The invention relates to a polymorphic
nonlinear optical crystal material of 3-amino-1, 2, 4-
triazole nitrate and preparation and application of the polymorphic
nonlinear optical crystal material, the
chemical formula of the polymorphic material is (C2H5N4) (NO3), the molecular weight is 147.11, and the polymorphic material specifically comprises two
crystal forms: (1) alpha-(C2H5N4) (NO3) belongs to a triclinic
system, the
space group is P1, the
cell parameters are alpha = 110.44-114.63 degrees, (2) beta = 93.04-97.71 degrees, gamma = 93.49-97.64 degrees and Z = 2, and compared with the prior art, the
cell volume of the polymorphic
nonlinear optical crystal material is larger than that of the prior art, and the
cell volume of the polymorphic
nonlinear optical crystal material is larger than that of the prior art The polymorphic alpha-(C2H5N4) (NO3) and beta-(C2H5N4) (NO3) materials involved in the invention have a relatively large frequency-doubled effect at 1064nm, and
phase matching can be realized by the polymorphic alpha-(C2H5N4) (NO3) materials and the polymorphic beta-(C2H5N4) (NO3) materials. In addition, the
ultraviolet absorption
cut-off edges of the crystal material are 240 nm and 248 nm respectively, and the crystal material has wide application prospects in the photoelectric technical fields of
laser frequency conversion, high-speed optical
signal modulation,
holographic storage systems and the like.