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451results about How to "Eliminate emissions" patented technology

Semi-closed brayton cycle gas turbine power systems

A semi-closed combined cycle power system 100 is provided which can also convert an open combined cycle gas turbine 10 into a non-polluting zero emissions power system. The prior art open combined cycle gas turbine 10 includes a compressor 20 which compresses air A' and combusts the air A' with a fuel, such as natural gas. The products of combustion and the remaining portions of the air form the exhaust E' which is expanded through the turbine 40. The turbine 40 drives the compressor 20 and outputs power. The exhaust E' exits the turbine 40 and then can optionally be routed through a heat recovery steam generator 50 to function as a combined cycle. According to this invention, the exhaust E' is not emitted into the atmosphere, but rather is routed to a divider 110. The divider 110 includes two outlets for the exhaust E' including a return duct 120 and a separation duct 130 which both receive a portion of the exhaust E'. The return duct 120 routes a portion of the exhaust E' back to the compressor 20. Before reaching the compressor 20, an oxygen duct 150 adds additional oxygen to the exhaust E' to form a gas mixture C which includes CO2 and steam from the exhaust E' and oxygen from the oxygen duct 150. This gas mixture C has characteristics which mimic those of air, so that the compressor 20 need not be modified to effectively compress the gas mixture C. The gas mixture C is compressed within the compressor 20 and routed to the combustor 30 where the fuel combusts with the oxygen of the gas mixture C' and produces exhaust E' which is substantially entirely CO2 and steam. This exhaust E' is routed through the turbine 40 and expanded to drive the compressor 20 and output power. The exhaust E' exits the turbine 40 and is routed back to the divider 110, preferably by way of a heat recovery steam generator 50 or other heat removal device, so that the semi-closed cycle operates as a combined cycle power system 100. The divider 110 directs a portion of the exhaust E' to a separation duct 130 which leads to a condenser 140. In the condenser 140 the exhaust E' is separated by condensation of the steam/water portion of the exhaust and removal of the remaining CO2 as gas from the condenser 140. The only exhaust from the semi-closed power system 100 is water and CO2 from the condenser. The CO2 exhaust is substantially pure and ready for appropriate further handling and disposal. Hence, no pollutants are emitted from the semi-closed power system 100. The return duct 120 can
Owner:CLEAN ENERGY SYST

Tire with low hydrocarbon emission rubber combination of tread and sidewall components with compositional limitations

The invention relates to a tire of a structural combination of tire tread and sidewall components with compositional limitations containing minimal, if any, of in situ formed alcohol and methyl isobutyl ketone byproducts. The tread component rubber composition contains pre-hydrophobated silica reinforcement. The sidewall component contains low unsaturation EPDM or brominated copolymer of isobutylene and p-methylstyrene and may contain pre-hydrophobated silica reinforcement. The silica reinforcement for said tread and sidewall components is a pre-hydrophobated precipitated silica. The pre-hydrophobated silica is prepared, prior to mixing with the elastomer(s), by reacting hydroxyl groups (e.g. silanol groups) contained on the surface of a precipitated silica with an alkoxyorganomercaptosilane or a combination of an alkoxyorganomercaptosilane and a substituted alkylsilane or with a bis-3(trialkoxysilylalkyl) polysulfide which contains an average of from 2 to 4 connecting sulfur atoms in its polysulfidic bridge to form a composite thereof. The alcohol byproduct therefrom is removed from the composite prior to its introduction into the rubber composition(s). In another aspect of the invention, the connecting sidewall rubber composition, and optionally the tread composition is free of N-(1,3-dimethylbutyl)-N′-phenyl-p-phenylenediamine antidegradant (referred herein to as 6PPD) in order to prevent in situ formation of methyl isobutyl ketone byproduct from the reaction of 6PPD with atmospheric oxygen and / or ozone.
Owner:THE GOODYEAR TIRE & RUBBER CO

Indirect air cooling method and system for working medium adopting parallel-connection positive and reverse refrigeration cycle

The invention discloses an indirect air cooling method and a system with the working fluid of parallel-connected obverse and inverse refrigeration cycles. Based on the phase transition in the working fluid cooling process, a double-phase transition heat exchanger and a single-phase transition heat exchanger are respectively coupled with an obverse refrigeration cycle and an inverse refrigeration cycle which are connected in parallel; the saturated gaseous refrigerant from the phase-transition heat exchangers is compressed, boosted and then sent to an air-cooled radiator for exothermic condensation, then the condensed refrigerant enters a liquid storage tank and is decompressed through a throttle valve and sent to the phase-transition heat exchangers so as to complete the obverse refrigeration cycle; or the saturated gaseous refrigerant from the phase-transition heat exchangers is throttled and decompressed through a thermal expansion valve and then sent to the air-cooled radiator and the liquid storage tank, pressurized by a booster pump and finally sent back to the phase-transition heat exchangers so as to complete the inverse refrigeration cycle. The method and the system can be widely applied to the cooling systems of the condensers in thermal power, nuclear power and other turbine-generator units or the cooling systems of the intercoolers in petroleum, chemical and other industries to reduce energy consumption, save investments, as well as improve water-saving rate and the adaptability of the cooling system to the environment; therefore, the method and the system are provided with promotional values and can produce larger social environmental benefits and economic benefits after implementation.
Owner:NORTHEAST DIANLI UNIVERSITY

Continuous recovery device and continuous recovery process of vanadium, molybdenum and titanium in SCR (selective catalytic reduction) waste catalyst

The invention discloses a continuous recovery device and a continuous recovery process of vanadium, molybdenum and titanium in an SCR (selective catalytic reduction) waste catalyst, wherein a crusher is connected with a secondary magnetic separation device, the secondary magnetic separation device is connected with a tunnel kiln, the tunnel kiln is connected with a smasher, the smasher is connected with an alkaline leaching kettle, the alkaline leaching kettle is connected with a suction filtration groove, the suction filtration groove is connected with a vacuum evaporation tank, the vacuum evaporation tank is connected with a vanadium sedimentation reaction tank, and the vanadium sedimentation reaction tank is connected with a molybdenum sedimentation suction filtration groove; the alkaline leaching kettle is clamped outside the reaction kettle, a top overflow opening is positioned in the upper side of the jacket, a charging opening and a filling opening are positioned in the upper part of the reaction kettle, and the filling opening is guided to the middle part of the reaction kettle by virtue of a guide pipe. According to the continuous device disclosed by the invention, the production efficiency is effectively improved, thereby facilitating subsequent automatic and continuous production. A flat plate type flue gas denitrification catalyst is continuously recovered, infiltrating water is recycled, and the water yield is greatly saved.
Owner:DATANG NANJING ENVIRONMENTAL PROTECTION TECH

Method and device for solar reduction iron making

The invention discloses a method and a device for solar reduction iron making. The device comprises a solar photovoltaic cell, a wind driven generator, an electrolyzer, a hydrogen heating chamber, a solar reduction furnace and gas treatment equipment. The hydrogen heating chamber and the reduction furnace are provided with a composite optical heating system consisting of a condenser, a heliostat and heat absorbing equipment. In the process of solar reduction iron making, hydrogen prepared by electrolyzing water is used as a reducing agent, the hydrogen is preheated and heat is provided for iron oxide reduction through a photo-thermal principle, the preheated hydrogen is introduced into the solar reduction furnace for reduction reaction so as to generate iron, the iron is smelted into molten iron, and the rest hydrogen is purified, and fed into a system for recycle through a circulating fan. Through the solar reduction iron making, non-renewable energy resources are saved, and the emission of greenhouse gases such as CO2 and the like is avoided. The electrolyzed hydrogen does not contain any harmful impurities, the temperature required by reduction in the reduction iron making process taking the hydrogen as the reducing agent is low, the reaction time is short, carbon dioxide is not generated, and the reduced iron has good quality.
Owner:SHIJIAZHUANG XINHUA IND FURNACE CO LTD

Method for preparing fatty acid methyl ester by using waste edible oil

The invention aims to provide a process for preparing fatty acid methyl ester. According to the process, glycerol is used for replacing methanol, no acid catalyst is added, and direct esterification is carried out for deacidifying and deodorizing waste oil through gas stripping dehydration by using an inert gas. The process is a clean production method which is characterized in that raw materials do not need to be pretreated, water generated during reaction is taken out of a reaction system during reaction, the yield of the fatty acid methyl ester is increased, and no waste water or waste gas is emitted. The process comprises the steps of mixing the waste edible oil (acid value of 30-160mgKoH / g) with glycerol in a molar ratio of fatty acid of 1:(1-2) and adding the mixture into a reaction kettle, introducing the inert gas nitrogen, reacting for 1-4h under the conditions that the reaction temperature is 140-200 DEG C and the vacuum pressure of the reaction kettle is 30-50 KPa, reducing the acid value of an esterification product to be below 3.0mgKoH / g; and preparing the fatty acid methyl ester from materials by adopting the traditional base catalysis ester exchange reaction after the esterification is ended. Because a process of directly esterifying the waste edible oil through acid-free catalysis is adopted, the conversion rate of fatty acid is high, the content of the fatty acid in the waste edible oil is low, and the base catalysis ester exchange is complete.
Owner:BEIJING INSTITUTE OF PETROCHEMICAL TECHNOLOGY

Tire with low hydrocarbon emission rubber combination of tread and sidewall components with compositional limitations

The invention relates to a tire of a structural combination of tire tread and sidewall components with compositional limitations containing minimal, if any, of in situ formed alcohol and methyl isobutyl ketone byproducts. The tread component rubber composition contains pre-hydrophobated silica reinforcement. The sidewall component contains low unsaturation EPDM or brominated copolymer of isobutylene and p-methylstyrene and may contain pre-hydrophobated silica reinforcement. The silica reinforcement for said tread and sidewall components is a pre-hydrophobated precipitated silica. The pre-hydrophobated silica is prepared, prior to mixing with the elastomer(s), by reacting hydroxyl groups (e.g. silanol groups) contained on the surface of a precipitated silica with an alkoxyorganomercaptosilane or a combination of an alkoxyorganomercaptosilane and a substituted alkylsilane or with a bis-3(trialkoxysilylalkyl) polysulfide which contains an average of from 2 to 4 connecting sulfur atoms in its polysulfidic bridge to form a composite thereof. The alcohol byproduct therefrom is removed from the composite prior to its introduction into the rubber composition(s). In another aspect of the invention, the connecting sidewall rubber composition, and optionally the tread composition is free of N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine antidegradant (referred herein to as 6PPD) in order to prevent in situ formation of methyl isobutyl ketone byproduct from the reaction of 6PPD with atmospheric oxygen and/or ozone.
Owner:THE GOODYEAR TIRE & RUBBER CO
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