1033 results about "Nanofibrous membrane" patented technology

The invention relates to the technical field of sewage treatment, in particular to a sewage treatment control process based on dynamic regulation and control of aeration and carbon source addition, which comprises the following steps: acquiring microbial metabolism heat change data in real time; biochemical treatment: monitoring the dielectric constant of a water body and the Reynolds number of sewage flow in real time, and constructing a multi-parameter coupling regulation and control model and dynamically regulating and controlling the aeration rate in combination with microbial metabolism heat change data obtained in the pretreatment step; accurately adding the carbon source according to a calculation result of the carbon source demand prediction model; sewage subjected to biochemical treatment is subjected to ultrafiltration through a nanofiber membrane and then subjected to combined disinfection treatment through ultraviolet rays and ozone, treatment parameters are regulated and controlled in real time according to the membrane flux attenuation trend in the treatment process, and dynamic and accurate control over sewage treatment is achieved. According to the method, the problem of energy consumption waste caused by excessive aeration or low degradation efficiency caused by insufficient aeration in a traditional process is solved, and accurate matching of dissolved oxygen supply and microbial requirements is realized.

The invention belongs to the technical field of biomedical engineering, and particularly relates to a biological rotator cuff patch with a double-gradient structure and a preparation method of the biological rotator cuff patch. The preparation method comprises the following steps: carrying out electrostatic spinning on a spinning solution, controlling the rotating speed of a receiving roller to increase at a constant speed in the electrostatic spinning process, and obtaining a nanofiber membrane after electrostatic spinning; l-polylactic acid and D-polylactic acid are simultaneously dissolved in the spinning solution; the minimum value of the rotating speed of the receiving roller is 100-500 rpm, and the maximum value of the rotating speed of the receiving roller is 3000-4000 rpm. The finally prepared biological rotator cuff patch with the double-gradient structure presents an orientation degree gradient and a piezoelectric effect gradient at the same time on the thickness scale, and has mechanical supporting capacity and biocompatibility, and bionic healing promotion of the patch with the gradient structure is achieved.

The invention discloses a phase change energy storage waterborne polyurethane nanofiber membrane and a preparation method thereof. Lignin-based phase change microcapsules are prepared by combining ultraviolet crosslinking with lignin shell packaging, and then the nanofiber membrane containing the phase change microcapsules is prepared through an electrostatic spinning technology. And finally, constructing the waterborne polyurethane phase change fiber membrane with asymmetric wettability through a low-temperature plasma technology. According to the invention, lignin is self-assembled to form nanoparticles, and ultraviolet light induces free radical polymerization to form a polymer film, so that the packaging capability of the phase change material is improved. The phase change microcapsule prepared by the method is high in packaging efficiency and excellent in phase change performance, the preparation process is green and environment-friendly, the technological operation is simple, the temperature of the prepared phase change energy storage waterborne polyurethane nanofiber membrane conforms to the comfortable temperature range of a human body, and the phase change energy storage waterborne polyurethane nanofiber membrane has excellent temperature regulation, waterproof and moisture permeable performance and is suitable for being used in the field of water treatment. Good application prospects are realized in the field of functional textiles with functions of intelligent temperature regulation, water resistance and air permeability and the like.

The invention discloses a C5F10O mixed gas decomposition component adsorption material as well as a preparation method and application thereof. The adsorption material is a metal organic framework / nanofiber composite membrane which is prepared by uniformly dispersing a metal organic framework material on a nanofiber membrane obtained by an electrostatic spinning technology through a spraying doping method and is used for adsorbing decomposition components of C5F10O mixed gas. According to the adsorption material provided by the invention, through mutual cooperation of the metal organic framework material and the porous nanofiber membrane base material, a formed composite membrane has a larger specific surface area and more metal active sites, adsorption of gas molecules is promoted, permeation and diffusion of the gas molecules are also facilitated, and the adsorption efficiency is improved. Therefore, the gas sensitivity and the adsorption effect of the adsorption material are remarkably improved.

The invention discloses a high-entropy nanoparticle catalytic material with a metal atom shell structure and a preparation method of the high-entropy nanoparticle catalytic material, and belongs to the technical field of preparation of catalytic materials. The preparation method comprises the following steps: dispersing a metal salt and a nanofiber precursor in an organic solvent, and carrying out electrostatic spinning to obtain a nanofiber membrane; and then calcining and pre-oxidizing the nanofiber membrane, and then carbonizing and calcining to obtain the nanofiber membrane. Wherein the selection principle of the metal salt is as follows: (n-1)-(n-2) metals are selected as an alloy substrate, and the sum of the mixing enthalpy of elements of the alloy substrate is not greater than-5kJ mol <-1 >; one or two metal elements serve as a precipitated phase, and the sum of the mixing enthalpy of the metal elements of the precipitated phase and the elements of the alloy substrate is larger than 20 kJ mol <-1 >; the high-entropy nanoparticle catalytic material obtained by the method shows relatively high catalytic activity and stability, and the method has wide universality.

The invention belongs to the technical field of nano porous materials, discloses a high-strength and low-thermal-conductivity SiC-TiO2 nanofiber aerogel and a preparation method thereof, and aims to solve the problems of insufficient structural stability, shear strength and high-temperature thermal conductivity of traditional ceramic aerogel. TiO2 nanorods are introduced onto a SiC nanofiber membrane by adopting an in-situ growth technology, and the high-strength and low-thermal-conductivity SiC-TiO2 nanofiber aerogel is prepared. And constructing the SiC nano composite fiber membrane into the layered porous ceramic nanofiber aerogel with a multilevel structure by combining a layer-by-layer stacking method with a directional freezing casting technology. TiO2 nanorods growing on the surface of the SiC fiber in situ serve as a secondary structure, so that the overall mechanical performance of the material is enhanced; the TiO2 nanorods have specific high infrared light reflection and scattering capabilities, so that the transmittance of the aerogel material to radiation is reduced, and the thermal radiation conduction in a high-temperature environment is effectively reduced. In addition, a silica sol binder is introduced between layers of the aerogel multilevel structure, stable bonding points are formed between fibers after calcination, and the mechanical stability is improved.

The invention belongs to the technical field of carbon material fibers, and discloses a preparation method of a carbon nanofiber reinforced carbon material fiber fabric, which comprises the following steps: fixing a weakly twisted carbon material fiber tow on an electrostatic spinning nano yarn machine; forming a carbon nanofiber membrane by utilizing electrostatic spinning, uniformly wrapping the carbon nanofiber membrane on a carbon material fiber bundle subjected to weak twisting, then rolling into a shaft, then weaving the rolled fibers into a fabric, and sequentially performing hot pressing and carbonization treatment on the fabric to prepare a carbon nanofiber reinforced carbon material fiber fabric; the weak twisting means that the twisting degree is 5-13 twists per meter. According to the invention, the carbon nanofiber is coated on the carbon material fiber, so that the interface bonding strength between the nanofiber and the carbon material fiber is improved, and then the fabric prepared from the carbon nanofiber is subjected to hot pressing and carbonization treatment, so that the mechanical property, the electrical conductivity and the heat-conducting property of the fabric are further improved; therefore, the composite material has a huge application prospect in the fields of high-performance composite materials, intelligent textiles and the like.

The invention relates to the technical field of medical instruments, in particular to an intelligent wound nursing system which comprises a dressing body, and the dressing body comprises a skin-friendly layer, a functional layer and a protective layer. A monitoring module, a control module, a medicine leading-in module, a flexible circuit layer and an alarm module are integrated in the functional layer. According to the method, the infection misdiagnosis rate is reduced through multi-sensor fusion monitoring and a preset infection risk threshold algorithm; according to the design, the micro-fluidic chip and the biological probe are integrated in the percolate component sensor, so that the infection detection rate is increased; a temperature-sensitive hydrogel micro-valve array and nanofiber membrane slow release technology is adopted, so that medicine waste or poor treatment effect is reduced; through a multi-sensor data fusion algorithm, the detection accuracy is improved; the layout of the micro-valve array and the annularly distributed independent medicine storage cavities is adopted, so that the release error is reduced; through the ultrathin flexible framework, the snakelike wiring circuit and flip chip packaging, circuit breakage is avoided, and the clinical failure rate is reduced.

The present invention relates to the technical field of flexible electronics, and relates to a breathable and stretchable circuit capable of being activated by imprinting, and a preparation method therefor and a use thereof. The preparation method for the breathable and stretchable circuit capable of being activated by imprinting in the present invention comprises the following steps: dissolving a thermoplastic polymer in a solvent, adding liquid metal particles, and mixing and dispersing to obtain a mixed solution; carrying out electrospinning on the obtained mixed solution to prepare a nanofiber membrane; and using a stamping model having a circuit pattern to stamp the obtained nanofiber membrane so as to obtain the breathable and stretchable circuit capable of being activated by imprinting. The present invention ensures the breathability and the stretchability by using the nanofiber membrane. The liquid metal particles match fibers in diameter, and therefore, liquid metal in nanofibers can be overflowed by means of imprinting to form a conductive path, achieving high-precision preparation of circuits.

The invention discloses a high-air-permeability humidity display film based on optical interference and a preparation process of the high-air-permeability humidity display film. Comprising a substrate layer, a humidity response layer, a middle layer and a hydrophobic layer, wherein the substrate layer is made of a transparent material; a plurality of breathable micropores are formed in the substrate layer; the humidity response layer is a thin film layer which is made of a humidity sensitive material and has the thickness of 50-100 [mu] m, micropores are formed in the humidity response layer, and the pore diameter of the micropores is 0.5-2 [mu] m; the middle layer is a nanofiber membrane, and the fiber diameter of nanofiber is controlled to be 100-300 nm; the density of the middle layers in the length direction is in gradient change so as to control the air permeability of the humidity response layers corresponding to the middle layers with different densities; the hydrophobic layer is made of a transparent and breathable material and provides a good protection effect for the humidity display film. According to the invention, the hydrophilic microporous structure material is adopted, the humidity can be rapidly conducted to the humidity response layer through the multilayer design, instant color change is generated, and the humidity indication effect is more sensitive.

The invention provides a flexible electromagnetic shielding film and a preparation method thereof. The preparation method comprises the following steps: mixing metal gallium and metal indium in a preset proportion to prepare a gallium-indium alloy; the preparation method comprises the following steps: putting a preset mass of gallium-indium alloy into an isopropanol solution, and treating through an ultrasonic cell disruption system to obtain a liquid metal particle suspension; stirring magnetic functional nanoparticles, an electrostatic spinning high-molecular elastomer and a solvent at normal temperature for a preset time to obtain an electrostatic spinning homogeneous solution; treating the electrostatic spinning homogeneous solution by adopting an electrostatic spinning process to obtain a magnetic nanofiber membrane; and spraying the liquid metal particle suspension onto the magnetic nanofiber membrane by adopting an electrostatic spraying process to obtain the flexible electromagnetic shielding film. According to the flexible electromagnetic shielding film and the preparation method thereof, the problem that the stability of an existing shielding material is reduced under the stretching effect can be solved.

The invention relates to the field of flexible sensing, and discloses a flexible dual-mode sensor with a foot arch and motion detection function, the flexible dual-mode sensor comprises an upper substrate, a lower substrate, an electrode layer, a conductive pin, a PVDF doped BTO-NPs nanofiber film and a PVDF doped ionic salt solution nanofiber film, the upper substrate and the lower substrate are polyimide films (PI), the electrode layer is an immersion gold (Au) pad, and the conductive pin is arranged on the electrode layer. The conductive pin is formed by fixing a copper wire on the electrode plate through silver paste, the nanofiber membrane is obtained by PVDF doped BTO-NPs and PVDF doped ionic salt electrostatic spinning, the gold immersion (Au) bonding pad membrane is designed on the PI substrate to form polar plates and electrodes of the capacitive sensor and the piezoelectric sensor, and the electrode plate is led out through the copper wire to serve as the conductive pin. According to the flexible dual-mode sensor, the flexible PI in a specific shape is prepared to serve as the upper substrate and the lower substrate of the flexible dual-mode sensor, and the gold immersion (Au) bonding pad films are designed on the PI substrates, so that the flexible sensor has flexibility and ductility and is more attached to surfaces with different curvatures.

The invention discloses a preparation method and application of a composite PVDF-HFP and polylysine nanofiber diaphragm, and belongs to the technical field of lithium batteries. The composite material is prepared by blending polyvinylidene fluoride-hexafluoropropylene (PVDF-HFP) and polylysine and then carrying out an electrostatic spinning process. The PVDF-HFP is utilized to provide excellent mechanical strength and chemical stability, rich polar amino functional groups in a polylysine molecular chain are utilized to improve the lyophilic property of the membrane, and anions in an electrolyte are fixed through an intermolecular acting force, so that the transference number of lithium ions is increased, and the lithium ions are induced to be uniformly deposited. The nanofiber membrane combines the characteristics of PVDF-HFP and polylysine, has high porosity, good thermal stability and excellent interface compatibility, can effectively inhibit the growth of lithium dendrites and prevent the diaphragm from being punctured, and can significantly prolong the cycle life and improve the safety performance of the lithium metal battery when being applied to the lithium metal battery.

The invention provides a superfine-diameter PCL / COL nanofiber membrane as well as a preparation method and application thereof, and relates to the technical field of skin wound repair materials. The PCL / COL nanofiber membrane material is prepared from PCL and I-type collagen as raw materials through electrostatic spinning and vacuum drying. According to the preparation method disclosed by the invention, an electrostatic spinning technology is combined with strict regulation and control on parameters, so that the stable and superfine 40-nanoscale PCL / COL nanofiber membrane material is prepared. The diameter of the superfine PCL / COL nanofiber membrane material reaches the bionic scale of the minimum natural collagen of an extracellular matrix, and meanwhile, the superfine PCL / COL nanofiber membrane material shows more excellent hydrophilicity and lower surface roughness, has good biological safety and mechanical stability, not only realizes high matching with a natural ECM hierarchical structure, but also has good application prospects. By enhancing the cell-material interface interaction, the adhesion, proliferation and migration capacities of fibroblasts are remarkably improved, the wound healing period can be effectively shortened, an excellent repair promoting effect is shown, and a solid foundation is laid for clinical transformation of materials.

The invention relates to the technical field of sewage treatment, in particular to an electrostatic spinning PVDF nanofiber membrane for sewage treatment and a preparation method and application of the electrostatic spinning PVDF nanofiber membrane. The preparation method comprises the following steps: dissolving PVDF (Polyvinylidene Fluoride) particles in a mixed solvent of DMF (Dimethyl Formamide) and acetone, adding nano TiO2 particles subjected to APTES (Aminopropyltriethoxysilane) surface modification, and adding PVP (Polyvinyl Pyrrolidone) into the solution to obtain a uniform spinning solution; spinning by adopting electrostatic spinning equipment to obtain a PVDF / TiO2 / PVP nanofiber membrane; the nanofiber membrane is soaked in a sodium hydroxide solution, then the membrane is soaked in a Tris-HCl buffer solution containing dopamine, and the final electrostatic spinning PVDF nanofiber membrane is obtained. The average diameter of nanofibers of the nanofiber membrane is 200-300nm, the porosity of the membrane is 70-80%, and the water contact angle is less than 60 degrees; when the nanofiber membrane is used for treating sewage containing organic pollutants and heavy metal ions, the removal rate of the nanofiber membrane on methyl orange can reach 95% or above; the rejection rate of copper ions can reach 90% or above; the removal efficiency of organic pollutants and heavy metal ions is obviously improved.

The invention provides an optical transparency-optical confinement composite nanofiber membrane as well as a preparation method and application thereof. The optical transparency-optical confinement composite nanofiber membrane comprises a PDMS (Polydimethylsiloxane) / PS (Polystyrene) / TPU (Thermoplastic Polyurethane) nanofiber membrane and a photothermal conversion material layer loaded on the PDMS / PS / TPU nanofiber membrane, the PDMS / PS / TPU nanofiber membrane is prepared by taking PDMS, PS and TPU as raw materials and adopting an electrostatic spinning technology; the photothermal conversion material layer comprises honeycomb porous carbon nanofibers and PDA (Personal Digital Assistant). The optical transparency-optical confinement composite nanofiber membrane and the PDMS / PS / TPU nanofiber membrane have excellent light transmittance and hydrophobicity, the photo-thermal conversion material layer has excellent light absorptivity and high photo-thermal conversion capacity, and the optical transparency-optical confinement composite nanofiber membrane has high membrane flux when being used for photo-thermal membrane distillation desalination. And the photo-thermal film is excellent in distillation performance stability.

The invention provides a micro-nano dual-scale synergistically enhanced MXene-based conductive composite film and a preparation method thereof, belongs to the technical field of multifunctional electromagnetic shielding composite materials, and aims to solve the technical problems that MXene is poor in structural stability and low in binding strength with a base material. The preparation method of the composite membrane comprises the following steps: dropwise adding a pyrrole monomer into an MXene solution to prepare an MXene nanosheet internally doped with PPy, and loading the MXene-PPy nanosheet onto a nanofiber membrane to prepare an MXene-based nanofiber conductive membrane; the MOF microspheres and a hydrophobic agent are mixed to prepare a hydrophobic solution, and the MXene-based nanofiber conductive film is soaked in the hydrophobic solution. The micro-nano dual-scale synergistically enhanced MXene-based conductive composite film prepared by the invention has excellent electromagnetic shielding performance, good hydrophobic property, light weight, softness and foldability, and can be flexibly applied to electromagnetic shielding in various complex environments.

The invention belongs to the related technical field of flexible electrodes, and discloses a preparation method, a product and application of a high-temperature-resistant flexible metallized ceramic nanofiber composite electrode. The method comprises the following steps: carrying out electrostatic spinning on electrostatic spinning sol doped with an organic polymer to obtain a precursor of a flexible ceramic nanofiber membrane; carrying out primary high-temperature calcination on the precursor to remove the doped organic polymer so as to obtain a flexible ceramic nanofiber membrane; growing and coating a metal conductive layer on the surface of the flexible ceramic nanofiber membrane to obtain an electrode precursor; and carrying out secondary high-temperature calcination on the electrode precursor to obtain the required composite electrode. The invention also discloses a product obtained by the preparation method and application. According to the invention, the problem that the flexible sensor is not resistant to high temperature is solved.

The invention relates to the technical field of breathable adhesive tapes, in particular to a double-layer composite high-breathability low-sensitivity adhesive tape and a preparation method thereof. The adhesive tape comprises a hydrophobic surface layer material, a high-breathability low-sensitivity composite adhesive and release paper. The high-breathability and low-sensitivity adhesive tape comprises a three-dimensional net-shaped breathable layer and a low-sensitivity adhesive layer. The hydrophobic surface layer material adopts a polyvinylidene fluoride electrostatic spinning nanofiber membrane with high specific surface area and porosity, so that the hydrophobicity and the adhesion with the lower layer material are improved; according to the high-breathability and low-sensitivity adhesive tape, polycaprolactone, a polylactic acid-glycolic acid copolymer and polyurethane are copolymerized to obtain a multifunctional three-dimensional net-shaped breathable layer; the high-breathability and low-sensitivity composite adhesive tape is prepared from dopamine modified polydimethylsiloxane microfibers decorated by oxidized dextran modified vinyl siloxane tip fibers, and the adhesive force and biocompatibility of the adhesive tape and skins with different roughness degrees are enhanced. Meanwhile, the lignosulfonate surfactant is added, so that the reproduction of bacteria and fungi in an adhesive tape attachment area can be inhibited.

The invention provides electroactive nano short fibers for osteoarthritis cartilage repair and a preparation method thereof, the preparation method comprises the following steps: preparing a nano fiber membrane from a composite material of gelatin, polylactic acid and glycine crystals through electrostatic spinning, and preparing the obtained nano fiber membrane into short fibers; performing freeze drying on the short fibers, and then performing heating treatment to obtain a short fiber stent; the short fiber support is smashed and reacts with graphene oxide, modified graphene oxide short fibers are obtained, and then the modified graphene oxide short fibers are soaked in a mixed solution of alkaline dopamine and phosphatidylcholine for a reaction. The electroactive nano short fiber provided by the invention is low in friction coefficient, the expression quantity of Sirt1 in OA cartilage cells can be remarkably increased under ultrasonic stimulation, the ATP (adenosine triphosphate) productivity can be remarkably improved, release of inflammatory factors and degradation of extracellular matrixes can be inhibited, and meanwhile, a guarantee is provided for updating of a hydrated lubricating layer.

According to the COF nanofiber membrane, the preparation method thereof and the application of the COF nanofiber membrane to uranium enrichment, adsorptive COF powder is synthesized through a solvothermal method, the maximum uranium enrichment amount of the adsorptive COF powder can reach 520 mg / g under the condition that the pH of the adsorptive COF powder is equal to 5, and the adsorptive COF powder is processed into the COF nanofiber membrane through an electrostatic spinning method. The COF nanofiber membrane prepared by the method can retain the properties of COF powder, not only has adsorption capacity to U (VI), but also has photocatalytic reaction capacity, and can convert soluble U (VI) into insoluble uranium and release additional adsorption sites, so that the enrichment capacity of a COF material to uranium is improved, and the enrichment efficiency of the COF material to uranium in water reaches 97% or above. In addition, the COF nanofiber membrane is also beneficial to use and recovery, and is more conveniently applied to the fields of uranium-containing wastewater treatment, uranium extraction from seawater and the like.

The present invention belongs to the technical field of carbon material fibers, and discloses a preparation method of a carbon nanofiber reinforced carbon material fiber fabric. The preparation method is as follows: Fix the weakly twisted carbon material fiber tow on an electrospinning nanofiber yarn machine, form a carbon nanofiber membrane by electrospinning and uniformly wrap it on the weakly twisted carbon material fiber tow, then wind it into a roll, and then weave the wound fibers into a fabric, and sequentially perform hot pressing and carbonization treatments on the fabric to obtain a carbon nanofiber reinforced carbon material fiber fabric; Weak twisting means that the twist is 5 to 13 turns / meter. The present invention first coats the carbon nanofibers on the carbon material fibers to improve the interfacial bonding strength between the nanofibers and the carbon material fibers, and then performs hot pressing and carbonization treatments on the fabric prepared therefrom to further improve the mechanical properties, electrical conductivity and thermal conductivity of the fabric, making it show great application prospects in the fields of high-performance composite materials, intelligent textiles, etc.

The present invention relates to the technical field of air purification, and particularly provides a nanofiber composite air purification filter material and a preparation method therefor. The nanofiber composite air purification filter material comprises a composite structure consisting of four layers arranged from top to bottom, which are respectively a non-woven fabric, a nanofiber membrane layer, a modified melt-blown non-woven fabric and a spunbond non-woven fabric; the non-woven fabric is PET needle-punched non-woven fabric; in parts by weight, the raw materials for preparing the nanofiber membrane layer comprise: 10-20 parts of polylactic acid, 3-5 parts of a reinforcing agent, 2-4 parts of modified nanoparticles and 100-150 parts of a solvent; and the spunbond non-woven fabric is made of PET or PP. The nanofiber composite air purification filter material provided by the present invention has air-permeability, radiation resistance, and antibacterial properties, can be widely applied in the field of air purification filter materials, and has considerable commercial application value.

The invention relates to the technical field of flexible sweat sensors, in particular to a preparation method and application of a laser-induced graphene oxide nanofiber membrane. Comprising the following steps: S1, preparing a graphene oxide nanofiber membrane through an electrostatic spinning process; s2, carrying out laser reduction on the graphene oxide nanofiber membrane, namely engraving an electrode pattern on the graphene oxide nanofiber membrane by adopting a laser, and reducing on the electrode pattern of the graphene oxide nanofiber membrane to generate an LGNF electrode; s3, performing hydrophobic treatment on the graphene oxide spinning fiber membrane; s4, catalytic particles and enzyme are modified on the LGNF electrode, and the laser-induced graphene oxide nanofiber membrane is prepared. The method is simple, efficient, convenient and easy to implement, low in requirement for manufacturing equipment and capable of well achieving mass production, and the sensor prepared through the method can spontaneously absorb sweat to the surface of the electrode to achieve sweat monitoring, so that the hydrophilicity of graphene can be effectively improved, and the electrochemical performance of graphene is improved.

The application belongs to the field of separation and specifically relates to a cellulose / PVDF electrostatic spinning oil-water separation membrane and a preparation method thereof. The preparation method comprises the following steps: S1: preparing cellulose stearate; S2: mixing cellulose stearate obtained in step S1 and polyvinylidene fluoride (PVDF) prepared into solutions respectively to obtain a spinning solution; and S3: defoaming the spinning solution obtained in step S2 and then electrostatic spinning to obtain a cellulose stearate / polyvinylidene fluoride (PVDF) hydrophobic oleophilic oil-water separation membrane. The mixed electrostatic spinning nanofiber membrane has better mechanical properties, and due to the addition of modified cellulose, the nanofiber membrane has greater separation flux, higher separation efficiency and greater porosity.

The invention provides a method for preparing a degradable bone-guided regeneration membrane with an asymmetric membrane layer, which comprises the following steps of: cutting a magnesium metal sheet into a magnesium net or a magnesium bracket with small holes by laser, carrying out heat treatment on the magnesium net or the magnesium bracket by using HF (Hydrogen Fluoride) to obtain a layer of MgF4 coating on the surface, and immersing the magnesium net or the magnesium bracket into a macromolecular solution until a solvent of the macromolecular coating is completely volatilized; then preparing an electrostatic spinning membrane on the surface of the sample: preparing a dense polymer membrane layer containing an antibacterial drug on the surface of the sample close to one side of the fiber tissue by adopting a hot pressing method, or preparing a dense electrostatic spinning ordered fiber membrane which contains an antibacterial nano-drug and is arranged in parallel by adopting an electrostatic spinning method; the designed structure and the used materials can realize an antibacterial function and shield fiber tissues from growing in. The nanofiber membrane which contains osteogenesis promoting substances such as nano-hydroxyapatite or nano-strontium and is conveyed disorderly is prepared on the side close to the bone tissue by adopting an electrostatic spinning technology, and the designed structure and the contained substances can promote osteogenesis.

The invention discloses warm-keeping polyimide aerogel and a preparation method thereof, and belongs to the technical field of high polymer materials. The preparation method comprises the following steps: 1, synthesizing a polyamide acid solution; 2, adding amino-containing organic silicon into the polyamide acid solution, mixing, and defoaming to form a spinning solution; step 3, preparing a nanofiber membrane by electrostatic spinning of the spinning solution; 4, crushing the nanofiber membrane, dispersing the crushed nanofiber membrane in a solvent, standing for 24-48 hours, and freeze-drying to obtain aerogel; and step 5, carrying out stepped heating thermal imidization treatment to obtain the polyimide aerogel. Amino-containing organic silicon is used as a cross-linking agent of polyamide acid, chemical connection is added for a three-dimensional network structure of the gel, and the structural stability of the aerogel is improved. In the thermal imidization process, organic silicon generates a silicon oxide and Si-O-Si network through staged pyrolysis, the silicon oxide exists in fiber gaps and forms an organic-inorganic hybrid interface with PI fibers, and the structural stability is further improved.

The invention discloses an antibacterial, hemostatic and self-powered asymmetric hybrid fiber membrane and a preparation method thereof, the antibacterial, hemostatic and self-powered asymmetric hybrid fiber membrane is composed of three layers of fiber membranes, including: a bottom layer piezoelectric fiber membrane; -a core layer electrically conductive fibrous membrane; -a skin fibrous membrane; the fiber membranes are connected through spinning; the water contact angle of the bottom layer piezoelectric fiber membrane is 140-150 degrees; the water contact angle of the core layer conductive fiber membrane is 50-60 degrees; and the water contact angle of the surface fiber membrane is 20-30 degrees. The invention also discloses a preparation method of the composition. The preparation method of the hybrid nanofiber membrane is simple and controllable, the material cell and blood compatibility is good, the hybrid nanofiber membrane has the functions of promoting cell migration and blood coagulation, growth of wound specific bacteria can be inhibited, cell proliferation is expected to be accelerated through self-powered stimulation, and the hybrid nanofiber membrane has good application prospects in the fields of wound dressings, bionic skin and the like.

The invention relates to the technical field of nanofiber membrane detection, and particularly discloses a thickness uniformity detection device and process for nanofiber membranes, and the thickness uniformity detection device comprises a detection table which is provided with a variable-diameter wheel structure, and the thickness uniformity of the nanofiber membranes can be detected by adjusting the variable-diameter wheel structure according to nanofiber membrane bodies with different thicknesses; the flattening roller can apply uniform pressure to a nanofiber membrane body, an adjusting ring frame can move during adjustment and drive an adjusting connecting arm, the angle of the adjusting connecting arm and the angle of an adjusting lead screw are changed, an arc plate can be driven to expand outwards or contract inwards through the change of the adjusting connecting arm, and then the overall diameter of a variable-diameter wheel structure is changed; therefore, the nanofiber membrane bodies with different thicknesses can be smoothed without replacing other smoothing compression rollers, and the detection efficiency of the nanofiber membrane bodies is improved.