oceanographic ship and facilities and a method for preparing the paint. The paint consists of the following components in percentage by weight: 15 to 55 percent of base material, 0.01 to 10 percent of antifouling agent, 10 to 30 percent of filler, 0.3 to 25 percent of pigment, 2 to 8 percent of auxiliary agent and 3 to 55 percent of solvent, wherein the antifouling agent is silver grains with average grain diameter of between 1 and 200nm. The paint does not contain toxic agents, such as dichloro-diphenyl-trichloroethane, organic tin,cuprous oxide and the like, at all while effectively suppressing corrosion of marine biological attachments, meets the related regulations of international maritime organization and future development trend of the antifouling paint, realizes non-toxicity and environmental friendliness of the marine antifouling technology, and can be widely applied to the facilities and the fields, such as ships, floating piers, marine oil platforms, submarine cables, cooling pipes of power plant near the sea, sea water culture net cage and the like.

Description

technical field [0001] The invention belongs to the technical field of coatings, in particular to a non-toxic antifouling coating used for marine vessels and facilities. Background technique [0002] One of the most important problems encountered in offshore operations is the attachment and fouling of some marine organisms to various marine facilities such as ships, offshore drilling platforms, buoys, mariculture cages, and marine detection instruments. At present, more than 200,000 species of marine organisms have been preliminarily proven, including thousands of species of attached organisms. This kind of marine organisms mainly attach to the hull and the parts below the waterline of marine facilities, which will bring great harm and considerable economic losses to offshore operations. Preventing the harm and adverse effects of marine attached organisms on ships and marine facilities has always been is the focus of attention. [0003] Statistics show that the damage and ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D123/06C09D167/08C09D161/24C09D195/00C09D175/04C09D133/00C09D127/06C09D193/04C09D5/16C09D161/06C09D115/02C09D163/00C09D7/12C09D149/00C09D161/28C09D127/12C09D1/00C09D131/04C09D183/00
Inventor 邹竞王虹吕丽云
Owner CHINA LUCKY FILM CORP
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