27 results about "Titanium hydroxide" patented technology

Provided here are methods for producing a shaped metal-supported catalyst. One such method includes the steps of mixing a support hydroxide with an aqueous mixture of an active metal compound to form a malleable mixture of an active metal incorporated support hydroxide, passing the malleable mixture through a molding device to produce a shaped metal-supported wet catalyst; and drying and calcining the shaped metal-supported wet catalyst. The support hydroxide contains one or more of aluminium hydroxide, silica hydroxide, zirconia hydroxide, cerium hydroxide, titanium hydroxide, lanthanum hydroxide, gallium hydroxide, or niobium hydroxide. The active metal compound can be one or more of vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, technetium, and rhenium.

The invention provides diaphragm coating slurry, a composite diaphragm, a preparation method of the composite diaphragm and a lithium ion battery containing the composite diaphragm. The composite diaphragm comprises a porous diaphragm base material and a coating located on one side or two sides of the porous diaphragm base material, the coating comprises an active adsorption material, a coupling agent, a binding agent and a dispersing agent, the active adsorption material is selected from one or more of gamma-aluminum oxide, pseudo-boehmite, titanium hydroxide and a molecular sieve, and the coupling agent is selected from one or more of a coupling agent, a binding agent and a dispersing agent. The porosity of the composite diaphragm is greater than or equal to 40%. The composite diaphragm disclosed by the invention can greatly reduce the gas concentration in the battery, and meanwhile, the thermal stability, the electrolyte wettability and the porosity of the diaphragm are also improved to a certain extent.

The application provides a lithium titanium aluminum phosphate and a preparation method and application thereof, and belongs to the field of solid-state batteries, wherein the preparation method of the lithium titanium aluminum phosphate comprises the following steps: adding a titanium source, a lithium source, an aluminum source and a phosphorus source into a solvent to obtain a mixed solution; the mixed solution is heated to a first preset temperature, an oxidizing agent is added, then the temperature is increased to a second preset temperature, and an initial product is obtained through reaction; the initial product is sequentially subjected to filtration, washing and drying treatment to obtain an intermediate product; the intermediate product is mixed with an auxiliary agent, and calcination treatment is performed to obtain the lithium titanium aluminum phosphate. Through optimization of raw material ratio and treatment process, the application utilizes oxidation of the oxidizing agent and hydrolysis of the titanium source to generate high-activity titanium hydroxide colloid, promotes phase conversion and formation of crystal nucleus of the lithium titanium aluminum phosphate, and can effectively control primary particle size and morphology. Through introduction of the auxiliary agent, the application prevents particle growth and fusion during the calcination process, improves the crystallinity of the lithium titanium aluminum phosphate, reduces particle size, and improves ion conductivity.

The present invention provides a method for increasing the surface adhesion of molecular sieve particles, and an oxide layer and / or a hydroxide layer are coated on the outer surface of a Cu-SSZ-13 molecular sieve by an atomic layer deposition method; the oxide layer includes one or more of silicon oxide, aluminum oxide, titanium oxide, zirconium oxide and rare earth oxide; the hydroxide layer includes one or more of silicon hydroxide, aluminum hydroxide, titanium hydroxide, zirconium hydroxide and rare earth hydroxide. The present invention is aimed at the disadvantages that the molecular sieve catalyst has low surface adhesion and is easy to fall off after coating, and the molecular sieve is coated with an oxide layer and / or a hydroxide layer to improve the surface adhesion of the molecular sieve. It does not affect the high activity temperature window of the molecular sieve catalyst, reduces the risk of falling of the molecular sieve catalyst, and improves the service life of the catalyst, which has good application value.

This invention provides a manufacturing method that allows for the production of a single phase of rutile-type titanium dioxide even under manufacturing conditions where the molar ratio of Ti to Sn (Ti / Sn) is high (i.e., the Sn content is low). [Solution] A method for producing rutile-type titanium dioxide comprising the following steps. (1) A gelatinization step in which hydrogen peroxide is added to an aqueous dispersion of titanium hydroxide gel, and the molar ratio of Ti to hydrogen peroxide (H2O2 / Ti) is adjusted to 15 or more to obtain a gelatinization solution. (2) A tin addition step in which a tin source is added to the gelatinizing solution and the molar ratio of Ti to Sn (Ti / Sn) is adjusted to 16 to 80 in order to obtain a hydrothermal treatment precursor. (3) Crystallization step of hydrothermally treating the hydrothermal treatment precursor to obtain rutile-type titanium oxide

The present application relates to the technical field of dielectric ceramic powder preparation, and particularly relates to a multilayer ceramic capacitor and a method for preparing high-performance nano-barium titanate powder used for the multilayer ceramic capacitor, the method comprising the following steps: high-purity titanium hydroxide precursor and solid-state barium source are mixed under the condition of deep cold medium at low temperature, so as to form an amorphous composite precursor with high reactivity, and finally, the nano-barium titanate powder is generated through a hydrothermal synthesis reaction. The present application realizes the forced mixing of the titanium hydroxide precursor and the solid-state barium source at the solid state through the low-temperature cryogenic grinding, so as to physically ensure that the Ba / Ti ratio is highly consistent in each micro area, and the problem of the out-of-control stoichiometric ratio is solved from the source. Meanwhile, the high activation of the precursor shortens the hydrothermal reaction time, greatly reduces the calcination temperature, effectively inhibits the abnormal growth of the crystal grains, and makes the product particle size distribution narrower and the performance better.

The disclosed method for manufacturing barium titanate particles comprises: a process (i) for preparing titanium hydroxide by simultaneously neutralizing an aqueous titanium halide solution and an alkaline substance under predetermined conditions; a process (ii) for preparing a slurry of the titanium hydroxide; a process (iii) for preparing a titanium compound by adding a predetermined amount of inorganic acid and an organic acid to the slurry and then maintaining the slurry at a temperature in the range of 40 to 90°C; and a process (iv) for synthesizing barium titanate particles by hydrothermal synthesis using a raw material containing the titanium compound. The titanium compound contains amorphous titanium hydroxide and anatase-type titanium dioxide. The specific surface area of ​​the titanium compound is 250 m² / g or more.

A preparation method of a digestion solution for corrosion of tantalum-niobium-containing alloy waste comprises the following synthesis steps: taking a certain amount of halogenated iron salt, adding the halogenated iron salt into dilute halogen acid under high-speed stirring until the halogenated iron salt is completely dissolved, then adding hexafluorotitanic acid and titanyl sulfate solids according to a certain proportion to be completely dissolved, then adding excessive newly-prepared titanium hydroxide to react for a period of time, and finally adding a catalyst to react for a period of time; and filtering and adding graphite powder for later use. The decomposition method comprises the following steps: shearing and crushing the tantalum-niobium alloy-containing waste material to obtain the result; and adding the digestion solution into a small section with the diameter of 50 mm, heating to 40-70 DEG C, dropwise adding hydrogen peroxide, cooling the discharged gas, and enabling the condensed water to flow back to the system. Filtering after sampling and detecting that no metal exists, adjusting the filtrate to an initial state after analyzing components, adding a proper amount of sulfuric acid and hydrofluoric acid into a filter cake to adjust and dissolve until the filter cake meets the extraction requirement, and entering an extraction process line.

The invention relates to the technical field of dielectric ceramic powder preparation processes, in particular to a multilayer ceramic capacitor and a method for preparing high-performance nano barium titanate powder for the multilayer ceramic capacitor. The method comprises the following steps: performing low-temperature freezing grinding on a high-purity titanium hydroxide precursor and a solid barium source in the presence of a cryogenic medium according to a stoichiometric ratio so as to form an amorphous composite precursor with high reaction activity, and finally performing hydrothermal synthesis reaction to generate the nano barium titanate powder. According to the method, the titanium hydroxide precursor and the solid barium source are forcibly mixed in a solid state through low-temperature freezing and grinding, so that it is physically guaranteed that the Ba / Ti ratio is highly consistent in each micro-area, and the problem that the stoichiometric ratio is out of control is solved from the source. Meanwhile, due to the high activation of the precursor, the hydrothermal reaction time is shortened, the calcination temperature is greatly reduced, the abnormal growth of crystal grains is effectively inhibited, the particle size distribution of the product is narrower, and the performance is better.

Disclosed is a method for producing barium titanate particles, the method including: a step (i) for preparing titanium hydroxide by simultaneously neutralizing an aqueous solution of titanium halide and an alkaline substance under specific conditions; a step (ii) for preparing a slurry of the titanium hydroxide; a step (iii) for preparing a titanium compound by adding a predetermined amount of an inorganic acid and a predetermined amount of an organic acid to the slurry and subsequently holding the resulting slurry at a temperature within the range of 40-90°C; and a step (iv) for synthesizing barium titanate particles by means of hydrothermal synthesis using a starting material that contains the titanium compound. The titanium compound contains amorphous titanium hydroxide and anatase-type titanium dioxide. The specific surface area of the titanium compound is 250 m2 / g or more.

The invention provides lithium titanium aluminum phosphate and a preparation method and application thereof, and belongs to the field of solid-state batteries, and the preparation method of the lithium titanium aluminum phosphate comprises the following steps: adding a titanium source, a lithium source, an aluminum source and a phosphorus source into a solvent to obtain a mixed solution; raising the temperature of the mixed solution to a first preset temperature, adding an oxidizing agent, then raising the temperature to a second preset temperature, and carrying out a reaction to obtain a head product; sequentially filtering, washing and drying the primary product to obtain an intermediate product; and mixing the intermediate product with an auxiliary agent, and calcining to obtain the lithium titanium aluminum phosphate. By optimizing the raw material ratio and the treatment process, high-activity titanium hydroxide colloid is generated through oxidizing of an oxidizing agent and hydrolysis of a titanium source, transformation of a titanium aluminum lithium phosphate phase and formation of crystal nucleuses are promoted, meanwhile, the primary particle size and morphology can be effectively controlled, growth and fusion of particles are hindered through decomposition in the calcination process by introducing an auxiliary agent, and the stability of the product is improved. The crystallinity of the lithium titanium aluminum phosphate is improved, the particle size is reduced, and the ionic conductivity is improved.

The invention discloses a preparation method of a carbon fiber solid base catalyst for preparing bosylamine. The preparation method comprises the following steps: S1, dissolving a magnesium source, an aluminum source, and a titanium source in deionized water; ultrasonically dispersing carbon fibers in the deionized water, and allowing the carbon fibers to adsorb aluminum ions, magnesium ions, and titanium ions on the surface of the carbon fibers; S2, continuously introducing ammonia gas into the deionized water dispersion system obtained in S1 until precipitation is complete, allowing magnesium hydroxide, aluminum hydroxide, and titanium hydroxide to grow on the surface of the carbon fibers, and filtering the precipitate; S3, calcining the precipitate obtained in S2 to obtain carbon fiber-supported MgO-Al2O3-TiO2; and applying the structurally stable solid base catalyst with an adsorption effect prepared by the invention to the preparation of bosylamine, thereby reducing the introduction of cations and cooperating with a double solvent reaction to reduce the chance of boric acid and the dehydration connection of hydroxyl groups of the product, thereby improving the purity and yield of bosylamine.

The invention discloses a supported noble metal catalyst with high-density surface hydroxyl groups as well as a preparation method and application of the supported noble metal catalyst. The preparation method comprises the following steps: by taking titanium hydroxide and ammonium sulfate as starting materials, preparing a titanium dioxide carrier with an exposed {100} crystal face through a hydrothermal method; the preparation method comprises the following steps: dispersing a titanium dioxide carrier with exposed {100} crystal faces, noble metal salt and / or noble metal acid and alkali metal hydroxide in water to obtain a mixed solution, and carrying out stirring dipping, solvent evaporation drying, drying and reduction heat treatment to obtain the supported noble metal catalyst with high-density surface hydroxyl groups. According to the preparation method, raw materials are easy to obtain, operation is easy and convenient, mass production is facilitated, the prepared catalyst has high intrinsic performance and rich surface hydroxyl groups, and the comprehensive catalytic performance of the catalyst is superior to that of most reported noble metal catalysts.

The invention relates to substituted Ti and N co-doped manganese dioxide prepared based on a solid phase method and application thereof, and the preparation method comprises the following steps: (1) dissolving a soluble titanium salt in an aqueous solution containing a divalent manganese salt, and adding a sodium carbonate solution into the solution while stirring until a mixed precipitate (Ti (HO) 4 / MnCO3) of titanium hydroxide and manganese carbonate is generated; (2) adding KMnO4 powder into the prepared Ti (HO) 4 / MnCO3 precipitate, fully grinding, putting the ground mixture into a muffle furnace, and carrying out heat treatment; (3) collecting the powder in the step (2), cleaning the powder with deionized water, placing the powder in a KOH solution for ultrasonic treatment, and washing and drying the treated powder to obtain Ti-doped manganese dioxide (Ti-MnO2); (4) adding NH2Na powder into the Ti-MnO2 powder, fully grinding, putting the ground mixture into a muffle furnace, and carrying out heat treatment; and (5) collecting the powder subjected to heat treatment in the step (4), and washing and drying to obtain the alternative Ti and N co-doped manganese dioxide (Ti / N-MnO2).

The adhesive film for circuit connection contains conductive particles and includes a region A containing a cationic polymerizable compound, a thermal cationic polymerization initiator, and an ion scavenger in the thickness direction of the film. The cationic polymerizable compound contains an epoxy compound, the thermal cationic polymerization initiator contains an anilinium salt, and the ion scavenger contains at least one metal compound selected from the group consisting of aluminum hydroxide, aluminum oxide, magnesium hydroxide, magnesium oxide, zirconium hydroxide, zirconium oxide, bismuth hydroxide, bismuth oxide, calcium hydroxide, calcium oxide, tin hydroxide, tin oxide, manganese hydroxide, manganese oxide, antimony hydroxide, antimony oxide, silicon hydroxide, silicon oxide, titanium hydroxide, and titanium oxide.

The present invention relates to barium strontium titanate, and to a barium strontium titanate fine particle powder characterized in that the average primary particle diameter of primary particles is 50 nm or less, and the difference between the lattice constant and the theoretical lattice constant is # imgabs 0 # or more and # imgabs 1 # or less. Furthermore, the present invention relates to a method for producing a barium strontium titanate fine particle powder, which is characterized by mixing a titanium raw material with an aqueous alkaline solution, obtaining a hydrated titanium hydroxide slurry by a neutralization reaction, washing with water, heating, adding to a mixed solution of an aqueous strontium solution and an aqueous barium solution, carrying out a wet reaction in a temperature range of 100-300 DEG C, and then washing with water and drying.

The invention relates to a two-dimensional titanium hydroxide nanosheet as well as a preparation method and application thereof. The two-dimensional titanium hydroxide nanosheet is prepared by combining an alkali-assisted hydrolysis method with an ultrasonic-assisted liquid phase crushing method. The transverse size of the two-dimensional titanium hydroxide nanosheet is 10-200nm, and the thickness of the two-dimensional titanium hydroxide nanosheet is less than 10nm. The two-dimensional titanium hydroxide nanosheet prepared by the invention has better catalytic oxidation resistance, biocompatibility and stability, and can be widely applied to the fields of catalysis and biomedicine.

The invention relates to the field of polymer waterproofing, in particular to a weather-resistant waterproof coiled material for metal protection and a preparation process of the weather-resistant waterproof coiled material. The invention discloses a preparation process of a weather-resistant waterproof roll for metal protection. The preparation process comprises the following steps: preparing a flame-retardant additive; preparing a modified molybdenum disulfide nanosheet; preparing an anti-ultraviolet additive; and preparing the waterproof coiled material. The preparation method comprises the following steps: firstly, adding a sodium hydroxide solution into a titanium tetrachloride solution to generate a titanium hydroxide precursor, then adding a halloysite nanotube dispersion liquid, heating and stirring for reaction to prepare a nano composite material, then preparing dealkalized lignin into a nano sheet structure, and then tightly combining the nano sheet structure with the nano composite material under a hydrothermal condition to obtain the titanium dioxide / halloysite composite material. After the stable anti-ultraviolet additive is fused and mixed with polyethylene and other raw materials to prepare the waterproof coiled material, a continuous ultraviolet protection network can be formed, migration is reduced, and the ultraviolet aging resistance of the waterproof coiled material is remarkably improved.

The application discloses a preparation method of titanium-doped and high-hydrated vanadium magnetite monocrystal under high temperature and high pressure. Solid triangular siderite crystal, solid bisacetylacetonate vanadium (IV) powder, liquid tetraisopropoxy titanium (IV), solid oxalic acid powder, solid alpha-phase goethite powder, solid titanium hydroxide powder and liquid dilute nitric acid are used as starting raw materials to prepare a cylindrical vanadium magnetite sample; alpha-phase goethite powder and titanium hydroxide powder with a weight ratio of 4:1 are used to prepare a water source sheet; the water source sheet is placed at two ends of the cylindrical vanadium magnetite sample and then is placed into an inner sleeve of a double-capsule structure sample bin, and finally high temperature and high pressure reaction is carried out to obtain the vanadium magnetite monocrystal. The application solves the blank of the preparation technology of titanium-doped and high-hydrated vanadium magnetite large-grain monocrystal under the current high temperature and high pressure condition, and obtains experimental samples of titanium-doped and high-hydrated vanadium magnetite large-grain monocrystal.

The disclosed method for manufacturing barium titanate particles includes: step (i), preparing titanium hydroxide by simultaneously neutralizing an aqueous solution of titanium halide and an alkaline substance under specified conditions; step (ii), preparing a slurry of the aforementioned titanium hydroxide; step (iii), preparing a titanium compound by adding specified amounts of inorganic acid and organic acid to the aforementioned slurry and maintaining the slurry at a temperature in the range of 40–90°C; and step (iv), synthesizing barium titanate particles by hydrothermal synthesis using raw materials containing the aforementioned titanium compound. The titanium compound contains amorphous titanium hydroxide and anatase titanium dioxide. The specific surface area of ​​the titanium compound is 250 m² / s. 2 / g or more.

The present application relates to the technical field of surface treatment, in particular to a preparation method of titanium oxychloride solution for cadmium-titanium plating test. In order to solve the technical problem that it is difficult to effectively prepare cadmium-titanium plating bath liquid meeting the requirements of navigation marks in the research and development stage, the present application uses industrial-grade titanium oxysulfate as raw material, adopts semi-quantitative analysis, and conveniently and effectively prepares the titanium oxychloride solution required in the research stage without complicated calibration process. By adjusting the addition amount of hydrochloric acid and the dissolution time of titanium hydroxide precipitation, the problem of easy turbidity of the plating bath liquid after adding the titanium oxychloride solution into the cadmium-titanium plating bath liquid is solved, thereby improving the stability of the cadmium-titanium plating bath liquid. Based on the preparation method, the difficulty of researchers in the development stage of cadmium-titanium plating technology is reduced, and the foundation for the effective development of subsequent electroplating process and electroplating parameter research is laid.

The disclosed method for producing barium titanate particles includes the steps of: (i) preparing titanium hydroxide by simultaneously neutralizing an aqueous solution of titanium halide and an alkaline substance under predetermined conditions; (ii) preparing a slurry of the titanium hydroxide; (iii) preparing a titanium compound by adding predetermined amounts of inorganic and organic acids to the slurry and then maintaining the slurry at a temperature in the range of 40 to 90°C; and (iv) synthesizing barium titanate particles by hydrothermal synthesis using raw materials containing the titanium compound. The titanium compound contains amorphous titanium hydroxide and anatase titanium dioxide. The specific surface area of the titanium compound is 250 m. 2 / g or more.

The invention discloses a porous composite photocatalytic material and a preparation method thereof, and belongs to the technical field of photocatalytic materials.The preparation method comprises the steps that a titanium source is added into water to obtain a titanium-containing aqueous solution, and an alkaline solution is added for a reaction to obtain a titanium hydroxide colloidal solution; adding an organic acid stabilizer into the titanium hydroxide colloidal solution for reaction to prepare a titanium hydroxide solid, repeatedly washing with deionized water, dispersing the titanium hydroxide solid into the deionized water and fully stirring, adding microfibers with a three-dimensional network structure and a hydrogen peroxide solution, heating for reaction, and then cooling to 4-6 DEG C through heat exchange to obtain the titanium hydroxide / microfiber composite material. And drying in vacuum, and calcining to obtain the titanium dioxide-loaded photocatalytic material. According to the preparation method disclosed by the invention, loading can be realized while titanium dioxide is generated, the adhesive force of titanium dioxide is greatly enhanced, the distribution uniformity of titanium dioxide is good, and the catalytic performance is effectively improved while raw materials are saved.

This method for producing a positive electrode active material for secondary batteries is characterized by including: an oxidation step of adding at least one hydroxide selected from the group consisting of aluminum hydroxide, strontium hydroxide, titanium hydroxide, bismuth hydroxide, zirconium hydroxide, and barium hydroxide to an Ni-containing compound, and performing oxidation treatment by heating the mixture; a firing step of mixing an oxide obtained in the oxidation step with an Li-containing compound, and firing the mixture; a water-washing step of mixing a fired product obtained in the firing step with water or an aqueous solution, and washing the mixture with water; and a drying step of drying the wet powder obtained in the water-washing step to obtain a lithium transition metal composite oxide, wherein the heating temperature in the oxidation step is 250°C-650°C inclusive.

The present invention provides a titanium dioxide dispersion, a method for producing the same, a titanium dioxide film, and a titanium dioxide electron transport layer, all of which have a low environmental impact and can reduce manufacturing costs. [Solution] The present invention provides a method for producing a titanium dioxide dispersion, comprising: a first step of obtaining titanium hydroxide by hydrolysis of a titanium compound; a second step of preparing a peroxotitanic acid complex solution with the titanium hydroxide using hydrogen peroxide and ammonia; a third step of adding a primary hydroxycarboxylic acid to the peroxotitanic acid complex solution to obtain a water-soluble titanium complex solution; and a fourth step of hydrothermally treating the water-soluble titanium complex solution to obtain a primary titanium dioxide dispersion.

A system (100) for synthesizing Ti 1-x Fe x O 2-δ -Photoelectrodes co-sensitized with the dye CdS QDs-N719, comprising: i) a nanoparticle synthesis apparatus (102) configured to synthesize Ti 1-x Fe x O 2-δ -To synthesize nanoparticles with an x-value in the range of 0.008 to 0.024, wherein the synthesis arrangement comprises: a) a primary mixing chamber (104) configured to mix titanium isopropoxide (TTIP) with anhydrous isopropanol and sodium dodecyl sulfate (SDS); b) a doping addition unit (106) configured to add a stoichiometric amount of an iron(III) nitrate nonahydrate solution in isopropanol to the primary mixing chamber (104); c) a pH control module (108) configured to add aqueous ammonia dropwise to maintain the pH at 9.00 ±0.10; d) a stirring module (110) connected to the primary mixing chamber (104) and configured to maintain continuous stirring for a certain period of time; e) a collection unit (112) connected to the primary mixing chamber (104) and configured to filter and collect white titanium hydroxide precipitate; f) a drying and calcining unit (114) configured to dry and calcine the precipitation at 450°C for 2 hours; ii) a photoelectrode manufacturing arrangement (200) comprising the following: a) a paste manufacturing unit (202) configured to Ti 1-x Fe x O 2-δ -Disperse nanoparticles sequentially in DMF and acetonitrile solvents; b) a coating module (204) configured to apply the paste evenly onto an FTO substrate to produce films which are then sintered; c) a sensitization arrangement (206) configured to sensitize the prepared sintered films successively with CdS quantum dots and N719 dye, together with ZnS deposition, wherein the sensitization arrangement first deposits CdS-QDs onto the films, then deposits a ZnS layer, and then deposits N719 dyes onto the surface of the modified Ti 1-x Fe x O2- δ -QDs films depositing ZnS particles; and d) a washing unit (208) comprising a detergent containing an equimolar mixture of tert-butyl alcohol and acetonitrile for washing the prepared electrodes to obtain uniform photoelectrodes.

A method of treating a leaching solution derived from a black mass from spent lithium-ion batteries comprising setting pH of the leaching solution to about pH 1.2 to 2.5, adding iron powder to induce copper cementation, adding lime after copper cementation, and after adding lime, transiting pH of the leaching solution to about pH 6 to extract calcium fluoride, titanium hydroxide, aluminium hydroxide, iron hydroxide, and iron phosphate. A black mass recycling system comprising an impurity removal reactor configured to receive a sodium hydroxide feed, an iron powder feed, and a lime feed.