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Continuous casting slab high-temperature oxidation resistant coatings and preparation process thereof

An anti-oxidation coating and preparation technology, applied in the direction of coating, etc., can solve the problems of inapplicability to industrial production and promotion, high cost of coating, and various additives, so as to prevent oxidation and decarburization and the loss of alloying elements, cost Inexpensive, natural exfoliation enhanced effect

Inactive Publication Date: 2010-04-14
UNIV OF SCI & TECH BEIJING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although this coating has certain high temperature resistance, oxidation resistance and thermal stability, the cost of the coating is too high, the process is complicated, the additives are too many, it is not easy to mix, and it is not suitable for industrial production and promotion.
[0006] Although the above-mentioned coatings have good high-temperature anti-oxidation effects on the specified billet to a certain extent, most of these coatings are limited to normal temperature coating, drying, film formation and static high-temperature protection, which limits the promotion of such achievements

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] Take zircon, mica, albite, wollastonite, vermiculite, carbon powder, etc. according to dry powder chemical composition: 3% ZrO 2 , 12% Al 2 o 3 , 40% SiO 2 , 15% MgO, 12% CaO, 3% Fe 2 o 3 , 5% C, 5% Na 2 O, 5% ZnO were ground to below 120 mesh respectively, mixed the materials, added the mixed binder and adjusted to the density of the final coating slurry with water to 1200kg / m 3 , to obtain the continuous casting slab high temperature anti-oxidation coating I of the present invention. The paint is sprayed on the surface of the Q345B cast slab at 800°C to form a layer of off-white protective coating. After heat treatment, the oxide scale protected by the coating is significantly thinner than that without coating protection, and the oxidation burning rate is reduced by more than 60%, and the coating can be peeled off naturally. After peeling off, the surface of the substrate is uniform and smooth without residue .

Embodiment 2

[0041]Take zircon, mica, albite, wollastonite, vermiculite, borax, carbon powder, etc. according to dry powder chemical composition: 4% ZrO 2 , 11% Al 2 o 3 , 30% SiO 2 , 15% MgO, 12% CaO, 3% Fe 2 o 3 , 4% B 2 o 3 , 10% C, 6% Na 2 O, 5% ZnO were ground to below 120 mesh respectively, mixed the materials, added the mixed binder and adjusted to the density of the final coating slurry with water to 1300kg / m 3 , to obtain the continuous casting slab high temperature anti-oxidation coating II of the present invention. The paint is sprayed on the surface of SS400 billet at 1000°C to form a layer of off-white protective coating. After heat treatment, the oxide scale protected by the coating is significantly thinner than that without coating protection, and the oxidation burning rate is reduced by more than 70%, and the coating can be peeled off naturally. After peeling off, the surface of the substrate is uniform and smooth without residue .

Embodiment 3

[0043] Take zircon, mica, potassium feldspar, corundum, talcum powder, carbon powder, etc. according to dry powder chemical composition: 3% ZrO 2 , 13% Al 2 o 3 , 44% SiO 2 , 12% MgO, 13% CaO, 2% ZnO, 7% C, 3% Na 2 O, 3%K 2 O are ground separately to below 120 mesh, mix the materials, add the mixed binder and adjust the density of the final coating slurry to 1200kg / m with water 3 , to obtain the continuous casting slab high-temperature anti-oxidation coating III of the present invention. The paint is sprayed on the surface of the Q345B cast slab at 900°C to form a layer of off-white protective coating. After heat treatment, the oxide scale protected by the coating is significantly thinner than that without coating protection, and the oxidation burning rate is reduced by more than 70%, and the coating can be peeled off naturally. After peeling off, the surface of the substrate is uniform and smooth without residue .

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Abstract

The invention relates to a preparation process of continuous casting slab high-temperature oxidation resistant coatings, which is characterized in that less than 120 meshes of powder, reductant containing carbon, inorganic binders, surfactants, suspending agents and the like with the compositions such as 25-55 wt% SiO2, 10-20 wt% Al203, 11-23 wt% MgO and the like are respectively grinded and mixed evenly, then water is used to be mixed and stirred sufficiently evenly, and finally the density of the coatings are adjusted within 1200-1500 kg / m3. The coatings can not only be sprayed onto continuous casting slabs at normal temperature, but also be sprayed onto high-temperature casting slabs, form continuous whole protective coating layers under the action of high temperature, effectively reduce temperature drop of the casting slabs and oxidation burning loss in even heating process of a heating furnace without changing original performance of matrixes, and effectively decrease dilution of alloying elements on the surfaces of the casting slabs. After the casting slabs are out of the heating furnace, natural spalling capability of the coating layers is strong, and oxidation matrixes of the casting slabs are smooth. Raw materials of the oxidation resistant coatings are easy to be obtained, and the coatings have low cost and simple preparation process and are adaptable to oxidation resistance for various steels when being heated at 700-1300 DEG C / 2-8 hours.

Description

technical field [0001] The invention belongs to the field of coatings, and in particular relates to high-temperature anti-oxidation coatings for continuous casting slabs and a preparation process thereof. Background technique [0002] Energy saving and emission reduction is the goal pursued by all industries in the world, especially for iron and steel enterprises with high energy consumption. The continuous casting slab needs to be heated in the heating furnace at a high temperature of about 1200°C and for a long time before hot rolling. This process makes the oxidative burning loss on the surface of the slab very serious, and the oxidation burning loss rate reaches 0.5-2.5%. In order to reduce the oxidative burning loss of the slab and reduce the surface temperature drop of the slab during transportation, an anti-oxidation coating is applied to the surface of the high-temperature slab to reduce the temperature drop of the slab and increase the yield and improve the steel qu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D1/00C21D1/68
Inventor 米振莉王岩左碧强赵征志苏岚陈银莉赵爱民唐荻孙蓟泉
Owner UNIV OF SCI & TECH BEIJING
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