955 results about "Magnesium Hydrate" patented technology

The invention relates to a magnesia-carbon refractory material with high thermal shock resistance and erosion resistance and a preparation method thereof. The magnesia-carbon refractory material with high thermal shock resistance and erosion resistance is prepared from fused magnesia aggregate, fused magnesia fine powder, silicon powder, crystalline flake graphite, Al2O3-MgO-CaO core-shell structure raw materials and phenolic resin. The Al2O3-MgO-CaO core-shell structure raw materials are prepared by the following steps: uniformly mixing calcium carbonate, magnesium hydroxide and alumina micro powder by adopting a planetary ball mill, and then carrying out granulation treatment by adopting a disc granulator by taking polyvinyl alcohol as a binding agent, so as to obtain core particles; and mixing the inner core particles and the alumina micro powder by taking alumina sol as a binding agent, and further sintering to obtain the core-shell structure raw material. The Al2O3-MgO-CaO core-shell structure raw material is utilized to improve the comprehensive performance of the magnesia-carbon refractory material, and the prepared magnesia-carbon refractory material has excellent thermal shock resistance and slag corrosion resistance and can meet the requirements of the current steel industry for the magnesia-carbon refractory material.

The invention relates to a modified chrome corundum ramming material and a preparation and construction process thereof, and belongs to the technical field of chrome corundum ramming materials. The ramming material comprises a material A, a material B and a material C, wherein the material A comprises chrome corundum aggregate, titanium dioxide coated aluminum oxide microspheres, calcium sulfide dehydrate and silicon carbide porous microspheres; the material B comprises chromium oxide-zirconium oxide composite nano powder, sodium thiosulfate pentahydrate, tricalcium phosphate and hexagonal boron nitride flaky crystals; and the material C comprises an aluminum dihydrogen phosphate-magnesium hydroxide compound, a calcium fluoride-aluminum oxide co-melt and a silane coupling agent. The preparation process comprises the steps of pretreatment of all the components, preparation of composite powder and layered preparation. The construction process comprises the steps of pretreatment, wet-process mixing, layered ramming, negative-pressure permeation, medium-temperature reaction, spraying curing, integral firing and the like. Generation of hexavalent chromium can be effectively inhibited, the thermal shock resistance, the mechanical strength and the heat-conducting property of the material are remarkably improved, and the material has the advantages of being good in environment friendliness, long in service life, excellent in construction performance and the like.

The invention discloses a silane cross-linked polyolefin halogen-free flame-retardant cable material and a low-energy-consumption preparation method thereof.The preparation method comprises the steps that EVA / EEA serves as a matrix, silane groups are covalently connected to a polyolefin molecular chain through a free radical grafting reaction, and a grafting material containing an active silane side group is prepared; meanwhile, vinyl isocyanate is adopted to chemically modify hydroxyl on the surface of magnesium hydroxide, vinyl is grafted to the surfaces of particles, the polarity of the particles is reduced, and the dispersity of the particles is enhanced; then carrying out melt blending on the grafted material and modified magnesium hydroxide, constructing an interface bridge by using an anhydride group, and shortening the two-phase distance; finally, through room-temperature natural cross-linking and warm water auxiliary cross-linking, silane groups are promoted to be hydrolyzed into silanol, the silanol is condensed to form a-Si-O-Si-three-dimensional network, meanwhile, vinyl on the surface of magnesium hydroxide and a polyolefin matrix are subjected to free radical copolymerization, and a covalent bond interface layer is formed between inorganic particles and an organic matrix. According to the method, the synergistic improvement of high crosslinking degree, strong stretchability and excellent flame retardance of the cable material is realized through molecular-level interface regulation and cross-linking network optimization.

The invention discloses a high-temperature-resistant flame-retardant nylon composite material and a preparation method thereof, and belongs to the technical field of high polymer materials. The preparation method comprises the following steps: uniformly mixing 100-110 parts of nylon resin, 40-60 parts of a flame retardant, 1-3 parts of a lubricant, 0.5-2 parts of an antioxidant and 0.5-2 parts of an ultraviolet light absorber, adding the mixture into a double-screw extruder from a main feed, adding the flame retardant into the double-screw extruder from a side feed, and performing extrusion, bracing, cooling, pelletizing and drying to obtain the high-temperature-resistant flame-retardant nylon composite material. The flame retardant disclosed by the invention contains high-dispersity magnesium hydroxide and halogen-free flame-retardant elements, namely nitrogen, phosphorus and silicon, and does not contain any halogen, so that the flame retardant disclosed by the invention has the flame-retardant effects of high flame retardance, low smoke generation amount and low harmfulness, and the application field of a nylon composite material can be effectively widened.

Disclosed in the present invention are a 90°C thermoplastic halogen-free low-smoke flame-retardant polyolefin sheath material and a preparation method therefor. The sheath material is prepared from raw materials comprising the following components in parts by mass: 20-40 parts of an ethylene-vinyl acetate copolymer, 20-40 parts of a linear low-density polyethylene, 2-10 parts of a high-density polyethylene, 20-40 parts of a metallocene ethylene-octylene copolymer, 10-15 parts of a maleic-anhydride-grafted metallocene linear low-density polyethylene copolymer, 58-73 parts of aluminum hydroxide, 20-25 parts of modified magnesium hydroxide, 64-84 parts of a synergistic flame retardant, 2-3 parts of a coupling agent, 1-4 parts of a lubricant, 1-3 parts of an antioxidant, and 2-7 parts of a coloring agent, wherein the synergistic flame retardant comprises lithium oxide. A matrix resin has low-temperature performance, mechanical properties and cracking resistance. With regard to flame retardance, a large amount of the synergistic flame retardant, i.e., lithium oxide, is added to a traditional magnesium-aluminum compound flame-retardant system, and therefore an off-white hard shell can be formed during a combustion process while low heat release is ensured, thereby ensuring no dripping during the combustion process.

The environment-friendly cable ethylene-propylene insulation material comprises the following raw materials: ethylene propylene diene monomer, an elastomer, a reinforcing agent, a flame retardant, a vulcanizing activator, a filler, a plasticizer, an anti-aging agent, a vulcanizing agent and a silane coupling agent. 50-70 parts by mass of ethylene propylene diene monomer rubber; the elastomer is a POE (polyolefin elastomer) of 30-50 parts; the flame retardant is prepared from 30 to 50 parts of nano magnesium hydroxide, 5 to 10 parts of microencapsulated red phosphorus and 3 to 5 parts of zinc borate; and the plasticizer is paraffin oil. According to the ethylene-propylene insulating material, a halogen-free flame-retardant system is combined with an interface modification technology, so that the defects of poor mechanical property and high material toxicity of a traditional material are overcome. The oxygen index is greater than or equal to 38%, the tensile strength is greater than or equal to 10Mpa, and the material is suitable for high-risk mine environments.

The invention relates to the technical field of cables, and provides a high-temperature-resistant flame-retardant cable and a preparation method thereof. The high-temperature-resistant flame-retardant cable comprises a conductor and a flame-retardant outer sheath, the flame-retardant outer sheath is prepared from the following raw materials in parts by weight: 40 to 50 parts of linear low-density polyethylene, 35 to 45 parts of ethylene-vinyl acetate copolymer, 10 to 15 parts of ethylene propylene diene monomer, 15 to 18 parts of modified aluminum hydroxide, 10 to 14 parts of modified magnesium hydroxide, 5 to 8 parts of polyethylene grafted maleic anhydride, 5 to 8 parts of microencapsulated red phosphorus, 2 to 3 parts of silane coupling agent and 0.8 to 1 part of antioxidant. The composite material is prepared from the following components in parts by weight: 0.5-1 part of a light stabilizer, 0.5-1 part of calcium stearate, 0.8-1 part of polyethylene wax and 0.5-0.9 part of carbon nanotubes. According to the cable prepared in the invention, the performance stability of an existing high-temperature-resistant material in a high-temperature environment is improved, and the problems of softening, melting and the like of the cable are avoided.

The invention relates to a high-dispersity magnesium hydroxide flame retardant as well as a preparation method and application thereof. The flame retardant comprises a magnesium hydroxide crystal and a multifunctional composite group which is modified on the surface of the magnesium hydroxide crystal and is used for improving the flame retardant property, wherein the magnesium hydroxide crystal accounts for 90-98% by mass, and the multifunctional composite group accounts for 2-10% by mass; the multifunctional composite group is composed of an organosilicon group, an olefin group, a nitrogen-containing group, a hydrophilic group and a hydrophobic group. A magnesium hydroxide crude product is subjected to surface modification treatment by adopting the weakly hydrophobic and strongly hydrophobic modifiers, and wet modification and dry modification processes are combined, so that the distribution narrowness (span) of the flame retardant is improved, the dispersion effect and the compatibility of the material are further improved, and the overall flame retardant property of the material is remarkably improved; meanwhile, the mechanical property of the filling material is maintained or enhanced, and an innovative solution is provided for developing an efficient and environment-friendly polymer flame-retardant material.

The present invention provides a high-efficiency flame-retardant board and a preparation method thereof, relating to the technical field of flame-retardant boards. The board comprises the following components, by weight: 80-250 parts of reinforcing fiber cloth; 60-95 parts of boron phenolic resin; 40-70 parts of alcohol; 5-45 parts of magnesium hydroxide; 5-15 parts of ceramic filler; and a silicate and a catalyst. In the present invention, under the premise of ensuring an optimal silicate hydrolysis degree of 20%-40%, the amount of silicate used is accurately calculated based on the water content of the phenolic resin, the number-average molecular weight of the silicate, and the average degree of polymerization of the silicate, thereby reasonably setting the ratio of silicate to phenolic resin. The silicate is then further hydrolyzed with an acidic catalyst, resulting in a smooth and easy-to-control reaction process. The resulting resin material has both strength and heat resistance. After being uniformly mixed with an inorganic flame-retardant component, the board is impregnated with the reinforcing fiber cloth and pressurized to obtain a high-efficiency flame-retardant board. The overall preparation process is simple, the amount of raw materials used is precisely and reasonably controlled, and the board is particularly suitable for large-scale industrial promotion.

The invention discloses an anti-ultraviolet high-flame-retardant polyester fiber and a preparation method thereof. The polyester fiber is prepared from the following raw materials in parts by weight: 100 parts of polyester chips, 20-60 parts of core-shell flame-retardant anti-ultraviolet particles and 2-4.5 parts of an anti-dripping agent. According to the invention, a porous alumina-titanium dioxide compound is used as a carrier, a magnesium hydroxide flame retardant, iron-doped carbon dots with photo-thermal performance and auxiliaries (an antioxidant and an ultraviolet light absorber) are combined with the carrier to construct a structural system loaded with multiple active components: functionalized flame-retardant particles, and then a polyurethane microporous membrane is coated, so that the flame-retardant polyurethane composite material is obtained. The core-shell type flame-retardant anti-ultraviolet particles are added into polyester fibers, so that the anti-ultraviolet performance and the flame-retardant performance of the polyester fibers can be remarkably improved. The polyester fiber provided by the invention can adaptively increase the release rate of the ultraviolet absorbent and the antioxidant when the ultraviolet property is enhanced in the environment, so that more optimized protection can be provided for a polyester fiber matrix at the moment.

The invention relates to the technical field of cables, in particular to a high-flexibility ethylene-propylene insulating rubber material for a charging pile cable and a preparation process. The composite material comprises an ethylene propylene diene monomer, a thermoplastic polyolefin elastomer, an ethylene-butylene copolymer, nanoscale magnesium hydroxide, a silane coupling agent, dicumyl peroxide, a hindered phenol antioxidant and a phosphite antioxidant. The ethylene propylene diene monomer and the ethylene-butylene copolymer form a flexible network skeleton, and the ethylene-butylene copolymer and the thermoplastic polyolefin elastomer are subjected to molecular-level blending, so that the elongation at break and the bending fatigue resistance are improved; silane coupling agent modified nano magnesium hydroxide is chemically bonded with a rubber matrix, so that the flame retardance and thermal aging resistance are enhanced, and the negative influence of filler agglomeration on flexibility is reduced; the compound antioxidant system effectively inhibits thermal oxidation degradation at high temperature, avoids insulation failure, realizes collaborative optimization of high flexibility and high heat resistance, and improves the reliability and applicability of the charging pile cable.

The invention relates to the technical field of cables, and provides a corrosion-resistant insulated power cable. The corrosion-resistant insulated power cable is sequentially provided with a conductor layer, an insulating layer and a sheath layer from inside to outside, and the insulating layer is prepared from the following raw materials in parts by weight: low-density polyethylene, magnesium hydroxide and calcium carbonate composite powder, an antioxidant, dicumyl peroxide, zinc stearate and polyethylene wax; the sheath layer comprises the following raw materials in parts by weight: PVC resin, magnesium hydroxide and calcium carbonate composite powder, diisononyl phthalate, a calcium-zinc composite stabilizer, an antioxidant, polyethylene wax and calcium stearate. According to the corrosion-resistant insulated power cable prepared in the invention, the corrosion resistance of the power cable in extreme corrosion environments such as strong acid, strong alkali, high-concentration salt mist and the like is improved, and the condition that a common cable sheath is easy to expand and crack in the extreme corrosion environments is improved.

An extreme-cold resistant low-fume halogen-free flame-retardant polyolefin sheath, a preparation method therefor, and a cable. The sheath comprises the following raw materials in parts by mass: 4-16 parts of an ethylene-vinyl acetate copolymer, 7-13 parts of a phosphate group functionalized linear low-density polyethylene, 9-15 parts of an ethylene-octene copolymer, 5-10 parts of a maleic anhydride-grafted ethylene-methyl methacrylate copolymer, 10-15 parts of magnesium hydroxide, 40-50 parts of aluminum hydroxide, etc. The preparation method for the phosphate group functionalized linear low-density polyethylene comprises: adding a catalyst to a pre-cooled ethylene monomer, adding a vinyl phosphate ester and an initiator after the reaction, and reacting for 1-2 hours at a temperature of 65-75°C and a pressure of 15-35 Mpa and then terminating the reaction, thereby obtaining the phosphate group functionalized linear low-density polyethylene. Compared with unfunctionalized polyethylene, the phosphate group functionalized polyethylene used has greatly improved low-temperature and flame-retardant performance, and can improve the overall flame-retardant and low-temperature performance of the formula.

The invention relates to the technical field of PU synthetic leather, and discloses flame-retardant PU synthetic leather, which comprises a base layer, a flame-retardant middle layer and a surface functional layer, the flame-retardant middle layer is prepared by mixing modified PU resin, a composite flame retardant, a synergist and a cross-linking agent, the composite flame retardant is prepared by compounding an organic phosphorus-nitrogen flame retardant and nano magnesium hydroxide according to a mass ratio of 3: 1-5: 1, and the surface functional layer is prepared by mixing modified PU resin, a composite flame retardant, a synergist and a cross-linking agent. The synergist is modified montmorillonite, the surface functional layer is a blend of fluorine-containing polyurethane resin and flame-retardant silicone oil, and the three-layer structure is integrally formed through a hot melting compounding process. The modified PU resin is prepared from polycarbonate diol, isophorone diisocyanate and a chain extender through a reaction. Three-dimensional flame-retardant protection from inside to outside can be achieved through the collaborative design of the base layer flame-retardant pretreatment layer, the flame-retardant middle layer and the surface functional layer, a finished product can reach a high flame-retardant grade, combustion spreading is effectively inhibited, release of smoke and toxic gas is reduced, and the problems that traditional PU synthetic leather is poor in flame retardance and prone to melting and dripping are solved.

The invention discloses an impact-resistant cross-linked polyolefin composite cable material and a preparation method thereof, belongs to the technical field of cable material processing, and aims to solve the technical problem that the impact resistance and flame retardance of a cable material in the prior art need to be further improved. The flame-retardant polypropylene composite material specifically comprises the following components in parts by weight: 60-80 parts of modified polypropylene, 20-25 parts of a modified flame retardant, 5-8 parts of modified magnesium hydroxide, 10-15 parts of an ethylene-octylene copolymer, 1-2 parts of a chain extender, 0.5-1 part of an initiator and 8-12 parts of an auxiliary additive. The cross-linked polypropylene, the modified flame retardant, the modified magnesium hydroxide, the ethylene-octylene copolymer and the auxiliary additive are added into a double-screw extruder for melt extrusion and granulation to obtain the composite cable material, so that the impact resistance and flame retardance of the cable material are improved, and the toughness of the cable material is also improved.

The invention relates to the technical field of high polymer materials, and discloses a flame-retardant composite material as well as a preparation method and application thereof, the flame-retardant composite material comprises the following components in parts by mass: 60-80 parts of matrix resin, 0.5-10 parts of a compatilizer and 50-150 parts of a flame retardant, the matrix resin comprises EVA, POE and EPR; the compatilizer is a mixture of EVA, POE and EPR modified by maleic anhydride; the flame retardant is prepared from a modified filler and expandable graphite in a mass ratio of 60: (1-5), and the modified filler is prepared from a silane coupling agent, magnesium hydroxide, aluminum hydroxide and magnesium oxide in a mass ratio of 1: (15-60): (40-120): (10-60). When the flame-retardant composite material is used as a cable sheath material, the flame-retardant composite material has high tensile strength, elongation at break and oxygen index.

The invention discloses a preparation method of high-performance cordierite DPF honeycomb ceramic, and belongs to the technical field of honeycomb ceramic carrier preparation. The preparation method comprises the following steps: mixing raw materials; kneading mud; performing extrusion molding; drying and shaping; cutting and firing to obtain a cordierite honeycomb ceramic carrier; and performing boundary dimension processing, film covering, hole dotting, mud scraping and drying to obtain a finished product. According to the invention, aluminum hydroxide is adopted to replace or partially replace aluminum oxide in the formula of the cordierite porous ceramic structure while magnesium hydroxide is used, and the two substances can form a synergistic heat absorption mechanism by virtue of the difference of the aluminum hydroxide and magnesium hydroxide in thermal decomposition temperature, so that the heat absorption efficiency of the cordierite porous ceramic structure is greatly improved in the low-temperature coke discharge stage of a carrier mud blank. Aluminum hydroxide is subjected to a decomposition reaction before magnesium hydroxide, and then magnesium hydroxide is continuously decomposed at a higher temperature, so that the temperature range covered by the whole heat absorption process is greatly widened, the heating rate of the carrier mud blank is effectively slowed down, and thermal shock caused by sudden rising of local temperature is avoided.

The invention relates to a flame-retardant composition, a flame-retardant layer and a new energy automobile power battery comprising the flame-retardant layer. The flame-retardant composition comprises the following components in percentage by weight: 50-68% of matrix resin which is a mixture of polycarbonate and polyphenyl ether in a weight ratio of (1: 1)-(3: 1); the composite flame retardant comprises a phosphate flame retardant, a cyanamide flame retardant and an inorganic flame retardant according to the weight ratio of 1: (0.5-0.8): (2-2.5), and the inorganic flame retardant is selected from one or more of aluminum hydroxide, antimony trioxide, magnesium hydroxide and zinc borate; 10-20% by weight of a thermally conductive agent; 5 to 10 wt% of a silane coupling agent; and 1-3 wt% of a lubricant. A flame-retardant layer formed by the flame-retardant composition is arranged between a power battery module and an aluminum shell of the new energy automobile power battery, has good flame retardance, heat conduction and mechanical properties, and can meet the use requirements of the new energy automobile power battery.

The invention relates to the technical field of cable processing, and discloses a magnesium hydroxide-silicone rubber flame-retardant cable filling material and a preparation method thereof.The preparation method comprises the following steps that KH-570 hydrolysate is dropwise added into magnesium hydroxide dispersion liquid, and modified magnesium hydroxide is obtained through a reaction; dispersing the modified magnesium hydroxide, PCS and a first catalyst in an organic solvent, and reacting in an inert gas atmosphere for 2-4 hours to obtain PCS-coated magnesium hydroxide; modifying the PCS-coated magnesium hydroxide with a silane coupling agent to obtain modified PCS-coated magnesium hydroxide; silicone rubber, modified PCS coated magnesium hydroxide, fumed silica and hydroxyl silicone oil are mixed to form a rubber material; and adding a cross-linking agent and a second catalyst, and reacting to obtain the flame-retardant cable filling material. According to the invention, after magnesium hydroxide is coated with PCS, the silane coupling agent is adopted for modification, and when the material encounters high temperature or flame, a firm and compact ceramic protection layer can be generated, so that the effects of heat insulation, oxygen insulation and melting and dripping prevention are achieved.

The present invention relates to the technical field of cable preparation, and in particular to a low-temperature-resistant, flame-retardant, and UV-resistant PVC cable sheath composition, a preparation method thereof, and a cable. The composition is based on polyvinyl chloride, supplemented with a chlorinated polyethylene elastomer, an environmentally friendly plasticizer, and a calcium-zinc stabilizer, and introduces nano-magnesium hydroxide, zinc stannate, passivated zinc borate, sodium tungstate, and modified montmorillonite to form a multi-component synergistic flame retardant system, which significantly improves the flame retardancy, low smoke properties, and thermal stability of the material. At the same time, through the synergy of ultraviolet absorbers and antioxidants, the weather resistance and service life of the material are enhanced. The prepared cable sheath material has excellent low-temperature flexibility, flame retardant and smoke suppression properties, and ultraviolet aging resistance, and is suitable for high-performance cable applications in harsh environments.

The invention relates to the field of flame-retardant textile fabrics, and provides a comfortable flame-retardant aramid fabric and a preparation method thereof. The composite filler with the average length of 3.0-8.0 mu m and the diameter of 0.4-1.0 mu m is prepared by adopting the design of multielement blended composite fibers of hydroxyapatite / magnesium hydroxide composite filler, meta-aramid polymer, para-aramid polymer, polybenzimidazole and the like through a hydro-thermal synthesis process of performing silanization surface activation and accurately controlling the molar ratio of calcium to phosphorus to be 1.60-1.67. The preparation method comprises the following steps: preparing the composite filler with the average length of 3.0-8.0 mu m and the diameter of 0.4-1.0 mu m; then industrial production processes such as graded shearing dispersion, continuous wet spinning, multi-stage stretching heat setting and after-finishing are performed, so that synergistic improvement of flame retardant performance and comfort performance is achieved, and the technical problems that a traditional aramid fiber fabric is poor in flame retardant effect, poor in comfort, unstable in processing performance and the like are solved; the fabric has wide application value in high-end application fields such as fire protection clothing, industrial protection textiles and military protection equipment.

The invention discloses a thermoplastic whole-core flame-retardant conveying belt and a preparation method thereof. The thermoplastic whole-core flame-retardant conveying belt is composed of a core layer, a flame-retardant covering layer, a wear-resistant layer and a bonding layer. The core layer adopts three layers of aramid fiber / polyester mixed fabric (the radial linear density is greater than or equal to 5000N / cm) and is impregnated with a halogen-free flame-retardant polyurethane sizing material (containing 15phr of APP and 10phr of zinc borate); the flame-retardant covering layer is an intumescent flame-retardant system formed by adding 5 phr of microencapsulated red phosphorus, 20 phr of magnesium hydroxide and 8 phr of melamine cyanurate into an EVA (Ethylene Vinyl Acetate)-based compound; the surface wear-resistant layer is made of ultra-high molecular weight polyethylene (Mw is larger than or equal to 3 * 10 < 6 >, and the thickness ranges from 0.8 The product has the advantages of high strength, light weight, flame retardance and high joint strength retention rate, and is suitable for heavy-load high-temperature scenes such as mines and metallurgy.

The invention relates to the field of building materials, in particular to a novel non-combustible composite board and a preparation process thereof. The novel non-combustible composite board comprises a base material layer, a fire-resistant flame-retardant layer and a protective surface layer which are sequentially arranged from bottom to top, the fireproof flame-retardant layer comprises the following components in parts by mass: 40-55 parts of a halogen-free flame retardant and 15-18 parts of a fiber auxiliary agent, and the halogen-free flame retardant comprises carboxylic acid modified aluminum hydroxide, silicon modified magnesium hydroxide and layered sodium silicate. Aiming at the problems that an existing composite board is poor in flame retardance, low in flame retardant efficiency, poor in board toughness, prone to cracking, poor in interlayer bonding performance and prone to delamination at high temperature, the combustion performance of the prepared novel non-combustible composite board completely meets the A2-level requirement, the combustion heat value is small, and the novel non-combustible composite board has the advantages of being good in toughness, high in strength and not prone to cracking.

The invention belongs to the technical field of flame retardance, and particularly discloses a production process of a polyester efficient flame retardant and application of the polyester efficient flame retardant to a thermal insulation material. Comprising the following steps: (1) dispersing montmorillonite in deionized water, adding PEG-400, octadecyl trimethyl ammonium chloride and aluminum metaphosphate, stirring at the temperature of 50-60 DEG C, and drying to obtain pretreated montmorillonite; (2) uniformly mixing composite glass fibers, magnesium hydroxide and silicon dioxide, dispersing the mixture into an ethanol solution, adding the pretreated montmorillonite in the step (1), and performing ultrasonic treatment, filtration and drying to obtain a mixture; and (3) spraying an epoxy resin solution on the surface of the mixture obtained in the step (2), and grinding to obtain the high-efficiency polyester flame retardant. According to the flame-retardant polyester material disclosed by the invention, various components are synergistically matched, a compact carbon layer is formed during combustion, heat is prevented from being transferred to a polyester matrix, a flame-retardant effect is achieved, and the inorganic components, the epoxy resin coating and the like can change the mechanical properties of the polyester material.

The invention provides a ternary synergistic flame retardant suitable for a polylactic acid composite material and a preparation method thereof. The ternary synergistic flame retardant comprises ternary components of magnesium hydroxide, zinc oxide and titanium dioxide, the ternary component is subjected to surface modification through a silane coupling agent solution containing an epoxy group, the mass ratio of magnesium hydroxide to zinc oxide to titanium dioxide is 4: 1.5: 1-5: 2: 1, and the ternary component is used for maintaining the mechanical property of polylactic acid and achieving the synergistic effect of flame retardance and smoke suppression at the same time. According to the polylactic acid composite material prepared by the invention, the limit oxygen index is increased to 28.85% from 19.91%, the increase amplitude is about 45%, and the UL-94 V-0 grade is reached; the maximum smoke density is reduced from 287 to 198, the reduction amplitude is about 31%, and the flame retardant efficiency of the material and the visibility in the combustion process are remarkably improved. The addition amount of the ternary synergistic flame retardant is controlled in a range of 15-25%, an excellent flame retardant effect can be obtained, the addition amount is greatly reduced compared with that of a single magnesium hydroxide system (generally, the addition amount needs to be larger than or equal to 40%), and the mechanical property loss caused by high filling is effectively avoided.

The invention relates to the technical field of cables, and provides a high-weather-resistance power cable. The high-weather-resistant power cable comprises a cable core and an outer sheath, the outer sheath is prepared from the following raw materials in parts by weight: 40 to 50 parts of low-density polyethylene, 25 to 35 parts of ethylene-vinyl acetate copolymer, 20 to 30 parts of ethylene propylene diene monomer, 10 to 12 parts of maleic anhydride grafted ethylene-vinyl acetate copolymer, 16 to 20 parts of ZrO2 coated modified hydrotalcite, 15 to 20 parts of magnesium hydroxide, 4 to 6 parts of silane coupling agent, 2 to 3 parts of dicumyl peroxide and 3 to 5 parts of zinc oxide; 6 to 10 parts of conductive carbon black, 0.8 to 1 part of antioxidant and 1 to 1.5 parts of zinc stearate. According to the cable prepared in the invention, the protection performance, the service life and the safety of an existing high-weather-resistance power cable under extreme weather conditions are improved, and the mechanical property of the cable is also improved.

The invention belongs to the technical field of inorganic chemical material preparation, and discloses a high-selectivity crystallization and impurity migration inhibition method of high-purity magnesium hydroxide. The method comprises the following steps: a phenylphosphonic acid surface modifier is introduced in the initial stage of crystallization, molecules of the phenylphosphonic acid surface modifier selectively occupy high-activity Mg < 2 + > sites of a magnesium hydroxide crystal face through bidentate coordination, and a molecular-level interface barrier with steric hindrance and electrostatic repulsion effects is formed, so that a Ca < 2 + > migration path is specifically blocked, and Mg < 2 + > crystallization is not influenced. The preparation method of the high-purity magnesium hydroxide is high in selectivity, high in efficiency, low in cost and environmentally friendly, the interface adsorption behavior of calcium ions is accurately intervened in the initial stage of crystallization through a molecular level surface engineering means, the technical bottleneck that impurity migration and lattice doping are difficult to control in a traditional process is fundamentally solved, and the preparation method is suitable for industrial production. And a brand new technical path is provided for green manufacturing of high-performance inorganic functional materials.

The invention relates to the technical field of high polymer materials, and particularly discloses a B1-grade low-smoke halogen-free flame-retardant polyethylene cable material and an extrusion molding process thereof. The invention discloses a B1-grade low-smoke halogen-free flame-retardant polyethylene cable material. The cable material is prepared from the following raw material components in parts by weight: 50 to 70 parts of linear low-density polyethylene, 50 to 70 parts of ethylene-vinyl acetate copolymer, 40 to 60 parts of nanoscale magnesium hydroxide, 5 to 8 parts of microencapsulated red phosphorus, 10 to 15 parts of intumescent flame retardant, 3 to 5 parts of zinc borate and 2 to 4 parts of carbon nanotubes. According to the cable material, the ethylene-vinyl acetate copolymer can improve the dispersing performance of the inorganic filler, the composite flame retardant composed of the nanoscale magnesium hydroxide, the microencapsulated red phosphorus and the intumescent flame retardant is utilized, and the synergistic effect of the zinc borate and the carbon nanotubes is matched, so that the obtained cable material has better flame retardance, and the release of smoke is less.

The invention discloses a high-temperature-resistant flame-retardant wire harness and a preparation method thereof, and relates to the technical field of electric harnesses. The method comprises the following steps: firstly, introducing phosphorus and silicon flame-retardant elements on a polyethylene molecular chain through plasma activation and free radical grafting reaction to prepare phosphorus-silicon grafted modified polyethylene, then compounding aminated silicon dioxide and organic intercalated montmorillonite by using isophorone diisocyanate as a bridging agent to prepare the phosphorus-silicon grafted modified polyethylene composite material. The preparation method comprises the following steps: preparing an isocyanate-bridged silicon dioxide-montmorillonite composite filler to improve the dispersity and compatibility of the filler in a matrix, carrying out extrusion granulation on modified polyethylene, an ethylene-butyl acrylate copolymer, maleic anhydride grafted polyethylene, the composite filler, nano magnesium hydroxide and other additives to prepare polyethylene wire harness particles, and finally, carrying out extrusion granulation on the polyethylene wire harness particles to prepare the cable harness. And coating the surface of a copper core wire with the particles through a single-screw extrusion coating machine, and carrying out subsequent water cooling, steam treatment, drying and rolling to obtain a finished wire harness. The wire harness prepared by the invention has excellent high temperature resistance and flame retardance.

The invention relates to the technical field of power cables, and discloses a high-flexibility high-temperature-resistant fireproof cable which comprises a conductor, an insulating layer, a shielding layer, an inner sheath layer, a fireproof layer and an outer sheath layer which are sequentially arranged from inside to outside, the conductor is formed by twisting multiple strands of fine copper wires, the surface of each fine copper wire is plated with a layer of tin, the insulating layer is made of a silicon rubber material, and the shielding layer is made of a silicon rubber material. A nanoscale magnesium hydroxide flame retardant and a high-temperature-resistant additive are added into the silicone rubber material; the shielding layer is a copper wire braided shielding layer; the inner sheath layer is made of a polyurethane material; the fireproof layer comprises a ceramic silicone rubber layer and a mica tape wrapping layer which are arranged in sequence; according to the scheme, the conductor is stranded by multiple strands of fine copper wires, and the diameter, the stranding pitch and the tension are optimized, so that the cable keeps excellent flexibility in frequent bending and moving environments, and the conductor is prevented from being broken. The tin coating improves the oxidation resistance and the welding performance, and ensures the long-term stability of electrical connection.