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Uniform carbon-coated mesoporous silicon carbon negative electrode material, preparation method and application

The invention relates to a uniform carbon-coated mesoporous silicon carbon negative electrode material and a preparation method and application thereof.The preparation method comprises the steps that a product obtained after pyrolysis and carbonization of a biomass carbon source is subjected to alkali activation treatment, acid pickling, drying, smashing, passivation, water washing and drying are conducted to obtain a mesoporous carbon matrix, nanometer silicon particles are deposited in pores of the mesoporous carbon matrix, and the uniform carbon-coated mesoporous silicon carbon negative electrode material is obtained. Then selecting a low-temperature carbonization material and polyethylene glycol to perform pre-carbonization and complete carbonization treatment on the mesoporous silicon carbon material to obtain a carbon coating layer, and finally obtaining the uniform carbon-coated mesoporous silicon carbon negative electrode material. When the uniform carbon-coated mesoporous silicon carbon negative electrode material is applied to a lithium battery, the mesoporous skeleton can effectively inhibit volume expansion of silicon in a battery circulation process, and the uniform carbon-coated layer can effectively reduce the risk of direct contact between the negative electrode material and an electrolyte, so that a stable SE I film is formed to reduce the occurrence of side reactions; and the first coulombic efficiency and the cycle performance of the battery are further improved.
Owner:LIYANG TIANMU PILOT BATTERY MATERIAL TECH CO LTD