583 results about "Nanofibrous membrane" patented technology

The invention discloses a preparation method and application of a composite PVDF-HFP and polylysine nanofiber diaphragm, and belongs to the technical field of lithium batteries. The composite material is prepared by blending polyvinylidene fluoride-hexafluoropropylene (PVDF-HFP) and polylysine and then carrying out an electrostatic spinning process. The PVDF-HFP is utilized to provide excellent mechanical strength and chemical stability, rich polar amino functional groups in a polylysine molecular chain are utilized to improve the lyophilic property of the membrane, and anions in an electrolyte are fixed through an intermolecular acting force, so that the transference number of lithium ions is increased, and the lithium ions are induced to be uniformly deposited. The nanofiber membrane combines the characteristics of PVDF-HFP and polylysine, has high porosity, good thermal stability and excellent interface compatibility, can effectively inhibit the growth of lithium dendrites and prevent the diaphragm from being punctured, and can significantly prolong the cycle life and improve the safety performance of the lithium metal battery when being applied to the lithium metal battery.

The invention relates to the technical field of sewage treatment, in particular to an electrostatic spinning PVDF nanofiber membrane for sewage treatment and a preparation method and application of the electrostatic spinning PVDF nanofiber membrane. The preparation method comprises the following steps: dissolving PVDF (Polyvinylidene Fluoride) particles in a mixed solvent of DMF (Dimethyl Formamide) and acetone, adding nano TiO2 particles subjected to APTES (Aminopropyltriethoxysilane) surface modification, and adding PVP (Polyvinyl Pyrrolidone) into the solution to obtain a uniform spinning solution; spinning by adopting electrostatic spinning equipment to obtain a PVDF / TiO2 / PVP nanofiber membrane; the nanofiber membrane is soaked in a sodium hydroxide solution, then the membrane is soaked in a Tris-HCl buffer solution containing dopamine, and the final electrostatic spinning PVDF nanofiber membrane is obtained. The average diameter of nanofibers of the nanofiber membrane is 200-300nm, the porosity of the membrane is 70-80%, and the water contact angle is less than 60 degrees; when the nanofiber membrane is used for treating sewage containing organic pollutants and heavy metal ions, the removal rate of the nanofiber membrane on methyl orange can reach 95% or above; the rejection rate of copper ions can reach 90% or above; the removal efficiency of organic pollutants and heavy metal ions is obviously improved.

The invention belongs to the related technical field of flexible electrodes, and discloses a preparation method, a product and application of a high-temperature-resistant flexible metallized ceramic nanofiber composite electrode. The method comprises the following steps: carrying out electrostatic spinning on electrostatic spinning sol doped with an organic polymer to obtain a precursor of a flexible ceramic nanofiber membrane; carrying out primary high-temperature calcination on the precursor to remove the doped organic polymer so as to obtain a flexible ceramic nanofiber membrane; growing and coating a metal conductive layer on the surface of the flexible ceramic nanofiber membrane to obtain an electrode precursor; and carrying out secondary high-temperature calcination on the electrode precursor to obtain the required composite electrode. The invention also discloses a product obtained by the preparation method and application. According to the invention, the problem that the flexible sensor is not resistant to high temperature is solved.

The application belongs to the field of separation and specifically relates to a cellulose / PVDF electrostatic spinning oil-water separation membrane and a preparation method thereof. The preparation method comprises the following steps: S1: preparing cellulose stearate; S2: mixing cellulose stearate obtained in step S1 and polyvinylidene fluoride (PVDF) prepared into solutions respectively to obtain a spinning solution; and S3: defoaming the spinning solution obtained in step S2 and then electrostatic spinning to obtain a cellulose stearate / polyvinylidene fluoride (PVDF) hydrophobic oleophilic oil-water separation membrane. The mixed electrostatic spinning nanofiber membrane has better mechanical properties, and due to the addition of modified cellulose, the nanofiber membrane has greater separation flux, higher separation efficiency and greater porosity.

The invention provides a functional nanofiber material as well as a preparation method and application thereof, and the preparation method comprises the following steps: (1) adding raw materials into water to form an electrostatic spinning solution; performing electrostatic spinning to obtain a nanofiber membrane; (2) cross-linking the nanofiber membrane in an organic solvent under the catalysis of acid to obtain a cross-linked nanofiber membrane; and (3) carrying out grafting reaction on the cross-linked nanofiber membrane in a polyamine cross-linking agent, and then reacting with a sulfur-containing reagent to obtain the functional nanofiber material, the functionalized nanofiber material prepared by the preparation method disclosed by the invention combines good biocompatibility of polyvinyl alcohol, high specific surface area and high porosity of nanofiber and a synergistic adsorption effect of the polyamine cross-linking agent and cysteine, and has the advantages of large adsorption capacity, high adsorption rate, strong selectivity, good biocompatibility, stable structure and the like; the heavy metal ions in the plasma can be efficiently and safely removed, and a plurality of defects of the existing adsorption material are overcome.

The invention relates to the technical field of polymer electrolytes, in particular to a composite solid electrolyte based on aramid nanofibers and a lithium-sulfur battery. The composite solid electrolyte is prepared by taking a composite aramid nanofiber membrane with a double-layer three-dimensional structure as a base material, an upper polyaniline base material provides good interface contact stability with a lithium negative electrode, and a lower aramid nanofiber skeleton provides good mechanical support performance for the fiber membrane; and meanwhile, the electrochemical performance of the composite solid electrolyte is comprehensively improved by doping the special porous structure of the composite solid electrolyte with the core-shell porous carbon.

The application discloses a kind of electrospinning preparation methods of superfine, no adhesion polyether ketone ketone nanofiber membrane: polyether ketone ketone is dissolved in solvent to obtain polyether ketone ketone spinning solution;Polyether ketone ketone spinning solution is loaded in the injector of electrospinning device, and spinning is carried out;The concentration of ethanol or water in spinning environment is improved using solvent atomization between injector needle and collecting device, and polyether ketone ketone jet phase separation is accelerated;The nascent polyether ketone ketone nanofiber is collected into membrane;The fiber membrane collected is soaked in coagulation liquid to make solvent remaining in fiber precipitate, after taking out, dry, obtain polyether ketone ketone nanofiber membrane.The application realizes low concentration electrospinning using the unique interchain topological entanglement of polyether ketone ketone, and promotes phase separation by introducing solvent atomization between spinneret and collecting device, overcome the problem that other polymers are difficult to obtain continuous fiber and fiber is easy to adhere in low concentration electrospinning, and prepare superfine, no adhesion polyether ketone ketone nanofiber membrane.

The invention discloses an iron-nickel diatomic fiber catalyst with a precise and adjustable local structure and a preparation method and application thereof.The method is based on an organic small molecule coordination strategy and comprises the steps that ferric nitrate, nickel nitrate and dicyandiamide are dissolved in DMF according to a certain molar ratio, and a solution A is obtained; dispersing ZIF-8 nanoparticles in DMF (Dimethyl Formamide), and adding polyacrylonitrile to obtain a solution B; the solution A and the solution B are mixed to obtain a spinning solution, and a nanofiber membrane is obtained through electrostatic spinning; and carrying out pre-oxidation and high-temperature carbonization treatment on the nanofiber membrane to obtain the carbon nanofiber catalyst loaded with iron-nickel bimetallic atoms (metal diatoms, heterojunctions and alloys in which the metal diatoms and clusters coexist). The problem that the metal active site local structure of a metal diatom catalyst is difficult to accurately regulate and control is solved, and the prepared metal diatom heterojunction shows excellent ORR and OER bifunctional catalytic performance and cycling stability as a zinc-air battery positive electrode catalyst.

According to the invention, a bicontinuous phase conductive core-shell nanofiber membrane is applied to construction of a flexible neural electrode and a neural conduit, firstly, a bicontinuous phase conductive polymer system is constructed, and the system realizes a three-dimensional network in which an electric phase and a mechanical phase are respectively continuous, interpenetrating but independent; and the long-term technical problems of conductive component agglomeration, conductive path interruption and the like are effectively solved. And preparing the conductive nanofiber scaffold with a core-shell structure by taking a high-molecular polymer as a core layer material and a bicontinuous-phase conductive polymer system as a shell layer material through a coaxial electrostatic spinning method. The construction mode effectively establishes a stable, continuous and uniform electron conduction path, can realize effective nerve electrical stimulation and high-fidelity electrophysiological signal recording in vivo, and can be used as a nerve conduit to regulate and repair related bio-electricity signals in a nerve repair process, so as to accelerate regeneration and repair of nerves.

The invention relates to a nerve repair guide catheter, a preparation method and application, an electrostatic spinning technology is adopted to construct a nanofiber membrane which is directionally and orderly arranged so as to guide nerve axons to directionally grow, and cell energy metabolism is promoted and tissue repair and regeneration are accelerated through metabolism and conversion of degradation products. Therefore, the nerve injury repairing effect better than that of traditional matrix materials without biological activity, such as PCL, is achieved. According to the invention, a novel solution is provided for solving the problem of insufficient biological activity of a traditional nerve conduit material by constructing a degradable high polymer material with biological activity. Therefore, the regeneration efficiency of peripheral nerve injury repair is improved, and the application prospect of the bioactive material in the fields of tissue engineering and regenerative medicine is expanded.

The invention provides a multi-stage synergistic wound repair nanofiber membrane and a preparation method thereof. The composite fiber membrane sequentially comprises an electrostatic spinning pullulan / tannic acid / tranexamic acid nanofiber membrane for promoting the formation of blood clots, a polydopamine / calcium chloride modified electrostatic spinning cellulose acetate membrane with coagulating, antibacterial and repairing effects, and a chitosan composite cellulose non-woven fabric, and the electrostatic spinning pullulan / tannic acid / tranexamic acid nanofiber membrane is a wound surface contact layer. The nanofiber membrane has the functions of a physical hemostasis barrier and continuously releasing regeneration promoting biological signals, and a dynamic hemostasis healing process is formed.

The present invention provides a nanofiber membrane having dual scale porosity, which is manufactured by a phase separation electrospinning method. The nanofiber membrane is composed of interfibrous pores and surface pores which are interconnected, thereby enhancing air permeability, diffusion rate and filtration performance. The methods employ solvents having different evaporation rates to induce phase separation during electrospinning, resulting in high porosity structures. The nanofiber membranes are suitable for use in air filtration, medical dressings, drug delivery systems, and diagnostic test paper, thereby improving performance characteristics, such as reducing pressure drop, enhancing diffusion, and increasing diagnostic sensitivity. The method enables cost-effective and scalable production while ensuring consistency of fiber morphology.

The invention belongs to the technical field of conductive hydrogel composite materials, and relates to nanofiber reinforced composite organic hydrogel as well as a preparation method and application thereof.The method comprises the following preparation steps: synthesizing a thermoplastic polyurethane (TPU) nanofiber membrane in advance, uniformly filling a TPU stretchable matrix with carbon nanotubes (CNTs) in a solvent by adopting ultrasonic assistance, and preparing the nanofiber reinforced composite organic hydrogel. A conductive network is adjusted by adjusting the loading capacity of carbon nanotubes on a fiber membrane through different ultrasonic time, and the upper layer and the lower layer of the modified fiber membrane are coated with a polyvinyl alcohol / glycerol / aqueous solution to prepare a conductive CNTs (at) TPU-X nanofiber membrane (x is ultrasonic time), so that the elastomer film sensor with a sandwich-like structure is obtained. According to the invention, the problems of dispersibility of the nanofiller in a hydrogel matrix and interfacial compatibility of fibers and gel are solved.

The invention discloses a polyarylene ether nitrile nanofiber membrane and a preparation method of the polyarylene ether nitrile nanofiber membrane through double-solvent synergistic electrostatic spinning, and relates to the field of high polymer material preparation. The method comprises the following steps: preparing two electrostatic spinning solutions with obvious volatilization rate and dissolution parameter difference, and alternately depositing two types of fibers on a collecting surface by adopting dual-channel synergistic electrostatic spinning; in the deposition and drying process, chain segments at fiber cross points are induced to swell, mutually diffuse and cure in situ to form bonding points by utilizing the poor evaporation rate of a high / low volatile solvent and the poor solvent-polymer compatibility, so that the self-densification and the structure stabilization of the nanofiber membrane are realized. The obtained nanofiber membrane has high-density in-situ bonding points and remarkably improved mechanical properties, does not need additional post-treatment such as hot pressing or solvent spraying, and is suitable for application such as interlayer reinforcement and interface toughening of composite materials. The process has continuity and controllability, and the density and mechanical properties of the membrane body can be customized by adjusting a solvent system and spinning parameters.

The invention discloses a flexible full-biodegradable Janus nanofiber membrane for oil-water separation, which is characterized in that two degradable polymer spinning solutions are spun into a composite nanofiber membrane with a Janus structure through a side-by-side electrostatic spinning method, and then hydrophilic modification is performed to obtain a hydrophilic nanofiber membrane used as an oil-water separation membrane. The product is the flexible full-biodegradable Janus nanofiber membrane for oil-water separation. The obtained hydrophilic nanofiber membrane has good mechanical flexibility, full biodegradability and excellent oil-water selective permeability, the oil-water separation effect and application stability are remarkably improved, the service life is remarkably prolonged, and the hydrophilic nanofiber membrane will become an oil-water separation membrane material with practical value.

The invention relates to the technical field of nanofiber membrane materials, in particular to a heat-insulation and warm-keeping nanofiber membrane material and a preparation method thereof.A mixed solution of tetraethoxysilane hydrolysate and a polyvinyl alcohol aqueous solution serves as a precursor of electrostatic spinning, modified titanium dioxide hollow microspheres are added in the preparation process, and the nanofiber membrane material is prepared; a near-vacuum environment is formed in the titanium dioxide hollow microspheres, heat is conducted by inhibiting collision of gas molecules, so that radiation heat transfer is blocked, the prepared nanofiber membrane material has a good heat preservation and heat insulation effect, a silane coupling agent forms hybrid bonds on the surfaces of the microspheres and is combined with polyvinyl alcohol molecular chains through chemical bonds, and the heat preservation and heat insulation effects are improved. The interface adhesion force is obviously improved, so that the hollow microspheres are prevented from collapsing during mechanical friction or bending; secondly, different types of quaternary ammonium salt antibacterial agents are compounded, the synergistic sterilization effect can be achieved, four quaternary ammonium salts are synergistic through different action targets, and the problem that a single antibacterial agent is prone to generating drug resistance can be solved.

The invention provides a composite solid electrolyte based on a porous meta-aramid nanofiber membrane and a fluorinated metal organic framework. A preparation method of the composite solid electrolyte comprises the following steps: preparing a porous poly (m-phenylene isophthalamide) nanofiber membrane; the fluorinated metal organic framework is prepared through two-step heat treatment synthesis and fluorination modification; and finally, coating the nanofiber membrane with a polymer electrolyte matrix comprising a fluorinated metal organic framework, polyethylene oxide and lithium salt to prepare the composite solid electrolyte. Through the synergistic effect of the porous polyisophthaloyl metaphenylene diamine nanofiber membrane and the fluorinated metal organic framework, while the mechanical strength and dendritic crystal inhibition capability of the composite solid electrolyte are remarkably improved, lithium ion transmission is effectively promoted, and the interface impedance is reduced; the prepared composite solid electrolyte is suitable for preparing a solid lithium metal battery with high safety and high performance.

The invention discloses a preparation method and application of an electrospun nanofiber membrane-based flexible SERS (Surface Enhanced Raman Scattering) substrate, and belongs to the field of preparation of SERS substrates. The preparation method comprises the following steps: firstly, preparing a polymer nanofiber membrane by adopting an electrostatic spinning method, and then depositing noble metal nanoparticles on the surface of the electrospinning polymer nanofiber membrane by adopting a magnetron sputtering technology, so as to obtain the noble metal nanoparticle and polymer nanofiber membrane flexible SERS (Surface Enhanced Raman Scattering) substrate. According to the present invention, the problems that the SERS substrate cannot be accurately controlled and cannot be continuously produced are solved, the preparation method has advantages of simpleness, high efficiency, no pollution, low cost and large-scale manufacturing compared with the existing preparation method, the substrate has characteristics of large specific surface area, high density hot spot distribution, good stability and adjustable size structure, and the trace detection of the pesticide residue on the irregular surface can be achieved.

The invention discloses a core-sheath / parallel structure hybrid nanofiber membrane, a preparation method, a spinning head and a high-voltage electrostatic spinning device. The spinning head comprises a transversely-arranged cylindrical spinning solution storage device with spinneret orifices in the bottom end and a plurality of stainless steel capillary tubes penetrating through the cylindrical spinning solution storage device. And the capillary tubes are gathered above the spinning solution storage device to form two common fluid inlets. Part of the capillary tubes and spinneret orifices in the bottom of the cylindrical spinning solution storage device are arranged in parallel to form parallel outlets of two fluids; the other part of the stainless steel capillary tube directly passes through the center of the spinneret orifice of the cylindrical spinning solution storage device to form a coaxial outlet of the two fluids; and the parallel outlets and the coaxial outlets are uniformly distributed in a staggered manner at the bottom of the transverse storage device. According to the spinning device, an outlet jointly formed by a spinneret hole in the bottom of a spinning head and a metal capillary tube serves as a template, different multi-strand microfluid combinations are guided into a high-voltage electrostatic field, and the core-sheath / parallel structure hybrid nanofiber membrane is directly prepared in batches in a single step.

The invention relates to an oil-water separation membrane as well as a preparation method and application thereof, and belongs to the field of gas field brine pretreatment. The oil-water separation membrane comprises a nanofiber membrane substrate and an MOFs layer loaded on at least part of the surface of the nanofiber membrane substrate, and the MOFs layer comprises two-dimensional MOFs nanosheets; the nanofiber membrane substrate is prepared by performing electrospinning on three-dimensional MOFs and an organic polymer; the two-dimensional MOFs nanosheet is obtained by secondary growth on the surface of the nanofiber membrane substrate through hydrothermal recrystallization. The oil-water separation membrane can be used for efficiently separating petroleum pollutants and solid suspended matters in the oil and gas field produced wastewater, and can be coupled with an advanced oxidation process based on sulfate free radicals to realize synchronous and efficient removal of oil, suspended particles and organic matters in the oil and gas field produced wastewater.

The application belongs to the field of medical biological materials, and relates to a preparation method of a hierarchical nanofiber composite film for nerve repair and application thereof. The method comprises the following steps: preparing multilayer nanofibers with different internal stresses through continuous multiple electrostatic spinning units, stacking the multilayer nanofibers with different internal stresses to form a composite nanofiber film with an internal stress gradient; chemically crosslinking the composite nanofiber film; performing adhesion molecule adhesion treatment on the upper surface of the composite nanofiber film; and preparing the hierarchical nanofiber composite film with an internal stress gradient and capable of self-deforming under the action of liquid to wrap nerves. The film provided by the application has excellent flexibility, biocompatibility and degradation performance, can efficiently and quickly adhere to the surface of damaged nerves, provides a good support microenvironment for nerve cell growth, promotes nerve regeneration and repair, and has a wide application prospect in the field of peripheral nerve injury repair.

The application provides a method and device for preparing oriented nanofiber membranes, which comprises the following steps: freezing polymer nanofibers with liquid nitrogen; sticking a substrate for preparing nanofiber membranes on the inner wall of a closed container of a device for preparing oriented nanofiber membranes; placing the frozen polymer nanofibers in the closed container and rotating at high speed; and finally taking off the substrate on the inner wall of the closed container, and the surface of the substrate is uniformly compounded with oriented polymer nanofibers, thus obtaining the oriented nanofiber membranes. The device for preparing oriented nanofiber membranes has a rotating component rotating at high speed, and under the action of high-speed shearing force, the device can realize the directional selection of nanofibers and apply centrifugal force to the fibers, so that the fibers are oriented and compounded with the substrate. The application can be applied to different polymer nanofiber materials, realizes the separation of fiber spinning and orientation process, overcomes the dependence of traditional methods for preparing oriented fiber membranes on electrospinning technology, realizes dry film forming technology, and has great application prospect.

The present application relates to a kind of humidity response actuator and its preparation method and application, belong to actuator technical field.The humidity response actuator of the present application is double-layer film structure, including humidity response active layer and humidity response inert layer;The humidity response active layer is made into nanofiber membrane by electrospinning technology to hydrophilic polymer material, the nanofiber membrane has orientation structure;The humidity response inert layer is non-hydrophilic polymer film adhesive tape.The humidity response actuator of the present application due to the orientation structure of fiber, the deformation of humidity response actuator only occurs in fiber orientation direction, so it can be designed fiber orientation direction and the relative change of shape direction of humidity response actuator, realize the design and programming of humidity response actuator deformation mode.

The invention belongs to the technical field of anticorrosive and antibacterial coatings, and particularly relates to a self-repairing antibacterial anticorrosive coating and a preparation method thereof. The core-shell structure nanofiber membrane with a high polymer material as a shell and a metal corrosion inhibitor as core liquid is prepared by adopting a coaxial electrostatic spinning technology. An epoxy resin coating is sprayed on an iron sheet in advance, the sprayed epoxy resin is subjected to low-temperature pretreatment to be in a semi-solidified state, and a core-shell structure nanofiber membrane is attached to the pretreated epoxy resin coating; and finally, spraying the epoxy resin containing the antibacterial agent and the antibacterial agent ethanol solution on the surface of the fiber membrane again to prepare the composite coating with a sandwich structure. The prepared composite coating has good antibacterial ability, after the iron sheet coating is damaged, the anti-corrosion coating can rapidly release an anti-corrosion healing agent to rapidly repair the damaged part of the coating, and the composite coating has efficient self-repairing anti-corrosion ability and has good application prospects in the anti-corrosion field.

The invention discloses a bismuth-based nanofiber photocatalytic material as well as a preparation method and application thereof, and belongs to the technical field of photocatalytic materials. The material is prepared by taking bismuth as a matrix and introducing vanadium, halogen or molybdenum elements through an electrostatic spinning and staged calcining process. The obtained material is of a three-dimensional nanofiber membrane structure, has a high specific surface area and excellent visible light response characteristics, can synchronously and efficiently photocatalytically degrade organic pollutants in electroplating wastewater and reduce and fix heavy metal ions, is easy to separate and recover, has good cycle stability, and is suitable for industrial production. And an efficient and green technical scheme is provided for deep treatment of the electroplating wastewater.

The invention discloses a preparation method and application of a porous para-aramid nanofiber membrane. The preparation method of the para-aramid nanofiber membrane comprises the following steps: placing a substrate coated with an aramid nanofiber solution in an aprotic solvent to obtain an aramid nanofiber membrane containing the aprotic solvent; and immersing the aramid nanofiber membrane containing the aprotic solvent into a protic solvent, replacing the aprotic solvent in the nanofiber membrane with the protic solvent, and heating and drying to obtain the para-aramid nanofiber membrane. The para-aramid nanofiber membrane prepared by the preparation method of the para-aramid nanofiber membrane has highly adjustable porosity and pore structure, and has a huge application prospect in the fields of battery diaphragm and membrane separation and the like, and the preparation method is simple and suitable for large-scale industrial application.

The application provides a preparation method of piezoelectric nanofiber aerogel, comprising the following steps: S1, zinc oxide is added into hexafluoroisopropanol, polyhydroxybutyrate is added after ultrasonic dispersion, and magnetic stirring is conducted to obtain a PHB@ZnO solution; S2, the PHB@ZnO solution is prepared into a nanofiber membrane through electrospinning, the nanofiber membrane is placed into a vacuum drying box for vacuum drying to obtain a PHB@ZnO nanofiber membrane; S3, the PHB@ZnO nanofiber membrane is added into deionized water, and a short PHB@ZnO nanofiber dispersion liquid is obtained after homogenization; S4, chitosan powder is added into deionized water, glacial acetic acid is added after stirring, and chitosan solution is obtained after continuous stirring; S5, the short PHB@ZnO nanofiber dispersion liquid, the chitosan solution and glutaraldehyde are uniformly mixed to obtain a mixture, the mixture is poured into a mold, the mold is placed into a freeze dryer for freeze drying to obtain piezoelectric nanofiber aerogel. The piezoelectric nanofiber aerogel prepared by the piezoelectric nanofiber aerogel has a porous structure and good piezoelectric performance, and can accelerate bone defect repair.

This invention pertains to the field of glucose detection and discloses a copper-based MOF nanofiber membrane, its preparation method, and its application. The copper-based MOF nanofiber membrane is prepared by a method comprising the following steps: (1) adding a polyvinyl alcohol solution to a copper acetate solution to form a spinning solution; (2) electrospinning the spinning solution to obtain a copper-based nanofiber membrane; (3) calcining the copper-based nanofiber membrane in an air atmosphere to obtain a copper oxide fiber membrane; (4) mixing the copper oxide fiber membrane with an organic ligand, adding a solvent, and performing a hydrothermal reaction to obtain a copper-based MOF nanofiber membrane. The copper-based MOF nanofiber membrane prepared by this invention, as an electrode material for an enzyme-free glucose sensor, can improve conductivity, sensitivity, and anti-interference performance. Furthermore, the preparation method is simple and can be mass-produced.

The invention provides a preparation method of a keratin-based temperature-sensitive composite nanofiber membrane. The preparation method comprises the following steps: polymerizing keratin and an N-isopropylacrylamide monomer (NIPAm) to obtain temperature-sensitive keratin; keratin, temperature-sensitive keratin and PEO are blended in proportion to obtain a keratin-based temperature-sensitive spinning solution, then a keratin-based temperature-sensitive composite nanofiber membrane is prepared through an electrostatic spinning technology, finally, the nanofiber membrane is soaked in an EDC-NHS solution for crosslinking, and the water-insoluble composite nanofiber membrane is obtained. The keratin-based temperature-sensitive composite nanofiber membrane not only has good biocompatibility and biological activity, but also has a temperature response function, and shows a wide application prospect in the fields of biomedicine and environment.

The invention relates to the technical field of functional nano material preparation, in particular to a preparation method of aluminum-based MOF (Metal Organic Framework) nanofiber aerogel. According to the specific technical scheme, the preparation method comprises the following steps: S1, calcining prepared precursor nanofiber membranes with different diameters to obtain amorphous silica-alumina precursor nanofiber membranes, and putting the membranes into a reaction solution A for synthesis to obtain aluminum-based MOF nanofiber membranes X, Y and Z with different diameters; s2, respectively crushing aluminum-based MOF nanofiber membranes with different diameters, respectively putting the crushed aluminum-based MOF nanofiber membranes into the reaction solution B for reaction, and after the reaction is finished, carrying out ultrasonic homogeneous dispersion to obtain homogeneous dispersion liquids X1, Y1 and Z1; s3, the homogeneous dispersion liquid X1, the homogeneous dispersion liquid Y1 and the homogeneous dispersion liquid Z1 are frozen and crushed, then a template is filled with the homogeneous dispersion liquid X1, the homogeneous dispersion liquid Y1 and the homogeneous dispersion liquid Z1, solidified blocks are obtained, then drying treatment is conducted, the solidified blocks are put into a reaction solution C to be activated, and then the aluminum-based MOF nanofiber aerogel is obtained, so that special-effect utilization of the aluminum-based MOF nanofiber aerogel in the fields of chemical protection, toxic and harmful gas treatment and the like is achieved.