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477 results about "Hydrogen sulphide" patented technology

Rectification mechanism and carbon disulfide production system comprising same

The invention discloses a rectification mechanism and a carbon disulfide production system containing the same. The rectification mechanism comprises an integrated rectification tower, and an inner cavity of a shell of the integrated rectification tower is sequentially divided into a function-integrated pre-separation and sulfur removal area, a main rectification and hydrogen sulfide removal area and a condensation reflux area from bottom to top in the vertical direction; the pre-separation and sulfur removal area comprises a settling tank arranged at the lower part of the shell, a gathering cover arranged above the inner wall of the settling tank, and a gas rising pipe I arranged above the gathering cover; the invention belongs to the technical field of chemical separation, and achieves the technical effects that multi-stage functions of pre-separation, main rectification, precise purification, final condensation and the like are innovatively integrated in a single tower, so that the fundamental simplification and compactness of the equipment structure are realized; in the traditional process, separate coarse removal, fine removal and finished product towers are replaced by unique expanded settling tanks in the towers, filler layers of integrated plate heat exchangers, tower tops with spiral condensation channels and side-draw systems.
Owner:SHANGHAI BAIJIN CHEM GROUP

Method for preparing 12-mercaptan through solid organic acid catalysis

The invention discloses a method for preparing 12-mercaptan through solid organic acid catalysis, belongs to the technical field of 12-mercaptan preparation, and aims to solve the problems of low catalyst activity, harsh reaction conditions, serious pollution, high cost and dependence on import in the prior art. N-dodecanol and hydrogen sulfide are used as raw materials and are mixed according to the molar ratio of 1: 1.2-1: 1.3; the method comprises the following steps: gasifying n-dodecanol, mixing with purified hydrogen sulfide, preheating to 210-240 DEG C, introducing into a fixed bed reactor filled with a solid organic acid catalyst, and reacting at-0.08-3.0 MPa for 3.5-4 hours; and cooling and condensing the reaction product, carrying out gas-liquid separation, rectifying and purifying the liquid product to obtain 12-mercaptan with the purity of more than or equal to 99.5%, and recycling unreacted hydrogen sulfide. The solid organic acid can be a catalyst of p-toluenesulfonic acid and the like or mesoporous silica loaded nickel, cobalt and molybdenum metal oxides. The method has the advantages of high catalytic activity, mild reaction conditions, high product yield (the conversion rate of n-dodecanol is greater than or equal to 94.5%), environmental protection and low cost, can realize the domestic mass production of 12-mercaptan, and meets the market demand.
Owner:GANSU QINYU BIOTECHNOLOGY CO LTD

Method for preparing lithium sulfide through cooperation of vacuum molten salt based on hydrogen sulfide-lithium salt reaction

A method for synergistically preparing lithium sulfide by vacuum molten salt based on hydrogen sulfide-lithium salt reaction belongs to the technical field of battery materials, and comprises the following steps: placing a lithium salt solid in a reactor, introducing a molten salt medium on the surface of the lithium salt or in a reaction system, introducing purified hydrogen sulfide gas under a vacuum auxiliary condition, controlling the reaction temperature to be 200-500 DEG C, and reacting for 1-2 hours; and adjusting the flow rate of hydrogen sulfide to be 50-1000mL / min and the retention time to be 5-180min, continuously exhausting gas to discharge water vapor in the reaction process, stopping introducing hydrogen sulfide gas after the reaction is finished, cooling the system to room temperature under the protection of inert gas, taking out the product, washing to remove residual fused salt, and carrying out vacuum drying to obtain the high-purity lithium sulfide. The prepared lithium sulfide has high purity (greater than or equal to 99.90%), low defect density and an excellent crystal structure, and can be widely applied to lithium-sulfur batteries, all-solid-state batteries and novel energy storage technologies, so that the energy density is improved, the cycle life is prolonged, and the energy consumption is reduced.
Owner:山西铁峰化工有限公司

Preparation method of lithium sulfide

The present invention relates to a method for preparing lithium sulfide, according to the present invention, when preparing lithium sulfide by a reaction between a lithium raw material and hydrogen sulfide, the reaction is carried out under relatively mild conditions compared to the prior art, so that frequent maintenance or replacement due to corrosion and failure of a reactor and various pipes is not required, thereby improving the economical efficiency of the process. Further, by reusing the unreacted hydrogen sulfide from which moisture has been removed and the solvent, process costs can be reduced, and economical efficiency can be ensured during mass production. Furthermore, moisture and water vapor generated in the lithium sulfide generation reaction are effectively removed, thereby preventing a reverse reaction for generating lithium hydroxide, promoting a positive reaction, and producing high-quality lithium sulfide with high purity and high yield. In addition, the particle size can be adjusted in units, and a separate pulverizing space or pulverizing table is not required, so that convenience and mass productivity are excellent.
Owner:LEIJINGKE TECHNOLOGY CO LTD

Triazine desulfurizer and preparation method thereof

The invention discloses a triazine desulfurizer and a preparation method thereof, and belongs to the technical field of gas purification. The triazine desulfurizer is mainly prepared from the following raw materials in percentage by weight: 20 to 50 weight percent of triazine derivative, 10 to 15 weight percent of sterically hindered amine, 3 to 7 weight percent of stabilizer, 1 to 3 weight percent of synergist, 0.5 to 1.5 weight percent of penetrant, 0.5 to 1.5 weight percent of inhibitor, 1 to 2 weight percent of additive and the balance of water, the preparation method of the triazine derivative comprises the following steps: adding 2-(diphenylphosphino) ethylamine into a toluene solvent, adding a paraformaldehyde aqueous solution in batches under a stirring condition, and reacting for 2-8 hours to obtain the triazine derivative. According to the triazine desulfurizer and the preparation method thereof provided by the invention, the triazine derivative and the sterically hindered amine are taken as a host, and the stabilizer, the synergist, the penetrant, the inhibitor and the assistant are compounded, so that the scaling trend of the triazine desulfurizer in an oil and gas well can be slowed down, the dissolution rate of hydrogen sulfide and the mass transfer rate in a solution are increased, and the desulfurization reaction is promoted; the desulfurization effect and the desulfurization rate are improved, and meanwhile, a very good scale inhibition effect is also achieved.
Owner:PETROCHINA CO LTD

RGO / CuO / Li sensitive material, preparation method thereof and application of rGO / CuO / Li sensitive material in H2S sensor

The invention belongs to the technical field of semiconductor oxide gas sensors, and particularly relates to an rGO / CuO / Li sensitive material, a preparation method thereof and application of the rGO / CuO / Li sensitive material in H2S sensors. The preparation method comprises the following steps: firstly, preparing a graphene oxide nanosheet by using an improved Hummers method, and then preparing the rGO / CuO / Li sensitive material by using copper nitrate, lithium chloride and the prepared graphene oxide nanosheet as raw materials, polyvinylpyrrolidone as a surfactant and N, N-dimethylformamide as a solvent by using a one-step solvothermal method. Under the condition of room temperature, the sensitive material shows a relatively high response value (220.1) and a relatively low detection lower limit (1ppb) on hydrogen sulfide, has good selectivity, repeatability and stability, and has a wide application prospect in trace-level hydrogen sulfide detection in the fields of industrial safety and atmosphere detection.
Owner:NORTHEASTERN UNIV CHINA

Liquid sulfur removal agent and preparation method thereof

The invention provides a liquid sulfur removal agent and a preparation method thereof, and belongs to the technical field of natural gas hydrogen sulfide removal treatment.The liquid sulfur removal agent comprises, by weight, 36-66% of s-triazine derivatives, 5-8% of sulfolane, 2-5% of a pH control agent, 10-12% of a stabilizer, 5-8% of a scale inhibitor, 1-2% of a bactericide and the balance deionized water; wherein the s-triazine derivative is selected from a mixture of hexahydro-1, 3, 5-triacetyl-hexahydros-triazine, 1, 3, 5-triacetyl-hexahydros-triazine and 1, 3, 5-triazinane-2, 4-diketone, and the structural formula of the s-triazine derivative is shown in the description. The liquid sulfur removal agent is high in sulfur removal efficiency, good in corrosion inhibition and sterilization performance and not prone to scaling.
Owner:CHINA PETROLEUM ENG & CONSTR +1

Boron-nitrogen-doped aluminum oxide catalyst as well as preparation method and application thereof

The invention relates to the technical field of acid tail gas treatment, and discloses a boron-nitrogen-doped aluminum oxide catalyst as well as a preparation method and application thereof. The method comprises the following steps: (1) mixing an aluminum source, a nitrogen source, a boron source and water to obtain a mixed solution, then adding a peptizing agent to adjust the pH of the mixed solution to be acidic, and then standing and aging; (2) drying the material subjected to standing and aging in the step (1), then roasting under protective gas, and then sequentially carrying out high-temperature nitriding and cooling; and (3) carrying out plasma treatment on the material cooled in the step (2). The catalyst prepared by the method has large specific surface area and catalytic activity, can well capture water and carbonyl sulfide, converts carbonyl sulfide into hydrogen sulfide and improves the purity and yield of enriched hydrogen sulfide, and the preparation method of the catalyst is simple and efficient.
Owner:CHINA ENERGY GRP NINGXIA COAL IND CO LTD +1

Method for producing lithium sulfide in a circulating bed reactor

The present invention relates to a process for preparing lithium sulfide (LiS) from lithium hydroxide (LiOH) and hydrogen sulfide (HS), characterized in that the lithium hydroxide is sulfided in a reaction zone (9) comprising at least one moving-bed tubular reactor (9a) with an ascending oscillating spiral configuration, in which the lithium hydroxide (4) circulates countercurrently to an anhydrous gas mixture (10) containing hydrogen sulfide and at least one inert gas.
Owner:EURECAT SA

Method for producing solid electrolyte, and electrolyte precursor

The present invention relates to a production method of a solid electrolyte in which adopting a liquid-phase method, a solid electrolyte having a high ionic conductivity, in which the generation of hydrogen sulfide is suppressed, the method including mixing a raw material inclusion containing a lithium element, a sulfur element, a phosphorus element, and a halogen element with a complexing agent containing a compound having at least two tertiary amino groups in the molecule; and an electrolyte precursor constituted of a lithium element, a sulfur element, a phosphorus element, a halogen element, and a complexing agent containing a compound having at least two tertiary amino groups in the molecule.
Owner:IDEMITSU KOSAN CO LTD

Preparation method of magnetic recoverable catalyst and method for synthesizing 3-mercaptopropionic acid

The invention provides a preparation method of a magnetic recoverable catalyst and a method for synthesizing 3-mercaptopropionic acid, and mainly solves the problem that a large amount of acid and alkali solutions are needed in the existing acrylonitrile-sodium hydrosulfide and acrylic acid-thiourea process routes. The thiohydracrylic acid synthesis catalyst is prepared. The use conditions of the catalyst are as follows: the temperature is 30-80 DEG C, the reaction pressure is 0.5-3 MPa, the mass ratio of the acrylic acid to the solvent is 0.1-5, and the mass ratio of the acrylic acid to the catalyst is 0.2-20. Compared with the prior art, the catalyst disclosed by the invention is used as a synthetic catalyst for preparing thiohydracrylic acid through reaction of acrylic acid and hydrogen sulfide, a solid catalyst and a liquid reaction system can be completely separated by adopting simple methods such as filtration, centrifugation or magnetic separation, and a complicated pickling step is not needed; and the problem that a homogeneous catalyst is difficult to rectify after salification in the use process is avoided.
Owner:HUBEI XINGFA CHEM GRP CO LTD +1

Apparatus and method for producing lithium sulfide

PendingCN122321783AThermodynamicsSulfidation
This invention relates to the field of chemical equipment technology, and discloses a lithium sulfide preparation device and method, comprising: an insulated shell; a reactor rotatably disposed inside the insulated shell, with a heating chamber formed between the reactor and the insulated shell; a rotating shaft fixed to one end of the reactor, passing through one end of the insulated shell and rotatably engaging with a support assembly; a rotating assembly connected to the rotating shaft to drive its rotation; and a heat source inlet pipe fixed to one end face of the insulated shell to communicate with the interior of the heating chamber. This invention utilizes a dynamic reactor, causing the solid material to continuously tumble and shift during the reaction process, greatly increasing the contact area between the solid phase and the gaseous hydrogen sulfide, enhancing mass transfer efficiency, significantly improving product purity and reaction efficiency, shortening the production cycle, reducing equipment investment and energy consumption, and facilitating large-scale industrial production of high-purity lithium sulfide.
Owner:ANHUI TAIHENGTE TECH CO LTD

Battery system

The battery system (100) comprises a single cell (10) made of a sulfide-based all-solid-state battery, a battery module (200) in which a plurality of single cells (10) are stacked between a pair of restraining members (31, 32), an intermediate plate (60) disposed between the stacked single cells (10), a detection unit configured to detect a load applied to the intermediate plate (60), and an estimation unit (300) configured to estimate the generation of hydrogen sulfide in the single cell (10) based on a change in the load applied to the intermediate plate (60).
Owner:TOYOTA JIDOSHA KK

Process and device for finely removing impurities from carbon monoxide after cryogenic separation of synthesis gas

The invention belongs to the technical field of coal ethylene glycol, and particularly relates to a process and a device for finely removing impurities from carbon monoxide after cryogenic separation of synthesis gas, the device comprises an impurity removal device, the impurity removal device comprises a desulfurization tank, a dechlorination tank and a decarbonylation tank which are sequentially connected in series, or an adsorption tower which is sequentially filled with desulfurization, dechlorination and decarbonylation adsorbents; the impurity removal device is arranged to remove trace hydrogen sulfide, hydrogen chloride, carbonyl iron and carbonyl nickel in CO after cryogenic separation, so that ppb-level removal of impurities in CO is realized, poisoning of a downstream dimethyl oxalate (DMO) synthesis catalyst is avoided, the service life of the catalyst is prolonged, the production cost of an enterprise is reduced, and the operation stability of the device is improved.
Owner:新疆天业汇合新材料有限公司

Flushing system for sodium hydrosulfide solution storage tank

The utility model relates to the technical field of chemical engineering, in particular to a sodium hydrogen sulfide solution storage tank flushing system which comprises a magnetic turning plate liquid level meter, a remote transmission liquid level meter, a sodium hydrogen sulfide storage tank, a condensation water pipeline, an upper flushing line, a lower flushing line and a remote transmission flushing line. A lower end inlet of the magnetic flap liquid level meter is connected with a lower end drain valve; a first short-circuit wire is led out from the sodium hydrosulfide storage tank to be connected to an outlet in the upper end of the magnetic flap liquid level meter, a second short-circuit wire is led out from the sodium hydrosulfide storage tank to be connected to an outlet in the lower end of the magnetic flap liquid level meter, a third short-circuit wire is led out from the sodium hydrosulfide storage tank to be connected to the remote transmission liquid level meter, and a remote transmission shower valve is arranged on the third short-circuit wire. On-line flushing of the sodium hydrogen sulfide solution storage tank is achieved, when liquid level display is different from remote liquid level, water flushing is carried out, checking is carried out again after flushing, and the operation risk is reduced.
Owner:DALIAN FUJIA DAHUA GASOLINEEUM CHEM

Hydrogen sulfide synthesis skid-mounted system

The utility model discloses a hydrogen sulfide synthesis skid-mounted system which comprises a liquid sulfur transfer module, a hydrogen sulfide synthesis module, a product gas pretreatment module, a product gas purification module, a tail gas treatment module and a public engineering module, the liquid sulfur transfer module, the hydrogen sulfide synthesis module, the product gas pretreatment module, the product gas purification module and the tail gas treatment module are sequentially communicated, and the product gas pretreatment module and the product gas purification module are both communicated with the liquid sulfur transfer module. According to the hydrogen sulfide synthesis skid-mounted system disclosed by the utility model, each functional component is modularized, the size of each module is configured in a coordinated manner and meets the transportation condition, corresponding process pipelines, instrument components, cables and the like can be prefabricated and mounted when leaving a factory, and debugging work can be carried out only by simple assembly and construction on a construction site; the workload of a construction site is greatly reduced, waste of installation materials is effectively reduced, and the device has the advantages of being small in occupied area, low in construction cost and the like.
Owner:CHANGSHA HASKY ENVIRONMENTAL PROTECTION TECH DEV CO LTD

Hydrogen sulfide scavenger for acid fracturing and preparation method thereof

The invention discloses a hydrogen sulfide scavenger for acid fracturing and a preparation method thereof, and relates to the technical field of hydrogen sulfide scavengers, the hydrogen sulfide scavenger comprises the following raw materials by weight: 30-45 parts of an aldehyde compound, 30-45 parts of an alcohol amine compound, 10-18 parts of a diamine bridging agent, 2-6 parts of a solubilizing compounding agent, 20-30 parts of a solvent and 1-3 parts of a catalyst; the aldehyde compound is divided into a component A and a component B, the mass ratio of the component A to the component B is 2: 1-3: 1, the component A is paraformaldehyde, and the component B is at least one of glyoxal or glutaraldehyde. By optimizing a molecular skeleton and introducing a hydrophilic group, the sulfur removal capacity and chemical stability in a strong acid environment are improved, compatibility with acid liquor is good, generation of acid sludge and insoluble precipitates is effectively inhibited, secondary damage to a stratum is avoided, and the high efficiency and mass transfer performance of a product are guaranteed through the preparation process.
Owner:CHENGDU HUAYANG XINGHUA CHEM CO LTD

Process for preparing 1,2-benzisothiazoline-3-one

The invention relates to a process for preparing 1,2′-benzisothiazoline-3-one according to formula (I), comprising the following steps: (a) reacting a 2-halogenbenzonitrile compound of general formula (II) with a reaction mixture, containing: (i) alkaline sulphide and / or alkaline hydrogen sulphide and (ii) an alkyl halide compound, represented by general formula (III): R1X (III) for producing an intermediate product of general formula (IV), and (b) reacting the intermediate product of general formula (V) obtained in step (a) with a halogenating agent or an oxidant and subsequent reaction of the 2-(alkylsulfoxy)benzonitrile with an acid to form 1,2-benzisothiazoline-3-one as well as a halide compound of general formula (V) R1X (V).
Owner:THOR GMBH

A tert-nonylthiol and its synthesis method

This invention provides a tert-nonylthiol and its synthesis method. The synthesis steps are as follows: nonene and hydrogen sulfide are preheated separately, then the preheated nonene and hydrogen sulfide are mixed, and the mixture is reacted under the action of a catalyst to obtain tert-nonylthiol. The preheating temperature of nonene is 40-50℃, and the preheating temperature of hydrogen sulfide is 50-60℃. This invention provides mild reaction conditions and precise preheating of nonene and hydrogen chloride separately. The product prepared by this method has a purity of over 99.0%, meeting the requirements of high-end industrial applications for high-purity tert-nonylthiol.
Owner:FUNUO (NINGXIA) CHEM TECH CO LTD

Preparation method for synthesizing lithium sulfide from industrial-grade lithium hydroxide and sodium sulfide, preparation method of solid electrolyte and solid-state battery

The invention provides a preparation method for synthesizing lithium sulfide from industrial-grade lithium hydroxide and sodium sulfide, a preparation method for a solid electrolyte and a solid-state battery, and the preparation method for synthesizing lithium sulfide from industrial-grade lithium hydroxide and sodium sulfide comprises the following steps: dissolving an industrial-grade lithium hydroxide raw material, and sequentially carrying out oxidation, filtration, washing and drying to obtain lithium sulfide; sodium sulfide and a flocculating agent are added for precipitation and filtration, then sodium carbonate and barium nitrate are sequentially added for impurity removal and filtration, and a lithium hydroxide purified solution is obtained; reacting the sodium sulfide solid with dilute sulphuric acid to obtain hydrogen sulfide gas; hydrogen sulfide gas is introduced into the lithium hydroxide purification liquid for a reaction, and lithium sulfide slurry is obtained; evaporating, concentrating and crystallizing the lithium sulfide slurry, and centrifugally separating; and carrying out vacuum calcination on the crystal, and crushing to obtain lithium sulfide powder. Through oxidative conversion, chemical precipitation and crystallization purification, efficient and deep removal of impurities is realized, the problems that raw material components are complex and difficult to separate are solved, and the purity of lithium sulfide is improved.
Owner:SHENZHEN ZHISHENG ENERGY TECHNOLOGY CO LTD

Liquid phase indirect preparation method of high-purity lithium sulfide

The invention discloses a liquid-phase indirect preparation method of high-purity lithium sulfide, and belongs to the field of fine chemical engineering. The preparation method comprises the following steps: firstly, enabling metal lithium to react with high-purity naphthalene at low temperature in an ether solvent in an anhydrous oxygen-free argon atmosphere to generate naphthyl lithium; then introducing high-purity hydrogen sulfide and a naphthyl lithium carrier to react at room temperature to generate lithium hydrosulfide; then converting at 100-150 DEG C to generate lithium sulfide; and cooling, filtering in an argon atmosphere, washing with an ether solvent, and carrying out vacuum drying to obtain high-purity finely-dispersed lithium sulfide with the purity of more than 99.99%. Compared with the prior art, the lithium sulfide obtained by the preparation method disclosed by the invention is powder which is high in purity, uniform in granularity, fine in dispersion and relatively good in flowability, is stable in process and product quality, can be suitable for industrial-scale production of high-purity lithium sulfide, and has a very good popularization and application value.
Owner:CHENGDU HUIEN FINE CHEM

Method and system for process control

A method for controlling a chemical process, by preparing methanol, hydrogen sulfide, methyl mercaptan, hydrocyanic acid, acrolein, 3-methylthiopropionaldehyde, 5-(2-methylmercaptoethyl)-hydantoin, methionine, a salt of methionine, and a derivative of methionine. The method includes providing a training set TS1, wherein TS1 is process values PV1 and process values PV2 being correlated to one another, and / or laboratory values LV1 and process values PV2 being correlated to one another. The method includes training a processing unit on the training set TS1 to identify a pattern of correlation between one or more measured process variables and at least one process variable. The method includes developing a calibration function CF1 for a calibrated soft sensor from the identified pattern of correlation and predicting at least one operating parameter for the chemical process as an approximation to LV1 and / or PV1. A system for controlling a chemical process.
Owner:EVONIK OPERATIONS GMBH

A method for in-situ suppression of hydrogen sulfide production

This invention relates to a method for in-situ suppression of hydrogen sulfide generation using fermentation broth. The specific method includes: concentrating sludge from a municipal wastewater treatment plant to increase its solids content; treating anaerobic fermentation broth from an anaerobic sludge treatment tank to remove SCFAs and soluble phosphorus, then storing it for later use; mixing the concentrated sludge with the treated fermentation broth in a certain proportion; pretreating the sludge substrate by controlling pH and temperature; and finally, anaerobic treating the sludge, maintaining stable continuous flow operation of the reactor by controlling the sludge retention time. Results show that this treatment method can significantly suppress hydrogen sulfide generation during anaerobic sludge treatment. Through a simple, inexpensive, and effective operation, utilizing wastewater treatment plant byproducts, this method achieves waste-to-waste treatment, reducing the generation of toxic and harmful gases such as hydrogen sulfide during anaerobic sludge treatment, which is of great significance for sludge treatment and disposal.
Owner:HUNAN UNIV

Electrostatic precipitator system for dust treatment

This invention discloses an electrostatic precipitator system for dust treatment, relating to the field of rubber production technology. It includes a pretreatment unit, a main treatment unit, and a post-treatment unit. The pretreatment unit includes a cyclone alkali spray tower, the main treatment unit includes a wet electrostatic precipitator, and the post-treatment unit includes a demister filter and an activated carbon adsorber. This invention employs a tiered process: cyclone alkali spray tower pretreatment, wet electrostatic precipitator main treatment, and demister filter and activated carbon adsorber post-treatment, targeting different types of pollutants. The pretreatment stage efficiently removes oily substances, large particulate dust, and hydrogen sulfide, creating suitable conditions for the main treatment; the electrostatic precipitator stage achieves deep dust separation; and the demister filter stage intercepts residual fine dust and water mist. This multi-stage synergy ensures efficient waste gas purification.
Owner:ANHUI FUYUN ENVIRONMENTAL TECHNOLOGY CO LTD

A tail gas absorption device for phenothiazine production

PendingCN122076213ASolve the problem of small inertia and difficulty in capturingAccurate temperature controlOrganic chemistryDispersed particle separationActivated carbonPhysical chemistry
This application relates to the field of tail gas absorption technology, specifically disclosing a tail gas absorption device for phenothiazine production. The pretreatment mechanism in this application can induce sublimation of phenothiazine microcrystals in the tail gas through multiple stages, allowing the microcrystals to grow sufficiently to a collectable size before entering the collection zone. Then, a multi-stage blade collection mechanism progressively adheres and collects the grown microcrystals, achieving efficient recovery of the phenothiazine microcrystals. Simultaneously, an absorption tower is set up to absorb hydrogen sulfide from the collected tail gas with alkaline solution, and an activated carbon adsorption tower is set up to deeply purify residual hydrogen sulfide and volatile organic compounds. This forms a complete treatment chain with graded treatment and each stage performing its specific function, effectively solving the problem of blockage caused by microcrystals directly entering the absorption tower in existing technologies, while also achieving the recycling of high-value products.
Owner:HUBEI PRETTY CHEM TECH CO LTD

08cr2almoe-21 steel and a preparation method thereof

This invention relates to the field of alloy preparation technology, specifically to a 08Cr2AlMoE-21 steel and its preparation method. This invention discloses a 08Cr2AlMoE-21 steel and its preparation method. This invention employs EBT electric arc furnace smelting-LF refining-VD vacuum refining-continuous casting processes, combined with strict control of elements such as carbon, silicon, manganese, phosphorus, sulfur, chromium, aluminum, molybdenum, oxygen, hydrogen, and nitrogen, to develop a low-alloy heat-resistant steel grade 08Cr2AlMoE-21 specifically designed to resist hydrogen sulfide stress corrosion. The 08Cr2AlMoE-21 prepared by this invention possesses both excellent mechanical and processing properties, and the finished pipe exhibits strong corrosion resistance, meeting application requirements.
Owner:CHANGSHU LONGTENG SPECIAL STEEL CO LTD

Two-photon fluorescent probe for detecting industrial hydrogen sulfide or sodium sulfide and preparation method thereof

The application discloses a kind of two-photon fluorescent probe for detecting industrial hydrogen sulfide or sodium sulfide and a preparation method thereof, and relates to the technical field of fluorescent probe.The application designs and synthesizes a compound with D-Π-A structure, which can be used as a two-photon fluorescent probe to selectively detect H2S, and is suitable for detecting H2S or Na2S residue in industry, with high sensitivity and good specificity.The reaction product of the compound and H2S can be used as an organic fluorescent dye.
Owner:ANHUI HERYI CHEM +1

A highly efficient desulfurizing agent, its preparation method, and its application in the desulfurization of heavy naphtha.

This invention relates to the field of petrochemical catalytic desulfurization technology, specifically disclosing a high-efficiency desulfurizing agent, its preparation method, and its application in the desulfurization of heavy naphtha. The desulfurizing agent provided by this invention has a "two-level" metal active center. The first level is a cobalt center in biochar, and the second level is a nickel-copper bimetallic center introduced through impregnation on the surface of a composite carrier. The desulfurizing agent provided by this invention has excellent desulfurization effect. Under conditions of 140°C and no hydrogen, it can simultaneously remove inorganic sulfur such as hydrogen sulfide and organic sulfur such as thiols, thioethers, and thiophenes from heavy naphtha obtained by hydrocracking of heavy diesel oil, wax oil, or mixed diesel and wax oil, reducing the total sulfur content from 25-40 μg·g. ‑1 Reduced to 0.2 μg·g ‑1 The following methods can effectively protect bimetallic (multimetallic) reforming catalysts from sulfur poisoning, and the preparation process is green and controllable, making it suitable for large-scale industrial applications.
Owner:HUBEI HUABANG CHEM +1

Preparation method of hydrogen sulfide gas sensor

The invention discloses a preparation method of a hydrogen sulfide gas sensor, and belongs to the field of gas sensors, according to the method, the arrangement regularity of nanospheres in the self-assembly process is effectively improved by optimizing technological parameters such as the inclination angle of a silicon wafer and the concentration of the nanospheres, and the pattern quality and stability of a mask are remarkably improved; meanwhile, the high-quality mask is applied to preparation of a hydrogen sulfide gas sensor, indium oxide (In2O3) and copper oxide (CuO) targets are sputtered on the surface of a silicon wafer at the same time through a magnetron sputtering oblique target co-sputtering process, and a thin film with a nano-composite structure is formed. According to the film, the high electron mobility of In2O3 and the high catalytic activity of CuO on H2S are fully utilized, and high-sensitivity and high-selectivity detection on H2S gas is realized. And a new technical path and a new solution are provided for the development of a hydrogen sulfide gas monitoring technology.
Owner:SINY OPTIC COM CO