Water-repellent, oil-repellent, sun-proof, anti-bend torsion and cold-resistant matt-leather-membrane aqueous coating adhesive for textiles and preparation method of matt-leather-membrane aqueous coating adhesive
A water-based coating and textile technology, applied in textiles, papermaking, fiber treatment, etc., can solve the problems of no other functions, achieve the effect of improving coating film performance, low surface energy, and improving wash fastness
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Embodiment 1
[0042] Emulsification reaction: In the pre-emulsion tank, fully mix deionized water 100, fatty alcohol polyoxyethylene ether XL90 2, sodium dodecylbenzenesulfonate 0.5, add isooctyl acrylate 70, methacrylate iso Bornyl ester 20, glycidyl methacrylate 2, trifluoroethyl methacrylate 15, vinyltrimethoxysilane 5, hydroxypropyl acrylate 1.5, and stir evenly to obtain a pre-emulsion.
[0043] Dissolve 0.3 ammonium persulfate and 10 deionized water evenly to prepare an aqueous solution of ammonium persulfate for use.
[0044]Initiate polymerization reaction: Take 20% of the weight of the above emulsion and add it to the reaction kettle, raise the temperature to 70-75°C, add 25% of the weight of ammonium persulfate aqueous solution to initiate, and then add the remaining emulsion dropwise at 70-75°C while keeping warm. At the same time, add the remaining initiator ammonium persulfate aqueous solution dropwise, and complete the dropwise addition within 2.5-3 hours, then raise the tempe...
Embodiment 2
[0047] Emulsification reaction: In the pre-emulsion tank, fully mix deionized water 120, fatty alcohol polyoxyethylene ether XL90 2.5, sodium dodecylbenzenesulfonate 0.6, add isooctyl acrylate 73, methacrylate iso Bornyl ester 22, glycidyl methacrylate 2.5, trifluoroethyl methacrylate 12, vinyltrimethoxysilane 6, hydroxypropyl acrylate 1.8, and stir evenly to obtain a pre-emulsion.
[0048] Dissolve ammonium persulfate 0.7 plus deionized water 15 evenly and set aside.
[0049] Initiate polymerization reaction: Take 20% of the weight of the above emulsion and add it to the reaction kettle, raise the temperature to 70-75°C, add 25% of the weight of ammonium persulfate aqueous solution to initiate, and then add the remaining emulsion dropwise at 70-75°C while keeping warm. At the same time, add the remaining initiator ammonium persulfate aqueous solution dropwise, and complete the dropwise addition within 2.5-3 hours, then raise the temperature to 80-85°C and keep it warm for 1.5...
Embodiment 3
[0052] Emulsification reaction: In the pre-emulsion tank, fully mix deionized water 150, fatty alcohol polyoxyethylene ether XL90 3.5, sodium dodecylbenzenesulfonate 0.7, add isooctyl acrylate 75, methacrylic acid Isobornyl 28, glycidyl methacrylate 3, trifluoroethyl methacrylate 14, vinyltrimethoxysilane 7, and hydroxypropyl acrylate 2 were stirred evenly to obtain a pre-emulsion.
[0053] Dissolve ammonium persulfate 0.5 plus deionized water 12 evenly and set aside.
[0054] Initiate polymerization reaction: Take 20% of the weight of the above emulsion and add it to the reaction kettle, raise the temperature to 70-75°C, add 25% of the weight of ammonium persulfate aqueous solution to initiate, and then add the remaining emulsion dropwise at 70-75°C while keeping warm. At the same time, add the remaining initiator ammonium persulfate aqueous solution dropwise, and complete the dropwise addition within 2.5-3 hours, then raise the temperature to 80-85°C and keep it warm for 1.5...
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