The invention discloses an organophosphorus conversion and
recovery method which comprises the following steps: step 1, adding a
calcium-doped catalytic material into organophosphorus-containing
wastewater, and complexing the catalytic material with organophosphorus to generate a complex containing a carbon-
phosphorus bond; step 2, irradiating the complex with light, so that a carbon-
phosphorus bond in the complex is cracked to obtain orthophosphate radical; and 3, combining the orthophosphate radical with
calcium ions in the catalytic material, and further treating to realize the
recovery of
calcium phosphate. According to the scheme,
organic phosphorus is subjected to photocatalytic oxidation, the efficiency is high, the high
salt water influence resistance is high, the secondary
pollution is low, the circularity is good, the excellent performance of adsorption and photocatalytic oxidation can be synergistically utilized, and the method is suitable for large-scale industrial production, popularization and application.