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44 results about "Elemental chlorine free" patented technology

Elemental chlorine free (ECF) is a technique that uses chlorine dioxide for the bleaching of wood pulp. It does not use elemental chlorine gas during the bleaching process and prevents the formation of dioxins and dioxin-like compounds, carcinogens. The traditional ECF sequence is DEopDEpD using the common letter symbols for bleaching stages, though many improved sequences are available.

Method for preparing high-alkali value (TBN400) synthesized calcium alkyl benzene sulfonate

The invention provides a method for preparing high base number (TBN400) synthetic calcium alkyl-benzene sulfonate. The method comprises the following steps of: adopting a mixed acid of long-chain linear alkyl-benzene sulfonic acid and high-boiling heavy alkyl-benzene sulfonic acid, calcium oxide and/or calcium hydroxide, low-carbon alcohol, alkaline-earth metal halide or nitrate, and a mixture of alkaline-earth metal alkylphenol or alkaline-earth metal alkylphenate and polyisobutylene succinic anhydride for a neutralization reaction in the presence of a solvent and cutback oil at a temperature of between 40 and 80 DEG C; then, passing through carbon dioxide to a product of the neutralization reaction at a temperature of between 40 and 60 DEG C for a carbonation reaction; and producing high base synthetic alkyl-benzene sulfonate with a total base number (TBN) of 400mgKOH/g by adopting a process of a one-step method. The product is divided into high-base number (TBN400) synthetic alkyl-benzene sulfonate containing chlorine and high-base number (TBN400) synthetic alkyl-benzene sulfonate without the chlorine. The product produced by adopting the method with low viscosity, small turbidity, easy filtration, light color and no skin formation has the advantages of excellent high-temperature detergency, excellent anti-foaming property and excellent heat storage stability.
Owner:JINZHOU DPF TH CHEM CO LTD

Pulping method of high-yield coniferous wood dissolving pulp and dissolving pulp prepared by pulping method

InactiveCN108867130ANo foulingIncrease product diversityDigestersPulp bleachingProduction lineSulfate
The invention provides a pulping method of high-yield coniferous wood dissolving pulp. The pulping method sequentially comprises the steps of cooking liquor presoaking, sulfate process cooking, cold alkali extraction and elemental chlorine free bleaching for the coniferous wood raw material, wherein the cooking liquor presoaking temperature is 20-100 DEG C, and the sulfate process cooking temperature is 170-185 DEG C. Compared with the traditional prehydrolyzed sulfate bleachable pulp, only a cold alkali extraction section needs to be added before bleaching of the prepared high-temperature sulfate dissolving pulp to reduce the polypentose content to a suitable level, and the waste liquor of the cold alkali extraction section can be reused in the cooking stage so as to avoid cost increase.The process is universal for production of the dissolving pulp in a pulp mill having sulfate process pulping production lines, and different grades of pulp can be produced on the same production lineonly by changing the cooking strength to realize conversion of the produced pulp between paper pulp and dissolving pulp, so as to increase the product diversity of enterprises, so that the enterprisescan produce the pulp in different purposes at any time according to changes in the market so as to enhance the anti-risk capability of the enterprises.
Owner:TIANJIN UNIV OF SCI & TECH

Methods for enhancing acid sites of FCC catalysts

The present invention discloses aqueous methods for enhancing the acid sites of fluid catalytic cracking (FCC) catalysts. The methods comprise the steps of contacting an FCC catalyst, either spent or fresh, with an aqueous solution comprising water, an inorganic acid substantially free of chloride and aluminum. The acid is preferably sulfurous or sulfuric acid. The aluminum is provided by an aluminum source selected from the group consisting of the alumina trihydrates and aluminum oxide. Chloride contamination of the aluminum source should be minimal, preferably less than about 1000 ppm chloride, more preferably less than about 200 ppm chloride. The pH of the aqueous solution is adjusted to about 3-12 by the addition of a sufficient quantity of ammonium hydroxide. The FCC catalyst is added to this solution, preferably with stirring, in a weight ratio of about 1 part catalyst to about 1-10 parts water to prepare an aqueous slurry. Upon stabilization of the pH of the aqueous slurry, enhancement of the acid sites of the catalyst is achieved and the catalyst may be separated from the slurry and, if desired, washed. This simple, aqueous process reduces the level of many metal poisons on the FCC catalyst and produces a catalyst having an enhanced number of acid reaction sites.
Owner:COASTAL CATALYST TECH

Wheat straw pulp elemental-chlorine-free bleaching wastewater recycling method

The invention discloses a wheat straw pulp elemental-chlorine-free bleaching wastewater recycling method which is characterized in that a paper pulp bleaching mode is DQP three-section bleaching, and the whole washing wastewater of pulp from hydrogen peroxide (P) section bleaching is reused, without being processed, in washing pulp from chlorine dioxide (D) section bleaching. The specific method is as follows: after the washing wastewater of pulp from the P section bleaching is reused in the D section bleaching, the pulp is diluted to the washing pulp concentration of 0.5-2%; the pulp is fully mixed and washed and then is concentrated to 15-18%; and the concentrated pulp is diluted with clear water and then is processed in a Q section. The amount of residual bleached chemicals in washing water from the P section is no less than 40%. By the method of directly recycling P-section bleaching wastewater in washing pulp from D-section bleaching without being processed, water consumption during the wheat straw pulp bleaching process and yield of bleaching wastewater can be reduced effectively. In addition, dosage of a bleaching agent can be decreased remarkably, pollution load can be reduced, and performance of the bleached pulp is basically not influenced. Heat energy of wastewater from the P section also can be utilized, and energy consumption of the bleaching section can be reduced effectively.
Owner:CHINA NAT PULP & PAPER RES INST CO LTD
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