Technique for chemomechanical pulp-making of poplar wood
A chemical-mechanical and pulping technology, used in chemical/chemical-mechanical pulping, pulp beating/refining methods, pretreatment with alkaline compounds, etc. It can reduce the pollution load of wastewater, improve the yield and optical performance, and eliminate the scaling problem.
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[0027]The poplar chips are steamed after being screened. After steaming, the wood chips are squeezed and decomposed, and the pulp after decompression enters the pulping process. In the prior art, the hydrogen peroxide chemical mechanical pulping with sodium hydroxide as the alkali source is carried out with a solution containing sodium hydroxide, hydrogen peroxide, magnesium sulfate, ethylenediaminetetraacetic acid (EDTA) and sodium silicate After treatment, extrusion and decompression are carried out, and then the above solution is used for treatment. After treatment, the first stage of refining, high-consistency residence and the second stage of refining are carried out. In the present invention, the enzyme solution is firstly used for treatment, and after the treatment, extrusion and decompression are carried out, and after decompression, it is impregnated with a solution containing magnesium hydroxide, hydrogen peroxide and ethylenediaminetetraacetic acid (EDTA). Refining ...
Embodiment 1
[0030] After five-year-old poplar wood chips are steamed and extruded, pulping is carried out according to the following steps:
[0031] 1. Enzyme treatment, the conditions are: slurry concentration 12%, temperature 40-50°C, time 1.5h, pH value 5-6, enzyme dosage 100IU / (g dry slurry), the enzyme used is laccase.
[0032] 2. Squeeze and decompress the slurry treated in the above step 1, and the decompression compression ratio is 4:1 volume ratio. Chemical pre-impregnation with magnesium alkali hydrogen peroxide solution, the process conditions of impregnation treatment are: temperature 70°C, slurry concentration 25%, time 30min, Mg(OH) 2 2.0% (relative to the weight of absolute dry pulp), 1.0% of EDTA (relative to the weight of absolute dry pulp), 6.0% (relative to the weight of absolute dry pulp), hydrogen peroxide.
[0033] 3. The slurry impregnated in step 2 and all the soaking liquid are subjected to the first stage of refining, the refining pressure is normal pressure, th...
Embodiment 2
[0038] After five-year-old poplar wood chips are steamed and extruded, pulping is carried out according to the following steps:
[0039] 1. Enzyme treatment. The conditions are: slurry concentration 15%, temperature 40-50°C, time 1.5h-2.0h, pH value 5-6, enzyme dosage 30IU / (g dry slurry). The enzyme used is a combined enzyme of laccase and manganese peroxidase with a mass ratio of 4:1.
[0040] 2. Squeeze and decompress the slurry treated in the above step 1, and the decompression compression ratio is 6:1 volume ratio. The slurry after extrusion and defrosting is impregnated with magnesium alkali hydrogen peroxide solution. The process conditions of dipping treatment are: temperature 50°C, slurry concentration 20%, time 50min, Mg(OH) 2 1.0% (relative to the weight of absolute dry pulp), 1.0% of EDTA (relative to the weight of absolute dry pulp), 4.0% of hydrogen peroxide (relative to the weight of absolute dry pulp).
[0041] 3. The slurry treated in the above step 2 toget...
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