Coating emulsion composition, and water/oil-repellent paper and making method
An emulsion composition, the technology of the composition, applied in the direction of coating, water repellent addition, etc., can solve the problems of difficulty in providing water and oil repellency, impaired water and oil repellency, etc.
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[0106] The present invention will be further described below by way of examples and comparative examples, but the present invention is not limited thereto. All parts and percentages in the examples are by weight.
[0107] Synthesis Example 1
[0108] Charge 498 grams of octamethylcyclotetrasiloxane, 2 grams of triethoxyphenylsilane, 50 grams of 10% aqueous sodium lauryl sulfate and 50 grams of 10% dodecylbenzenesulfonate in a 2 liter polyethylene beaker acid solution. Use a homogeneous mixer to emulsify each component uniformly, and after emulsification, slowly add 400 grams of water for dilution. Then emulsify twice under the pressure of 30 MPa by a high-pressure homogenizer to obtain a uniform white emulsion. The emulsion was then transferred to a 2-liter glass flask equipped with a stirrer, a thermometer, and a reflux condenser, and polymerization was carried out at 50° C. for 24 hours. Aging at 10° C. for 24 hours, then neutralized to pH 6.2 with 12 grams of 10% sodium...
Embodiment 5
[0131] Mix the following ingredients together:
[0132] Component (a): 100 grams of linear methyl polysiloxane (degree of polymerization is 1000, hydroxyl content is 0.004 mol / 100 grams),
[0133] Component (b): 1 g of reaction product of maleic anhydride and 3-aminopropyltriethoxysilane (molar ratio=1 / 1),
[0134] Component (c): 15 grams of untreated dry silicon dioxide (with a BET surface area of 200 square meters per gram and an average particle size of 10 nanometers),
[0135] Component (d): linear polysiloxane (the degree of polymerization is 30, the organic group connected to the silicon atom is 10% octyl group, 2% propoxyl group, and the rest is methyl group) 3 grams ,
[0136] Sodium Lauryl Sulfate 10g
[0137] 129 grams of water,
[0138] And use a homogeneous mixer for uniform emulsification to form a uniform white water-based polysiloxane resin emulsion. The emulsion is a water-repellent and oil-repellent polysiloxane-based composition containing 50% active i...
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