Styrene series non-halogen flame retardant injection-grade wood plastic composite and preparation method thereof

A wood-plastic composite material, styrene-based technology, applied in the field of styrene-based halogen-free flame-retardant injection molding grade wood-plastic composite materials, can solve the problems of poor appearance quality, low strength of parts, poor fluidity, etc., and achieve flame retardancy Less dosage, simple production process, good effect of halogen-free flame retardant

Active Publication Date: 2010-11-03
GUANGDONG KINGFA TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In addition, the existing wood-plastic preparation technology is mainly based on extrusion molding, die-casting molding and extrusion molding technology, which are mainly used for the production of plate products, which are greatly restricted for injection molded parts with complex molding structures. The main problem is Due to the poor fluidity of wood-plastic composite materials added with a large amount of wood powder, the strength of the parts is low and the appearance quality is poor
[0005] At present, there is no report on the flame-retardant modification of wood-plastic composite materials with red phosphorus flame retardants, and there are few reports on flame-retardant injection molding grade wood-plastic composite materials.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Raw material components are calculated by mass percentage as:

[0031] ABS resin: 46.9%

[0032] 100 mesh wood flour: 25%

[0033] ABS-g-MAH: 5%

[0034] ABS high rubber powder: 5%

[0035] Liquid paraffin: 1%

[0036] Butyl stearate: 1%

[0037] N,N'-bisethylene stearamide: 1%

[0038] Thermosetting resin coated red phosphorus: 5%

[0039] 3000 mesh superfine magnesium hydroxide: 10%

[0040] Antioxidant 1010: 0.1%

[0041] First dry the wood powder at 150°C for 4 hours, then mix it evenly in a high-mixer, then add it to the extruder to extrude and pelletize. The processing temperature is controlled at 170°C to obtain a halogen-free flame-retardant injection molding grade ABS. Wood-plastic composites.

[0042] The tested properties of the above-mentioned wood-plastic composite materials are as follows:

[0043] Specific gravity 1.18g / cm 3

[0044] Tensile strength 34.3Mpa

[0045] Elongation 7.1%

[0046] Izod beam unnotched impact strength 187J / m

[0047]...

Embodiment 2

[0052] Raw material components are calculated by mass percentage as:

[0053] HIPS: 42.4%

[0054] 100 mesh bamboo powder: 25%

[0055] HIPS-g-MAH: 5%

[0056] Oil-extended SBS: 5%

[0057] Liquid paraffin: 1%

[0058] Silane coupling agent: 0.5%

[0059] N,N'-bisethylene stearamide: 1%

[0060] Red phosphorus masterbatch (red phosphorus content 70%): 10%

[0061] 3000 mesh superfine magnesium hydroxide: 10%

[0062] Antioxidant 1010: 0.1%

[0063] First dry the wood powder at 150°C for 4 hours, then mix it evenly in a high-mixer, and then add it to the extruder to extrude and pelletize. The processing temperature is controlled at 170°C to obtain a halogen-free flame-retardant injection molding grade HIPS Wood-plastic composites.

[0064] The tested properties of the above-mentioned wood-plastic composite materials are as follows:

[0065] Specific gravity 1.17g / cm 3

[0066] Tensile strength 31.4Mpa

[0067] Elongation 8.1%

[0068] Izod beam unnotched impact st...

Embodiment 3

[0074] Raw material components are calculated by mass percentage as:

[0075] AS resin: 37.9%

[0076] 100 mesh bamboo powder: 30%

[0077] ABS-g-MAH: 5%

[0078] ABS high rubber powder: 5%

[0079] Liquid paraffin: 0.5%

[0080] Dibutyl phthalate: 0.5%

[0081] N,N'-bisethylene stearamide: 1%

[0082] Red phosphorus masterbatch (red phosphorus content 70%): 10%

[0083] 3000 mesh magnesium hydroxide: 10%

[0084] Antioxidant 1010: 0.1%

[0085] First dry the wood powder at 150°C for 4 hours, then mix it evenly in a high-mixer, then add it to the extruder to extrude and pelletize, and the processing temperature is controlled at 185°C to obtain halogen-free flame-retardant injection molding grade AS Wood-plastic composites.

[0086] The tested properties of the above-mentioned wood-plastic composite materials are as follows:

[0087] Specific gravity 1.17g / cm 3

[0088] Tensile strength 45.9Mpa

[0089] Elongation 5.6%

[0090] Izod beam unnotched impact strength ...

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Abstract

The invention discloses a styrene series non-halogen flame retardant injection-grade wood plastic composite and a preparation method thereof. The styrene series non-halogen flame retardant injection-grade wood plastic composite is prepared from the following components in percentage by mass: 25-60 percent of styrene series resin, 5-60 percent of plant fiber, 0.5-20 percent of compatilizer, 0-30 percent of flexibilizer, 0.5-8 percent of dispersing agent, 5-40 percent of fire retardant and synergetic fire retardant and 0-1 percent of antioxidant. Compared with the traditional wood plastic composite, the styrene series non-halogen flame retardant injection-grade wood plastic composite prepared by the invention has the characteristics of simple production flow, less consumption amount of fireretardant, good non-halogen flame retardant effect, wide range of moulding ways, and the like, and is suitable for various injection moulded parts such as shells of electric appliances, parts for vehicles, and parts for furniture and buildings, and the like.

Description

technical field [0001] The invention relates to the field of wood-plastic composite materials, in particular to a styrene-based halogen-free flame-retardant injection molding-grade wood-plastic composite material. Background technique [0002] In recent years, because wood-plastic composite materials have many advantages such as low cost and environmental protection, their market demand has grown rapidly, especially in interior products, construction and automotive products. But on the other hand, the fast-growing market demands put forward higher requirements on the performance of wood-plastic composite materials. Combustion modification, and for products with complex structures, processing methods other than extrusion, molding, etc. are required. [0003] In order to solve the flammability problem of wood-plastic composite materials, the method of adding flame retardants to wood-plastic composite materials is usually used for flame-retardant modification. It is well known...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L25/06C08L51/00C08L25/08C08L25/12C08L25/14C08L55/02C08L97/02C08K3/02C08K9/10C08K3/22C08K3/38C08K3/34
Inventor 付锦锋刘建中胡志华王林郭少华黄恒梅叶南飚
Owner GUANGDONG KINGFA TECH CO LTD
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