29 results about "Urushiol" patented technology

The invention discloses a high-barrier antibacterial packaging material, a preparation method thereof and a packaging bag, and belongs to the technical field of packaging, the packaging material comprises the following raw materials by weight: 75-85 parts of polylactic acid, 15-25 parts of poly (butylene succinate), 2-6 parts of epoxidized urushiol, and 1-3 parts of benzyl quaternary ammonium salt modified montmorillonite; the epoxidized urushiol is prepared by carrying out epoxidation reaction on urushiol and organic peroxy acid; the packaging material further comprises the following raw materials: 2-5 parts of sepiolite fiber loaded magnesium oxide; according to the invention, biodegradable polylactic acid and poly (butylene succinate) are taken as base materials, and epoxidized urushiol is taken as a reactive compatilizer, so that the compatibility between polylactic acid and poly (butylene succinate) is improved, and meanwhile, the binding property between a polymer matrix and benzyl quaternary ammonium salt modified montmorillonite and sepiolite loaded magnesium oxide is enhanced; the packaging material with good mechanical property, barrier property and antibacterial property is obtained.

According to the urushiol-modified resorcinol-formaldehyde resin and the preparation method thereof, through chemical grafting of urushiol and a resorcinol-formaldehyde prepolymer, flexible chain segments and natural active sites of urushiol are combined, the high bonding strength of the resorcinol-formaldehyde resin is achieved, and the resin has the advantages of being high in mechanical strength, high in mechanical strength and good in mechanical property. The modified resin with excellent heat resistance, hydrophobicity, bonding strength and environmental friendliness is prepared, the modified resin is used for replacing resorcinol-formaldehyde resin to be applied to tire tread rubber, heat resistance, wear resistance, hydrophobicity and wet skid resistance can be remarkably improved, and the modified resin is suitable for manufacturing of high-performance tires.

The present invention relates to a method for manufacturing flexible polyurethane foam having a coating layer formed thereon, the coating layer being formed on polyurethane foam (PUF). In addition, the coating layer is characterized by comprising yellow clay, a zeolite mineral, and a germanium raw material. Moreover, as the coating layer further comprises a urushiol extract, the present invention has remarkable effects including minimal alteration of the physical properties of the polyurethane foam, excellent antibacterial properties, enhanced far-infrared radiation, superior deodorization, odor reduction, and dehumidification capabilities, as well as heat-storage and heat-generation properties.

The invention belongs to the field of polymerization, and particularly relates to a cross-linked acrylate polymer and a preparation method thereof. A soft monomer (31.4%-37.4%), a hard monomer (1.7%-2.0%), acrylic acid (0.2%-3.0%), an urushiol glycidyl ether crosslinking agent (1.2%-18%) and a mixed solvent (50%-59%) are mixed according to a specific ratio, and a segmented dropwise adding process and a vacuum defoaming curing technology are combined to prepare the adhesive. Compared with the prior art, the cross-linked acrylate polymer has the following advantages: 1, the cross-linked acrylate polymer shows excellent heat resistance and can meet the ever-increasing requirements of the market on high-performance cross-linked acrylate polymers; 2, urushiol glycidyl ether is derived from natural raw lacquer, has functionality and sustainability, and has good environmental protection value; 3, the prepared cross-linked acrylate polymer keeps excellent performance in a high-temperature environment and is suitable for various high-temperature application scenes such as automobile manufacturing, military equipment and electronic materials, and the application range of the acrylic cross-linked acrylate polymer is further expanded.

The application discloses a spraying type urushiol antibacterial waterproof paint and a preparation method thereof, and belongs to the technical field of biomass paint, and comprises the following steps: carrying out a thermal polymerization reaction on urushiol and pyrogallic acid at high temperature to obtain a high-polyphenol polymer; then taking the high-polyphenol polymer as raw material, blending the high-polyphenol polymer with other additives, and then reacting with diisocyanate to obtain the urushiol antibacterial waterproof paint. The paint has good film forming property, corrosion resistance and antibacterial waterproof property, and can be widely applied to the fields of medical devices, food equipment, furniture decoration and building paint.

The invention discloses a green marine antifouling coating based on a urushiol-based eutectic solvent and a preparation method of the green marine antifouling coating, and belongs to the technical field of natural polymer antifouling coatings. The coating is composed of nano cuprous oxide, an auxiliary antifouling agent, an antibacterial agent, an auxiliary agent, a cross-linking agent, a photoinitiator, a urushiol-based eutectic solvent and an acrylate monomer. The preparation method of the coating is simple and convenient and comprises the following steps: mixing the components in proportion, coating the surface of a base material with the mixture, and curing by ultraviolet irradiation and baking. The coating is green and environment-friendly, free of emission of volatile organic compounds, high in raw material utilization rate, high in coating adhesion, good in mechanical property, synergistic and lasting in antifouling property, suitable for the field of marine antifouling and good in industrial popularization prospect and ecological application value.

The invention discloses a raw lacquer acrylic resin composite material, a preparation method and application, the composite material comprises the following components by mass: 5%-30% of raw lacquer or urushiol, 1%-2% of a catalyst, 1%-10% of an aldehyde substance, 10%-20% of a cross-linking agent, 10%-30% of acrylic resin, 25%-70% of a solvent, and 1%-5% of a thickening agent; the sum of the percentages of the raw materials is 100%. According to the raw lacquer, the molecular weight, viscosity and drying performance are improved through the reaction of aldehyde substances and the cross-linking agent, the molecular weight is further enhanced through the acrylic resin, the drying performance, weather resistance, flexibility and mechanical performance of the resin are improved, and the raw lacquer has the advantages of being small in viscosity and high in adhesive force; compared with the prior art, the acrylic resin has the advantages of high adhesion and yellowing resistance of acrylic resin, provides a new material for cultural relic protection and repair as a novel bio-based material, can be widely applied to the fields of furniture coating, lacquerware manufacturing, high-end printing, high-performance adhesives and the like, and has industrial application potential.

The application discloses a green micro-extraction method of urushiol compounds in lacquer tree. The method mainly comprises raw material pretreatment, high-speed grinding of raw materials, additives and stainless steel balls in a vortex instrument, then micro-extraction is carried out by means of ultrasonic cavitation or vortex oscillation, and finally centrifugation and filtration are carried out. The method can effectively extract and enrich urushiol compounds, the operation time is short, the urushiol can be efficiently enriched, and the extraction efficiency is improved. Meanwhile, the operation process is simple, the contact between the sample and the solvent is small, the risk of allergy caused by urushiol is greatly reduced, and the rapid extraction and analysis of urushiol can be realized.

The present application discloses a chitosan porous membrane and its preparation method and application. The present application utilizes the processes of electrospinning, urushiol cross-linking, and swelling to prepare a porous chitosan membrane with a nanoscale pore structure. By introducing oligomeric urushiol, a structure is constructed with chitosan molecules that are easily soluble in a swelling agent solution as the main chain and acid-resistant and hydrophobic polymeric urushiol as the cross-linking bridge. This allows for slow and controllable swelling of chitosan nanofibers, solving the problem of precise and effective control of the pore size and structure of the chitosan membrane. Furthermore, the nanofiber swelling process is utilized to transform the disordered stacked nanofiber precursors formed by electrospinning into a cross-fused continuous network, thereby forming a continuous porous membrane with high strength.

The present invention discloses a cardanol emulsion, a preparation method thereof and a method for using the same in reinforcing archaeological paint films, belonging to the technical field of cultural relics protection. The preparation method of the cardanol emulsion includes: a cardanol monomer dispersion step: taking 1-4 parts of cardanol, 1-3 parts of a solvent, 1-3 parts of an emulsifier, and 4-6 parts of water, mixing the cardanol and the solvent in an appropriate ratio to form a dispersion; an emulsification step: sequentially adding the emulsifier and water to the dispersion, and fully mixing evenly to form a cardanol emulsion. In the present invention, cardanol penetrates into the damaged archaeological paint film, and through the catalysis of fungal laccase, cardanol reacts with the broken urushiol polymer fragments in the paint film to in-situ generate oligomers similar to raw paint films, playing a role in repairing the holes in the paint film, promoting the healing of the cracks in the paint film, and improving the strength of the paint film. The present invention simulates the film-forming process of raw lacquer, ensures the maximum compatibility between the reinforcing material and the cultural relic body, and at the same time has the remarkable advantages of environmental friendliness.

The invention relates to the technical field of composite coatings, in particular to a nano zinc stannate modified urushiol composite coating and a preparation method thereof. The paint comprises urushiol and zinc stannate powder. According to the invention, the urushiol is subjected to oxidative polymerization with a long alkyl side chain through a high-activity phenolic hydroxyl group of the urushiol, so that a three-dimensional cross-linked network skeleton is formed, and basic film-forming property and adhesive force are provided; zinc stannate nanoparticles and urushiol molecular chains form hydrogen bonds / chemical bonds through surface hydroxyl groups, and the zinc stannate nanoparticles are embedded into pores of a cross-linked network to construct a rigid reinforcement phase, so that the interface bonding strength is synergistically improved; zinc / tin ions released by zinc stannate are chelated with the urushiol degradation intermediate, a compact ceramic barrier layer is formed at a high temperature, free radicals are captured, oxygen diffusion is inhibited, and therefore hardness strengthening, adhesive force improving and heat stability enhancing are synergistically achieved.

The application discloses cellulose acetate nanofiber membrane and a preparation method and application thereof, and the preparation method comprises the following steps: mixing cellulose acetate and N,N-dimethylacetamide, heating to 50-60 DEG C under stirring and stirring at the temperature for 6-8 h to obtain a first mixed solution, adding urushiol into the first mixed solution to obtain a second mixed solution, heating to 70-80 DEG C under stirring and stirring at the temperature for 4-6 h to obtain a third mixed solution, cooling to room temperature, adding anhydrous copper sulfate into the third mixed solution under stirring, continuing to stir for 4-6 h to obtain a spinning solution, and performing electrostatic spinning on the spinning solution to obtain the cellulose acetate nanofiber membrane. The cellulose acetate nanofiber membrane has high acid resistance, prevents clothes covered with the cellulose acetate nanofiber membrane from being corroded and damaged by acidic agents during use, has good killing effect on escherichia coli and staphylococcus aureus, and also has good killing effect on influenza A virus.

The invention discloses modified raw lacquer and a preparation method thereof. The modified raw lacquer contains modified urushiol shown in a formula (I) and is prepared by performing esterification reaction on dialkyl phosphonyl chloride and urushiol in an inert atmosphere. The modified raw lacquer has excellent flame retardant property. The preparation method is simple in process, the grafting rate reaches up to 82%, and the method is suitable for the fields of furniture, handicrafts, buildings, chemical engineering and the like.

The invention belongs to the technical field of traditional Chinese medicine extract combined disinfectants, and discloses a traditional Chinese medicine extract composite disinfectant based on mulberry leaf, cocklebur fruit and resina toxicodendri ternary synergy and a preparation method thereof. A disinfection system with a three-dimensional synergistic effect is formed by taking a mulberry leaf flavonoid substance as an antibacterial synergistic carrier, taking a siberian cocklour fruit glycoside component as a cell membrane penetrating agent and taking a dry lacquer phenol derivative as a broad-spectrum bactericidal element through compounding in a specific ratio and stabilizing treatment. Compared with the prior art, the invention has the following breakthrough progresses: 1, sterilization performance: the killing rates of staphylococcus aureus (ATCC6538) and escherichia coli (8099) acting for 10 minutes respectively reach 99.96% and 99.93%, and the medical high-level disinfection requirements of Technical Specifications for Disinfection are met; 2, stability: the retention rate of the active ingredients is greater than 95% after 6 months of accelerated test at 50 DEG C, and no precipitate is separated out after 180 days of storage at normal temperature; and 3, economic benefits: the production cost is reduced by 62% compared with that of a Japanese nano packaging technology, and the shelf life is prolonged by 3 times.

This invention discloses a UV-curable raw lacquer hybrid prepolymer coating and its preparation method, comprising: rosin acid, hydroxyethyl acrylate, p-toluenesulfonic acid, polymerization inhibitor, 4-acryloyloxybenzophenone, polyethylene glycol methyl ether acrylate, azobisisobutyronitrile, refined raw lacquer, trimethylolpropane triacrylate, leveling agent, and defoamer. The coating uses rosin acid as a rigid framework, forming a macromolecular photoinitiator by side-linking benzophenone photoinitiator groups and flexible polyether segments. Then, through a controllable UV pre-irradiation process, it undergoes free radical grafting with lacquer urushiol to construct a "rigid-tough tunable" hybrid network. This invention solves the problems of slow curing of raw lacquer, easy migration of small-molecule photoinitiators, and high coating brittleness in existing technologies. The coating uses a macromolecular photoinitiator design, with the initiating groups fixed to the rosin framework through chemical bonds, fundamentally solving the migration problem. Furthermore, the "pre-grafting" process improves compatibility, endowing the coating with excellent comprehensive properties.

The invention belongs to the technical field of traditional Chinese medicine calcining, and particularly relates to a dry paint calcining method. The calcining method of the dry paint comprises the following steps: (1) crushing and sieving a dry paint raw material; (2) the sieved dry paint is put into a medicine calcining furnace, a sealing cover is fastened, and a 1 cm hole is reserved in the center of the sealing cover; (3) starting a medicine calcining furnace for calcining; (4) shutting down the medicine calcining furnace, and taking out the dry paint; the calcining temperature in the step (3) is 350 + / -3 DEG C to 380 + / -3 DEG C. The calcined dry lacquer obtained by the dry lacquer calcining method provided by the invention is high in urushiol content, the total ash content does not exceed 8%, the acid-insoluble ash content does not exceed 5%, and the total ash content and the acid-insoluble ash content all meet the specified standard in Chinese Pharmacopoeia.

The invention discloses a lacquer ware pattern transfer printing method based on a raw lacquer medium, which belongs to the technical field of porcelain processing, and specifically comprises the following five steps: selection of a transfer printing medium, coating of the transfer printing medium, image transfer printing, removal of drawing paper and reinforcement and color protection. The natural raw lacquer coating with the urushiol content of 80% or above serves as a lacquer pattern transfer printing medium, namely, a raw lacquer coating is coated on the lacquer surface again, the compatibility problem of the transfer printing medium raw lacquer coating is well solved, the raw lacquer coating is self-contained and totally natural, the attractiveness of pattern pictures is ensured, meanwhile, special image transfer printing equipment is adopted, and the production cost is reduced. And the whole technology is low in cost, easy and convenient to operate and suitable for mass production of lacquerware.

The present invention discloses a high-color-yield, low-waste-gas environmentally friendly thickener and its application in a printing process. The raw materials of the high-color-yield, low-waste-gas environmentally friendly thickener in the present invention include: 30-40 parts of acrylic acid monomer, 1-3 parts of methacrylate urushiol ester monomer, 40-50 parts of neutralizer, 3-5 parts of heavy oil, 20-30 parts of white oil, 1-3 parts of cross-linking agent, 1-2 parts of initiator, 2-3 parts of emulsifier, and 2-3 parts of diverting agent; the emulsifier includes urushiol polyoxyethylene ether and span-80 in a mass ratio of 0.3-0.5:0.7-1.2. The present invention adds urushiol methacrylate ester monomer to copolymerize with acrylic acid monomer, and adds urushiol polyoxyethylene ether to the emulsifier, so that heavy oil and white oil can be used instead of kerosene as the continuous phase during emulsion preparation. The prepared thickener has good thickening and electrolyte resistance while not containing components such as kerosene that have a large pollution to the environment, meeting the needs of printing production.

The invention provides a method for detecting mango urushiol. The method comprises the following steps: (1) extracting; (2) purifying; and (3) detecting. The pretreatment bottleneck of a high-sugar and high-moisture sample is broken through a liquid nitrogen rapid freezing and crushing technology, and the problems of long drying pretreatment process time and urushiol loss in the drying process in traditional detection are solved; the improved betaine-lactic acid DES is used as an extracting agent to replace traditional trichloromethane, so that the extraction rate is increased, and green and efficient extraction is realized. In general, the invention provides a mango urushiol detection method with high sensitivity and operation safety.

The invention belongs to the technical field of raw lacquer materials, and particularly relates to anacardol and urushiol thermal polymer modified raw lacquer liquid and a preparation method thereof. The modified raw lacquer liquid is prepared by adding a cardanol / urushiol thermal polymer into a raw lacquer liquid and uniformly mixing, wherein the mixing mass ratio of the cardanol / urushiol thermal polymer to the raw lacquer liquid is (1: 0.25)-(1: 4). The anacardol and urushiol thermal polymer is prepared by mixing anacardol and urushiol according to a mass ratio of 3: 7-9: 1 and then heating at 160-200 DEG C for 3-40 hours. The modified raw lacquer liquid belongs to a whole bio-based product and is dried into a film through laccase catalytic polymerization, and the drying time is short. The preparation method is simple and easy to implement, no VOC (volatile organic compound) is discharged in the preparation and use processes, the environment-friendly effect is achieved, a product paint film is excellent in hardness, glossiness, flexibility and the like, the paint film is light in color, color paint is easy to prepare, and the paint can be applied to the field of industrial and civil coating.

The application discloses a sodium alginate / urushiol-based water-based paint modifier, which is prepared by the following steps: firstly, pre-supporting treatment of alpha-zirconium phosphate is carried out by using cetyltrimethylammonium bromide, and in-situ reduction of the alpha-zirconium phosphate is carried out to generate urushiol titanium, so as to obtain a urushiol-based corrosion inhibitor; simultaneously, grafting of sodium alginate is carried out by using dodecyl triethoxysilane, so as to obtain amphiphilic sodium alginate; then, the obtained urushiol-based corrosion inhibitor and the obtained amphiphilic sodium alginate are stirred and uniformly mixed in deionized water, and the water-based paint modifier is prepared by ball milling. The prepared water-based paint modifier has good hydrophilicity and corrosion inhibition effect, and when the water-based paint modifier is used in water-based paint, the long-term corrosion resistance of the water-based paint to a metal substrate can be effectively improved.

This patent discloses a lacquer-based DA-bond self-healing coating and its preparation and application methods. The coating film exhibits high hardness, excellent corrosion resistance and antibacterial properties, and can autonomously repair microcracks under thermal stimulation when applied to material surfaces. 67-74 parts of raw lacquer (urushiol mass fraction ≈ 65%) undergo vacuum degassing pretreatment. Separately, 11-18 parts of N,N′-(4,4′-methylenediphenyl)bismaleimide are dissolved in anhydrous ethanol to prepare a homogeneous BMI-ethanol solution. The BMI-ethanol solution is slowly added to the pretreated raw lacquer and stirred. Then, 1-4 parts of triethylamine and 1-4 parts of pentaerythritol tetrakis(3,5-di-tert-butyl-4-hydroxyphenylpropionic acid) ester are added sequentially to continue the reaction. A thermally reversible three-dimensional network is constructed using the Diels-Alder reaction between the inherent conjugated diene of the urushiol side chain and the maleimide groups of BMI. The final product is cured and defoamed to obtain the lacquer-based DA-bond self-healing coating.

The invention relates to the technical field of polymer composite materials, in particular to mussel-imitating anti-corrosion and anti-fouling integrated resin and a preparation method thereof. The preparation method comprises the following steps: firstly, carrying out addition reaction on unsaturated C = C double bonds on a long side chain of urushiol and hydrogen-terminated polydimethylsiloxane under the action of a catalyst to prepare organic silicon modified urushiol; then, blending the organic silicon modified urushiol with epoxy resin to prepare organic silicon-containing urushiol modified epoxy resin; and finally, cooling the urushiol modified epoxy resin containing organic silicon to room temperature, adding a stoichiometric curing agent, coating on the surface of a base material, and curing at normal temperature or heating to form a film. The spontaneous gradient layering effect in the curing process is achieved through molecular structure design, an anti-corrosion barrier layer and a low-surface-energy anti-fouling active surface can be synchronously constructed in a single coating system, and an innovative solution with engineering economy and environment compliance is provided for ship whole-life-cycle maintenance.

This invention discloses a high-barrier antibacterial packaging material, its preparation method, and packaging bags, belonging to the field of packaging technology. The packaging material, by weight, comprises the following raw materials: 75-85 parts polylactic acid (PLA), 15-25 parts polybutylene succinate (PBS), 2-6 parts epoxidized urushiol, and 1-3 parts benzyl quaternary ammonium salt modified montmorillonite. The epoxidized urushiol is obtained by epoxidation of urushiol with organic peroxyacid. The raw materials also include 2-5 parts of sepiolite fiber-supported magnesium oxide. This invention uses biodegradable PLA and PBS as base materials and employs epoxidized urushiol as a reactive compatibilizer to improve the compatibility between PLA and PBS while strengthening the bonding between the polymer matrix and benzyl quaternary ammonium salt modified montmorillonite and sepiolite-supported magnesium oxide, thus obtaining a packaging material with good mechanical properties, barrier properties, and antibacterial properties.

The invention discloses an artificial urushiol monomer prepared based on a fused ring aromatic compound and a terpenoid. The artificial urushiol monomer is obtained through the Friedel-Crafts alkylation reaction between the easily-prepared fused ring aromatic compound and the cheap and easily-obtained terpenoids or derivatives thereof, the synthetic method is relatively short in route, and the product can be directly used without purification. The prepared artificial urushiol monomer is free of sensitization, has good film-forming property, can be used for preparing various photosensitive coatings, and has good application potential in the fields of photocatalysis, fluorescence sensing and the like.

The invention relates to the field of bio-enzyme synthetic high polymer materials, and particularly discloses a preparation method of an enzymatic self-assembled urushiol functional membrane, by introducing polyporus bellis laccase and utilizing plant source urushiol to directionally and enzymatically synthesize the urushiol functional membrane, the limitation that the urushiol depends on lacquer tree laccase to form a membrane in the prior art is effectively broken through, and the application prospect is broad. The technical problems that lacquer tree laccase is high in price, large in extraction difficulty and the like are solved, and an example for catalyzing urushiol to form a film through exogenous laccase is provided. According to the method for forming the urushiol film through self-assembly of the laccase, green, environment-friendly, simple, convenient, efficient, specific and definite preparation of the functional film through the enzymatic reaction is achieved, a material basis is provided for research and function development of urushiol film forming, and meanwhile theoretical and technical supports are provided for follow-up industrial production and utilization of urushiol biomass coatings.

The application provides application of urushiol derivatives in a lacquer extract in preparation of anti-myocardial fibrosis drugs. The urushiol derivative is shown as a structural general formula I. In the formula I, R1 represents H or -OH, R2 represents a straight-chain alkyl of C 10 -C 20 , or a straight-chain alkyl of C 10 -C 20 containing at least one substituent of a double bond, C=O, COOH, OH, or -Q-R4, wherein Q represents a straight-chain alkyl of C 10 , and R4 represents a substituted or unsubstituted benzene ring, or -QCO-R4, wherein Q represents a straight-chain alkyl of C 10 , and R4 represents a substituted or unsubstituted benzene ring, or -QCOO-R5, wherein Q represents a straight-chain alkyl of C 10 , and R5 represents C1-C6 alkyl; and R3 represents at least one of H, -OH, HCO-, CH3CO-, CH3CH2CO-. The results of a pharmacological activity experiment show that the compound has better inhibition activity on myocardial fibrosis.

This invention relates to a water-based dyeing process for lacquered leather using natural lacquer, belonging to the technical field of leather dyeing and improvement of traditional techniques. The technical problem this invention aims to solve is the poor adhesion of existing mineral pigments to leather surfaces and the tendency for patterns to peel off. The key technical points of this invention include: firstly, pre-treating the leather surface; then preparing a lacquer layer on the pre-treated leather surface, formed by drying and curing natural lacquer at 20-30℃ and 60-80% relative humidity; next, preparing a natural plant-based paint solution and a mineral pigment dispersion; then, dripping the pigment dispersion onto the paint solution surface to draw the pattern; and finally, water-based dyeing of the lacquered leather surface by contacting the paint solution for 5-30 seconds; and finally, completing the color fixation process by drying at 20-30℃ and heat-fixing for 24-72 seconds. This invention significantly improves pigment adhesion by forming stable chemical bonds through the coordination complexation reaction between the phenolic hydroxyl groups of urushiol in the lacquer layer and the metal ions in the mineral pigments, achieving a color fastness of grade 4 or higher for both wet and dry rubbing. This invention is applicable to high-end leather goods, furniture, artworks, and home decorations.