Composite flame retardant containing microcapsule-coated intumescent flame retardant and preparation method

A technology of intumescent flame retardant and composite flame retardant, which is applied in the field of flame retardant materials, can solve the problems of low flame retardant efficiency of a single flame retardant, and achieve the advantages of reducing smoke phenomenon, improving flame retardant efficiency and improving flame retardant efficiency. Effect

Inactive Publication Date: 2014-04-16
LIAONING TECHNICAL UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Most of the flame retardants in the above prior art use melamine-formaldehyde resin prepolymer, urea-formaldehyde resin prepolymer or epoxy resin to coat a single flame retardant such as ammonium polyphosphate, melamine phosphate, and the flame retardant of a single flame retardant Inefficiency, therefore, requires very high loadings to make the material flame retardant

Method used

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  • Composite flame retardant containing microcapsule-coated intumescent flame retardant and preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] The composite flame retardant containing microcapsule-coated expansion flame retardant of the present invention, its composition is by mass percentage: microcapsule expansion flame retardant 75%, flame retardant synergist aluminum hydroxide and red phosphorus add up to 15%, ph Smoke agent zinc borate 9%, hindered amine light stabilizer 770 1%.

[0025] Wherein said microcapsule-coated expansion flame retardant uses expansion flame retardant powder as core material and urea-formaldehyde resin as shell material, and said expansion flame retardant powder accounts for 65% of the total mass of expansion flame retardant The acid source material ammonium polyphosphate, the gas source material melamine and dicyandiamide accounting for 25% of the total mass of the intumescent flame retardant, and the carbon source material pentaerythritol accounting for 10% of the total mass of the intumescent flame retardant.

[0026] The specific preparation method is:

[0027] Weigh 650g of am...

Embodiment 2

[0031] The composite flame retardant containing microcapsule-coated intumescent flame retardant of the present invention is composed by mass percentage: 80% of microcapsule intumescent flame retardant, 12% in total of flame retardant synergist magnesium hydroxide and montmorillonite, The smoke suppressant antimony trioxide and ferrocene accounted for 6.8%, and the hindered amine light stabilizers 622 and 944 accounted for 1.2%.

[0032] Wherein said microcapsule-coated intumescent flame retardant uses intumescent flame retardant powder as the core material and urea-formaldehyde resin as the shell material, and the intumescent flame retardant powder accounts for 70% of the total mass of the intumescent flame retardant The acid source material melamine polyphosphate and PNP expansion flame retardant, the gas source material urea accounting for 18% of the total mass of the expansion flame retardant, and the carbon source material dipentaerythritol accounting for 12% of the total m...

Embodiment 3

[0037] The composite flame retardant containing microcapsule-coated expansion flame retardant of the present invention, its composition is by mass percentage: microcapsule expansion flame retardant 60%, flame retardant synergist organosilicon and carbon nanotube total 25%, ph Smoke agent molybdenum trioxide 10%, hindered amine light stabilizer 622 5%.

[0038] Wherein said microcapsule-coated expansion flame retardant uses expansion flame retardant powder as core material and melamine formaldehyde resin as shell material, and said expansion flame retardant powder accounts for the total expansion flame retardant powder The acid source material melamine cyanurate with a mass of 40%, the gas source material urea accounting for 30% of the total mass of the intumescent flame retardant powder, and the carbon source material dipentaerythritol accounting for 30% of the total mass of the intumescent flame retardant powder.

[0039] The specific preparation method is:

[0040] Weigh 40...

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Abstract

The invention belongs to the field of flame retardant materials, and particularly relates to a composite flame retardant containing a microcapsule-coated intumescent flame retardant and a preparation method. The composite flame retardant containing the microcapsule-coated intumescent flame retardant consists of the following components in percentage by mass: 60-94 percent of microcapsule intumescent flame retardant, 5-25 percent of flame-retardant synergist, 0.9-10 percent of smoke suppressant and 0.1-5 percent of hindered amine light stabilizer. The preparation method comprises the following steps: preparing the microcapsule-coated intumescent flame retardant; placing the microcapsule-coated intumescent flame retardant, the flame-retardant synergist, the smoke suppressant and the hindered amine light stabilizer into a high-speed mixer for mixing uniformly, and discharging to obtain the composite flame retardant containing the microcapsule-coated intumescent flame retardant. Multiple components in the composite flame retardant can play roles in retarding flame in a synergetic way, so that the flame retardance of a high polymer material is improved remarkably, the production of toxic and harmful smog in a burning process can be suppressed, and the flame retarding efficiency is increased greatly.

Description

technical field [0001] The invention belongs to the field of flame retardant materials, and in particular relates to a composite flame retardant containing a microcapsule-coated expansion flame retardant and a preparation method thereof. Background technique [0002] In recent decades, the application of polymer materials has advanced by leaps and bounds, and has received extensive attention in various fields, and the output of polymer materials has also increased year by year. Compared with metal materials and inorganic materials, polymer materials have unique physical properties and processing properties, but most polymer materials are flammable, and when burned, they emit toxic fumes that suffocate people. According to statistics, among the people who died in fire, more than 80% died of suffocation due to smoke loss or suffocation due to inhalation of toxic gas. It can be seen that the flammability of polymer materials brings hidden dangers to personal safety. Therefore...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08K13/06C08K9/10C08K3/32C08K5/3492C08K5/315C08K5/21C08K5/053C08K5/06C08L23/12
Inventor 洪晓东姜海艳秦昌强杨东旭
Owner LIAONING TECHNICAL UNIVERSITY
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