Preparation method of high power capacity lithium ion battery cathode material

A technology for lithium-ion batteries and negative electrode materials, applied to battery electrodes, circuits, electrical components, etc., can solve the problems of limited improvement and material cycle performance that cannot meet the needs, achieve high specific capacity, easy industrial production, and preparation process simple effect

Active Publication Date: 2012-11-07
内蒙古斯诺新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, magnetron sputtering or chemical deposition is used to deposit silicon thin films on current collectors, chemical vapor deposition is used to deposit nano-silicon thin films on graphite surfaces, nano-Si-Ni alloys are used, and silicon-carbon composite materials are produced by high-energy mechanical ball milling. Silicon powder with an average particle size of 80 nanometers is used to make silicon-carbon composite materials. These methods can indeed improve the cycle performance of silicon to a certain extent, but the degree of improvement is limited, and the cycle performance of the material still cannot meet the needs.

Method used

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  • Preparation method of high power capacity lithium ion battery cathode material
  • Preparation method of high power capacity lithium ion battery cathode material
  • Preparation method of high power capacity lithium ion battery cathode material

Examples

Experimental program
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Embodiment 1

[0023] Weigh a certain amount of natural spherical graphite, according to the ratio of graphite:concentrated sulfuric acid:potassium permanganate=1:2.5:0.05 (mass ratio), first add concentrated sulfuric acid and stir until uniform, then slowly add potassium permanganate, Continue to stir for 30 minutes after the addition, then wash with water until neutral, then dry, expand in a muffle furnace at a temperature of 900°C for 25 seconds to obtain micro-expanded graphite, and mix micro-expanded graphite and silicon powder in a mass ratio of 1:0.15 Mix, then ultrasonically disperse until uniform, then suction filter, dry, then mix and coat the obtained powder with 13% asphalt, heat to 1000°C under nitrogen protection, keep it warm for 3 hours, then cool to room temperature, and finally get this product Invented silicon-carbon composite anode materials, such as figure 1 As shown, nano-silicon 2 is distributed between graphitic carbon layers 3 , and the silicon-carbon composite negat...

Embodiment 2

[0026] Prepare micro-expanded graphite as described in Example 1, mix micro-expanded graphite and silicon powder at a mass ratio of 1:0.2 and ultrasonically disperse until uniform, then suction filter and dry, and then mix the obtained powder with 15% asphalt coating, heating to 1100° C. under the protection of nitrogen, keeping the temperature for 3 hours, and then cooling to room temperature to finally obtain the silicon-carbon composite negative electrode material of the present invention.

[0027] The test conditions of the electrode material are as described in Example 1, charging and discharging at a current density of 50 mA / g. The first discharge point capacity of the electrode material is 990mAh / g, and the capacity after 100 cycles is still 772mAh / g, with a retention rate of 78%.

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Abstract

A preparation method of a high power capacity lithium ion battery cathode material uses natural spherical graphite to serve as raw materials, uses concentrated sulfuric acid to serve as an inserting layer agent, uses potassium permanganate to serve as an oxidizing agent, conducts expansion treatment at high temperature to obtain micro-expanded graphite, then enables the micro-expanded graphite in different proportions to be mixed with nanometer ganister sand, conducts ultrasonic dispersion, suction filtration and dying to obtain the micro-expanded graphite with the nanometer ganister sand inserted in layers, enables the micro-expanded graphite to be mixed and coated with carbon source carbon source according to certain proportion, and finally conducts carburizing sintering under inert gas shielding to prepare completely coated silicon carbon composite cathode material with sufficient obligated obligate inside. Electrochemistry shows that the silicon carbon composite material prepared by the preparation method has high specific capacity and cycling stability and is the ideal high power capacity lithium ion battery cathode material.

Description

technical field [0001] The invention relates to the field of batteries, in particular to a method for preparing a high-capacity lithium-ion battery negative electrode material. Background technique [0002] Since Japan's Sony Corporation took the lead in developing and commercializing lithium-ion batteries in 1990, lithium-ion batteries have developed rapidly. Nowadays, lithium-ion batteries have been widely used in many fields such as civilian and military. With the continuous advancement of science and technology, people have put forward more and higher requirements for the performance of batteries: the miniaturization and personalized development of electronic equipment requires batteries to have smaller volumes and higher specific energy output; aerospace energy requirements Batteries have cycle life, better low-temperature charge and discharge performance, and higher safety performance; electric vehicles require batteries with large capacity, low cost, high stability ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/62H01M4/38H01M4/583
CPCY02E60/12Y02E60/10
Inventor 田东鲍海友谌江宏谭建可
Owner 内蒙古斯诺新材料科技有限公司
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