The present application discloses a method for preparing a low-salt permeability bipolar membrane, which belongs to the field of bipolar membrane preparation. In view of the inherent characteristic that the anion
membrane layer is difficult to form a cross-linked structure in the
casting process, the present application separately designs the
high selectivity of the anion
membrane layer and the good intermediate
interface layer formed by the anion and cation membrane
layers. After the surface of the anion
membrane layer is coated with a water dissociation catalyst, an anion membrane
polymer solution is coated to form a thinner anion membrane layer, and then a
highly selective anion membrane is attached and the membrane
layers are fixed together to form a whole by a
hot melt process; the first anion membrane layer is a thinner anion membrane layer formed by
coating, and the design focus is to make the bipolar membrane have a low water dissociation
voltage, and the second anion membrane layer is a
highly selective anion membrane layer, which ensures the
low salt permeability of the bipolar membrane; the anion membrane layer, the first anion membrane layer and the second anion membrane layer are all designed to be fused together by a
hot melt process, and the prepared bipolar membrane has
low salt permeability and low water dissociation
voltage.