67 results about "Dissolved hydrogen" patented technology

The invention discloses a method, a system, a medium and equipment for predicting hydrogen in oxygen of an alkaline electrolysis system, and the method comprises the steps: obtaining a total calculation formula for predicting hydrogen in oxygen of the alkaline electrolysis system based on the contribution of dissolved hydrogen which is not separated by a gas-liquid separator, gaseous hydrogen which is not separated by the gas-liquid separator, electrolytic bath saturation diffusion and electrolytic bath supersaturation diffusion mechanisms to hydrogen in oxygen of the system; according to experimental data of the alkaline electrolysis system under different alkaline liquid circulation flow working conditions, calibrating a to-be-fitted coefficient; according to experimental data of the alkaline electrolysis system under different system pressure working conditions, calibrating a to-be-fitted coefficient; according to experimental data of the alkaline electrolysis system under different working current working conditions, calibrating a to-be-fitted coefficient; according to experimental data of the alkaline electrolysis system under different temperature working conditions, a to-be-fitted coefficient sum is calibrated; and inputting temperature, pressure, alkali liquor circulation flow and current experiment data of the alkaline electrolysis system, and calculating hydrogen in oxygen of the alkaline electrolysis system so as to output system HTO under different operation conditions in real time.

A process for producing an aldehyde is disclosed. The process comprises: hydroformylating an olefin to form the aldehyde using a hydroformylation catalyst; recovering an effluent stream comprising the aldehyde, hydrogen and the hydroformylation catalyst; passing the effluent stream to a stripper; contacting the effluent stream with a strip gas in the stripper to produce a stripped effluent stream having a lower hydrogen concentration than the effluent stream; and recovering the stripped effluent stream.

The present application relates to a kind of nano platinum colloids and its preparation method and its application, the average particle size of the nano platinum colloids is 50-100nm, D90 is 100-150nm, D10 is 30-70nm, zeta potential is-25mV to-40mV, pd I is 0.2-0.5, sphericity is 0.85-0.97.The nano platinum colloids prepared by the present application has small particle size, as catalyst has higher catalytic efficiency, can quickly capture hydrogen to occur reaction, is not influenced by hydrogen escape, is used in the detection reagent for determining the dissolved hydrogen concentration in water, reaction rate is fast, titration result is more accurate.

The present invention provides an aqueous formulation comprising fullerene, structured water having a three-dimensional helical structure of polygonal water molecules with hollow cavities, dissolved hydrogen, a mineral, and an additive. The formulation provides a stable and biocompatible fullerene, which can be surrounded by micelles. The aqueous formulation has long term stability, thereby maintaining the concentration of hydrogen dissolved in the aqueous formulation over time. Also provided are methods of treating cancer comprising administering to a subject in need thereof an aqueous formulation comprising a fullerene, structured water having a three-dimensional helical structure of polygonal water molecules of hollow cavities, dissolved hydrogen, a mineral, and an additive.

The utility model discloses a healthy water nourishing machine with an electrolytic hydrogen production water and membrane wire hydrogen mixing system. The healthy water nourishing machine comprises a water purifier module, an electrolytic hydrogen production water module and a membrane wire hydrogen mixing module, the alkaline electrolytic bath and the pressure membrane filament gas mixing unit are arranged on the water outlet main channel; the water outlet auxiliary channel conveys water to the membrane wire water tank; the proton membrane electrolytic bath, the membrane filament water tank and the membrane filament water pump are communicated through a membrane filament electrolysis water path; a hydrogen output gas path is arranged at the hydrogen generation end of the proton membrane electrolytic cell; and the hydrogen output gas path is connected with the pressure membrane wire gas mixing unit and can dissolve hydrogen into the water outlet main channel. According to the utility model, the technical bottleneck of the traditional single process is successfully broken through by innovatively integrating electrolytic hydrogen production water and membrane wire hydrogen mixing double systems, the stability of the core physical and chemical indexes of the electrolytic water is ensured by the double-channel shunting waterway design, and the hydrogen content is greatly increased through physical hydrogen mixing, so that healthy water which conforms to the indexes and is sterilized by ultraviolet rays is formed.

The application relates to the technical field of gas-liquid separation, and provides a device and a method for reducing hydrogen content in oxygen by using a multistage gas-liquid separation technology, which comprises a separator, the inner cavity of the separator is sequentially divided into a first separation cavity and a second separation cavity from top to bottom, and the first separation cavity is communicated with the second separation cavity; a gas-liquid cyclone inner part is arranged in the first separation cavity; a strong centrifugal force field generated by the gas-liquid cyclone inner part is used for making micron-sized bubbles in a hydrogen-electrolyte mixture coalesce and separate, and free-state fine bubbles in the hydrogen-electrolyte mixture are efficiently removed; a throttling device is arranged between the first separation cavity and the second separation cavity, over-saturated dissolved hydrogen in hydrogen-rich electrolyte after first separation in the first separation cavity is depressurized through the throttling device, the hydrogen is actively precipitated by using static pressure drop, and separation is completed in the second cavity, so that the purpose of reducing hydrogen content in oxygen is achieved. The two-stage progressive separation structure significantly improves the hydrogen separation efficiency, and reduces the hydrogen content in oxygen to a low level.

A method of operating an electrochemical cell including introducing an aqueous solution into the electrochemical cell, applying a current across an anode and a cathode to produce a product, monitoring the voltage, dissolved hydrogen, or a condition of the aqueous solution, and applying the current in a pulsed waveform responsive to one of the measured parameters is disclosed. An electrochemical system including an electrochemical cell including an anode and a cathode, a source of an aqueous solution having an outlet fluidly connectable to the electrochemical cell, a sensor for measuring a parameter, and a controller configured to cause the anode and the cathode to apply the current in a pulsed waveform responsive to the parameter measurement is disclosed. Methods of suppressing accumulation of hydrogen gas within the electrochemical cell are also disclosed. Methods of facilitating operation of an electrochemical cell are also disclosed.

This invention relates to the field of coal mine safety, specifically to a method for predicting the risk of hydrogen sulfide outbursts in coal seams. Currently, manual sampling for hydrogen sulfide gas detection in domestic mines is highly dangerous; furthermore, dissolved hydrogen sulfide is corrosive to mechanical measuring devices, resulting in low efficiency and the need for corrosion protection. This invention first determines the presence of geological water in the coal seam. If geological water is present, a small amount is deacidified and then tested with lead acetate test paper. If no geological water is present, a safe pH range is determined through mathematical statistics. While drilling into the coal seam at the measurement location in the tunneling face or return airway, the borehole flushing fluid is recovered, the pH value is measured, and the average value is calculated and compared with the safe pH range to determine whether there is a risk of hydrogen sulfide outbursts in the coal seam. This invention is highly practical in underground operations, highly safe, simple to operate, low in cost, and provides rapid and timely results, effectively ensuring the safety of underground workers and the safe and efficient production of coal mines.

The present invention relates to a functional composition for activating plant root respiration in soil and a method using the same. The present invention is a technology related to agricultural methods, in which an oxygen generating catalyst composition is prepared by dissolving an inorganic substance selected from the group consisting of aluminum, titanium, chromium, manganese, iron, cobalt, nickel, copper, zinc, tungsten, and a salt form selected from the group consisting of sulfate, chloride, nitrate, acetate, phosphate, fluoride, and a chelating agent, to a concentration of 0.05 to 25 wt% in stored water, and an oxygen generating composition is prepared by dissolving hydrogen peroxide or persulfate to a concentration of 50 wt% or less in stored water, and the A solution and the B solution are used in a C method in which the A solution is diluted to a concentration of 10 ppm to 900 ppm and sprayed, and then the B solution is diluted to a concentration of 25 ppm to 5,000 ppm and sprayed on a crop cultivation site, or in a D method in which the A solution is diluted to a concentration of 10 ppm to 900 ppm and stored in a container (A-1) equipped with a drain line and a discharge device, and the B solution is diluted to a concentration of 25 ppm to 5,000 ppm and stored in a container (B-1) equipped with a drain line and a discharge device, according to the crop cultivation environment, thereby achieving an oxygen agricultural method for crops to achieve high yield cultivation.

The utility model discloses a generator stator cooling water dissolved hydrogen measurement water sample backwater device which comprises a middle water storage tank, the top of the middle water storage tank is communicated with a monitoring device through a water inlet pipeline, and the lower end of the middle water storage tank is communicated with a generator stator cooling water tank through a double-pump system; a low-liquid-level sensor, a high-liquid-level sensor and a high-liquid-level sensor are arranged on one side in the middle water storage tank and used for monitoring the liquid level of the middle water storage tank; the device relates to the technical field of measurement water sample recovery, and is simple in structure, easy in function and high in reliability, meanwhile, the measured water sample is directly recovered to a generator stator cooling water tank, the water quality of generator stator cooling water is not affected, leakage and leakage are avoided, water resources are saved, and the device is suitable for popularization and application. Meanwhile, safe operation of generator stator cooling water is guaranteed, and different generator stator cooling water tank forms on site are met.

To provide a hydrogen gas concentration sensor for blood that can safely and easily measure the dissolved hydrogen concentration in blood simply by piercing the rubber stopper of the blood collection tube (blood collection vessel). [Solution] A hydrogen gas concentration sensor is provided in which a container's tubular section is placed inside the needle tube section, and a first electrode piece is provided protruding from this tubular section, for example, the first electrode piece, a second electrode piece and an electrolyte are placed inside the container or tubular section, and when the needle tube section is inserted into the rubber stopper of the blood collection tube, the dissolved hydrogen gas in the blood in the blood collection tube comes into contact with, for example, the first electrode piece and the electrolyte interposed in the gap, thereby measuring the dissolved hydrogen concentration in the blood.

The invention discloses a double-loop water chemical multi-parameter coordinated regulation and control test device for nuclear power material corrosion simulation. The double-loop water chemical multi-parameter coordinated regulation and control test device comprises a low-pressure water chemical pretreatment loop, a high-temperature and high-pressure corrosion simulation loop and a control module, the low-pressure water chemical pretreatment loop is connected with the high-temperature and high-pressure corrosion simulation loop through a pipeline and a valve, so that the test medium regulated and controlled by the low-pressure water chemical pretreatment loop is conveyed to the high-temperature and high-pressure corrosion simulation loop and flows back to the low-pressure water chemical pretreatment loop; the control module is electrically connected with the first monitoring component, the second monitoring component, the dissolved hydrogen / oxygen control unit, the dosing unit and the autoclave heating unit, receives and analyzes the hydrochemical parameter deviation of the low-pressure hydrochemical pretreatment loop and the high-temperature and high-pressure corrosion simulation loop by adopting a PID (Proportion Integration Differentiation) regulation algorithm, and dynamically regulates the working state of the execution unit; therefore, multi-parameter coordinated regulation and control are realized.

The invention discloses an optical fiber-palladium alloy membrane single hydrogen sensor machine control method based on temperature compensation, and relates to the technical field of online monitoring of power equipment. A hydrogen-sensitive sensing unit and a temperature compensation module are arranged in the sensor. The hydrogen-sensitive sensing unit and the temperature compensation module are arranged in parallel, are completely immersed in insulating oil, are in contact with oil flow and are used for monitoring dissolved hydrogen in situ in real time; the hydrogen-sensitive sensing unit adopts an optical fiber structure of which the side wall is plated with a palladium alloy nano-film, and is used for sensing the concentration of hydrogen dissolved in oil and generating corresponding optical signal change; the temperature compensation module adopts an optical fiber structure inert to hydrogen and is used for synchronously measuring the oil temperature of the position where the probe is located. By means of the structure and the matched control method, in-situ and real-time monitoring of the concentration of the hydrogen in the sleeve is achieved, the reliability and stability of hydrogen concentration monitoring data are greatly improved, a more accurate basis is provided for early fault diagnosis of a transformer, and the device and the method have great significance in guaranteeing safe operation of a power grid.

The utility model relates to the technical field of hydrogen mixing, and discloses a hydrogen mixing waterway and drink preparation equipment, which comprises at least one waterway (160 / 170) used for introducing / outputting hydrogen water and at least one hydrogen mixing device (130A / 130B), the input end of the hydrogen mixing device (130A / 130B) is connected with the output end of the waterway (160 / 170), the hydrogen mixing device (130A / 130B) is used for dissolving hydrogen in the waterway (160 / 170) into the hydrogen water, and the hydrogen mixing device (130A / 130B) is used for mixing the hydrogen in the waterway (160 / 170). A flow disturbing assembly (130b) is arranged on the input side of the hydrogen mixing device (130A / 130B), the flow disturbing assembly (130b) and the hydrogen mixing device (130A / 130B) are detachably arranged, a plurality of through holes (130h) are formed in the flow disturbing assembly (130b), and the hole diameters of the through holes (130h) are irregularly arranged.

The invention discloses a water recycling control method of a water electrolysis hydrogen production system and the hydrogen production system, and the control method comprises the following steps: after a hydrogen production starting signal is received, closing a first exhaust valve; determining whether the pressure in the hydrogen-water secondary liquid separation tank is greater than a preset pressure threshold value or not, and determining whether the liquid level in the hydrogen-water secondary liquid separation tank is smaller than a first preset liquid level or not; when the pressure in the hydrogen-water secondary liquid separation tank is larger than a preset pressure threshold value and the liquid level in the hydrogen-water secondary liquid separation tank is smaller than a first preset liquid level, a first exhaust valve is opened, so that gas in the hydrogen-water secondary liquid separation tank is exhausted through a back pressure valve, and the pressure built in the hydrogen-water secondary liquid separation tank is used as driving force; and the liquid water is pressed back to the pure water storage tank through the first drain valve. According to the invention, the technical problems of hydrogen escape loss, water resource waste, high energy consumption and system complexity caused by dependence on an external water pump when high-pressure pure water containing dissolved hydrogen separated from the cathode side is recycled in the existing electrolytic hydrogen production technology can be solved.

An aqueous formulation including a three-dimensional helical cage structure of polygonal water molecules, wherein the polygonal water molecules include two or more adjacent water molecules connected by hydrogen bridges, the helical cage structure has a central hollow lumen, and when viewed from a top, the helical cage structure has a hexagonal shape. The aqueous formulation also includes molecular hydrogen and at least one additive located within the central hollow lumen of the helical structure.

An oil chromatography online monitoring system device for transformer oil is characterized in that a hydrogen sensor (2), a temperature sensor (3), a pressure sensor (4), a flow sensor (5) and an oil pump (6) are respectively arranged on a first tube shell (1), a flow stabilizing valve (8) and a three-way joint (9) are respectively arranged on a second tube shell (7), and a first control valve (91) is arranged between the second tube shell (7) and the first tube shell (1); and a second control valve (92) is arranged between the three-way joint (9) and the oil chromatography online monitor (93), so that the fault transformer can be selected and distinguished according to a single fault gas content signal; the technical problem that the running state of the transformer is diagnosed and analyzed by monitoring the content of fault gas such as hydrogen, carbon monoxide, methane, ethylene, ethane, acetylene and carbon dioxide dissolved in oil through oil chromatography online monitoring is solved, and therefore the online monitoring effect of the terminal transformer is improved.

The present application relates to the technical field of boiler pipeline safety monitoring, in particular to an electrochemical impedance-dissolved hydrogen boiler four-pipe monitoring system. Through multi-modal collaborative monitoring technology, electrochemical impedance spectroscopy, dissolved hydrogen photoacoustic spectroscopy detection and ultrasonic thickness monitoring are integrated. An adaptive modal weight dynamic adjustment mechanism, a corrosion product layer thickness inversion module, a dissolved hydrogen photoacoustic signal enhancement algorithm, a multi-scale time series feature extraction module and a warning threshold dynamic updating mechanism are innovatively introduced. A CNN and attention mechanism Transformer hybrid model is used to fuse three modal data, a corrosion-leakage dynamic correlation model is established, and early corrosion and leakage of the boiler four-pipe are accurately warned. The present application solves the problems of one-sidedness of traditional single modal monitoring, inadaptability of data fusion to working condition changes, weak signal anti-interference ability, false alarm and missed alarm caused by fixed warning threshold, significantly improves the monitoring accuracy, warning accuracy and working condition adaptability, and provides reliable protection for safe operation of the boiler four-pipe.

1. The name of the design product: oil-filled electrical equipment dissolved hydrogen gas multi-parameter monitor. 2. The use of the design product: for monitoring the dissolved hydrogen gas in oil-filled electrical equipment multi-parameter. 3. The design points of the design product: in shape. 4. The picture or photo that best indicates the design points: perspective view 1. 5. The bottom view is the same as the top view, and the bottom view is omitted; the rear view is the same as the front view, and the rear view is omitted.

The invention relates to the technical field of electrochemical preparation of a water body containing dissolved hydrogen, and discloses an electrolysis method for improving hydrogen solubility by wave hydrogen mixing, which comprises the following steps: S1, adding a water source into an electrolytic bath to form an electrolyte system; s2, heating the electrolyte system to a target temperature and keeping the temperature; s3, applying electric energy to the electrolyte system for electrolysis; s4, a periodic fluctuation flow field and periodic pressure waves are formed in the wave structure action area through the diaphragm pump; s5, carrying out crushing treatment on the hydrogen bubbles; s6, enabling the micro-nano hydrogen bubbles to be in contact with the electrolyte system in the dissolving area and dissolving the micro-nano hydrogen bubbles; and S7, the concentration of dissolved hydrogen is detected on line, and pulsating flow parameters output by the diaphragm pump are adjusted. Pulsating flow is provided through a diaphragm pump, a hydrogen-containing gas-liquid mixture flows through a wave structure acting area, a periodic fluctuation flow field and pressure waves are formed, breaking is carried out, meanwhile, the dissolved hydrogen concentration is detected and adjusted, the dissolving process is in a controllable state, and the dissolved hydrogen concentration is kept within a preset target range.

This invention discloses a three-dimensional simulation method and system for dissolved hydrogen diffusion in an alkaline electrolyzer, belonging to the field of electrolyzer simulation calculation technology. The method includes: establishing a three-dimensional geometric model of an alkaline electrolyzer unit comprising bipolar plates, flow channels, electrodes, and a diaphragm; constructing a dynamic equilibrium module for dissolved hydrogen coupled with the hydrogen dissolution and evolution processes; constructing a diffusion simulation module including concentration diffusion, convection diffusion, and electroosmotic diffusion mechanisms; constructing a dynamic upper limit control model for dissolved hydrogen concentration, dynamically selecting the actual dissolved hydrogen concentration; coupling the determined actual dissolved hydrogen concentration to the diffusion simulation module to obtain the concentration distribution of dissolved hydrogen in the electrolyzer, and outputting simulation results including HTO based on the concentration distribution. This invention improves the prediction accuracy of HTO under low current density conditions by introducing a dynamic upper limit control mechanism for dissolved hydrogen concentration, simultaneously considering the dual constraints of generation rate limitations at low current densities and oversaturation limitations at medium to high current densities.

The invention discloses a ZSM-5 molecular sieve, a catalyst, preparation methods of the ZSM-5 molecular sieve and the catalyst, and application of the ZSM-5 molecular sieve and the catalyst in liquid-phase isomerization reaction of xylene. According to the ZSM-5 molecular sieve disclosed by the invention, the peak area ratio of framework aluminum to non-framework aluminum in the ZSM-5 molecular sieve is (1.05-5.5): 1 according to a 27Al NMR (Nuclear Magnetic Resonance) characterization result; in addition, the molar ratio of SiO2 / Al2O3 of the ZSM-5 molecular sieve is less than or equal to 20; the size of the ZSM-5 molecular sieve is less than or equal to 100nm. The nano ZSM-5 molecular sieve with the low silica-alumina ratio is prepared, the ZSM-5 molecular sieve has the advantages of nano size, low silica-alumina ratio, high activity and high stability, and the ZSM-5 molecular sieve has a specific peak area ratio of skeleton aluminum to non-skeleton aluminum. The catalyst prepared by adopting the ZSM-5 molecular sieve disclosed by the invention has very high p-xylene concentration and very low C8 aromatic hydrocarbon loss rate when being used in a xylene liquid phase isomerization reaction under the condition of dissolved hydrogen (trace hydrogen), and has a very good application effect.

To provide a hydrogen water production apparatus and a production method capable of stably producing hydrogen water having a low hydrogen concentration.SOLUTION: A hydrogen water production device comprising a hydrogen gas generator, a deaerator for deaerating ultrapure water, a gas dissolving device for dissolving hydrogen gas in the ultrapure water deaerated by the deaerator, and a feed line for feeding the hydrogen gas generated by the hydrogen gas generator to the gas dissolving device, wherein the feed line feeds the hydrogen gas to the gas dissolving device at 2 to 45sccm.SELECTED DRAWING: Figure 1

The utility model discloses a kind of high-pressure-resistant dissolved hydrogen analyzers, it is related to dissolved hydrogen concentration measurement field.A kind of high-pressure-resistant dissolved hydrogen analyzer, including instrument body, the open flow cell of upper end part, dissolved hydrogen sensor, the dissolved hydrogen sensor is electrically connected with instrument body, further include: mounting disc, with the fixed connection of the dissolved hydrogen sensor, and for plugging the opening of the flow cell;The utility model is inclined upper end face design by fixed block, simplifies the installation step of dissolved hydrogen sensor and mounting disc, improves installation convenience, saves time, and the time and manpower cost of convenient assembly and disassembly lower maintenance, reduce operation damage risk, prolong the service life of instrument;Air bag pressurization cooperation sealing groove and sealing pad, greatly enhance the sealing effect of mounting disc and flow cell opening, effectively prevent sample leakage under high pressure environment, ensure measurement accuracy and avoid external impurity interference.

The utility model discloses a high-concentration alkalescence hydrogen-rich water production device which comprises a filtering device, a water electrolyzing machine, a degasser, a hydrogenation device, a filling machine, a cap screwing machine and a high-temperature sterilization device which are connected in sequence, the filtering device is used for filtering a water source, the water electrolyzing machine is used for electrolyzing the filtered water source, and the degasser is used for degasser. The degasser is used for completely removing dissolved gas in the electrolyzed water, the hydrogenation device is used for carrying out hydrogen dissolving treatment on the degassed water body, the filling machine is used for filling the hydrogenated water body, the cap screwing machine is used for carrying out cap screwing treatment on the filled tank body, and the high-temperature sterilization device is used for carrying out high-temperature sterilization treatment on the tank body. The high-quality hydrogen-rich water with the shelf life as long as 12 months or above, the ORP lower than-500 mv, the alkalescence higher than 9.5 and the dissolved hydrogen concentration higher than 3000 ppb can be produced, and the requirements of consumers for healthy and efficient functional drinks can be met.

A process for producing aldehydes is disclosed, the process comprising: hydroformylating an olefin using a hydroformylation catalyst to form an aldehyde, recovering an effluent stream comprising the aldehyde, hydrogen, and the hydroformylation catalyst, passing the effluent stream through a stripper, contacting the effluent stream with a strip gas in the stripper to produce a stripped effluent stream having a lower hydrogen concentration than the effluent stream, and recovering the stripped effluent stream.

The invention discloses a hydrogen-rich water generating device capable of efficiently dissolving and storing. The hydrogen-rich water generating device comprises a machine shell, a PEM electrolytic hydrogen production module, a nanometer bubble hydrogen dissolving module and a controller. The PEM electrolytic hydrogen production module, the nano-bubble hydrogen dissolution module and the controller are fixedly mounted in the shell; the PEM electrolytic hydrogen production module is used for preparing hydrogen by electrolyzing water and enabling the hydrogen to enter the nano-bubble hydrogen dissolution module; the nanobubble hydrogen dissolving module is used for dissolving the hydrogen prepared by the PEM electrolytic hydrogen production module in water in a micro-nanobubble form to form hydrogen-rich water; and the controller is used for controlling the PEM electrolytic hydrogen production module and the nano-bubble hydrogen dissolution module to prepare hydrogen-rich water. According to the hydrogen-rich water generation device, high-purity hydrogen-rich water can be obtained, it is fundamentally ensured that the final product water does not make contact with the anode and the whole oxygen evolution reaction area completely, and therefore pollution caused by any oxidizing by-products is completely eradicated.

The present application relates to natural gas processing technical field, especially to a kind of hydrogen sulfide removal device in oilfield associated natural gas, including cylinder and the water tank being located in the lower end of cylinder and being communicated with cylinder, water tank is equipped with water in inside and its top is inserted with air inlet pipe, cylinder is equipped with the support rod that can move longitudinally in inside, the top packing layer is fixed in the top of support rod, multiple subsidiary packing layers are hung below top packing layer, the support rod is used to drive top packing layer and subsidiary packing layer to be lifted to immerse it in water, make its surface attach water and obtain uniform liquid film, to dissolve hydrogen sulfide and form sulfur ion, and top packing layer and subsidiary packing layer are used to promote sulfur ion oxidation and form sulfur element;The present application obtains uniform liquid film using lifting packing layer, and compared with leaching, there is no short circuit and no leaching dead angle, and the device has leaching and reaction absorption function simultaneously, hydrogen sulfide absorbed by water is also oxidized and removed, removal efficiency is higher than pure leaching effect and there is no secondary pollution.

This invention discloses a method for synergistically controlling hydrogen sulfide and deeply denitrifying wastewater in urban drainage pipes, comprising the following steps: adding a suspended iron-based composite material to the urban drainage pipe; the suspended iron-based composite material flowing with the wastewater; in the urban drainage pipe, the ferric iron in the suspended iron-based composite material captures electrons, the dissolved hydrogen sulfide in the wastewater is oxidized, and the precipitates of ferrous sulfide and elemental sulfur generated by the reaction are loaded onto a carrier to obtain a reduced suspended iron-based composite material; the reduced suspended iron-based composite material is recovered at the outlet of the drainage pipe and added to a denitrification reaction tank; under anaerobic conditions, denitrifying microorganisms use ferrous sulfide and elemental sulfur as electron donors to perform denitrification, while ferrous iron is oxidized to ferric iron, resulting in a regenerated suspended iron-based composite material. This invention fundamentally reduces the need for chemical agents through "electron transport," achieving low-carbon, low-cost, and efficient treatment of urban water pollution.

An aqueous formulation comprising structured water comprising a plurality of water molecules in a planar orientation wherein adjacent water molecules are connected by hydrogen bridges to form hexagonal rings of water molecules, thereby forming planes of a two-dimensionally ordered hexagonal matrix arrangement, and a plurality of helical cage structures repeating in a plurality of planes stacked in a direction perpendicular to the plane of the two-dimensional ordered hexagonal matrix arrangement and connected via hydrogen bridges to form a plurality of layers of the two-dimensional ordered hexagonal matrix arrangement, thereby forming a plurality of three-dimensional helical cage structures of polygonal water molecules, each having a central hollow inner cavity, and each having a hollow inner cavity as viewed from above. Each having a hexagonal shape, and water dispensing means for producing the aqueous formulation. A water dispensing device comprising a structured water generator having a vortex generator.