The invention discloses a method for removing sulphate from an outdoor crisp brick cultural relic. The method is as follows: spraying a salt-damaged crisp part of a brick body with a solution A evenly, then evenly spraying the salt-damaged crisp part of the brick body with a deionized water and solution B mixed liquid with the volume ratio of deionized water to solution B of 1: 6 to 9, and repeating spraying with the solution A and the deionized water and solution B mixed liquid for 3 to 8 times, wherein the solution A is an ethanol solution containing 5 to 15 g / L of phosphoric acid and 10 to25 g / L of dihydrate oxalic acid, and the solution B is a methanol containing 8 to 25 g / L of barium hydroxide octahydrate. According to the method, the outdoor crisp brick cultural relic is desalted for transformation of most destructive Na2SO4 in the brick relic into BaSO4 to deposit in the brick, chlorine salt and sulfate that are not involved in the transformation can be separated from the brickbody in the manner of moving of salts along with water; while desalination, reinforcement function is achieved, the ''fragile'' status of salt-damaged crisp powder of the brick body may not be aggravated, the mechanical strength is significantly increased, the salt penetration increases after the desalination, and the salt retention time in the brick can be reduced.