The invention discloses a comprehensive utilization method of high-
salinity wastewater produced by hydrometallurgical treatment of bastnaesite, which comprises the following steps: A, mixing alkaline
wastewater and acidic
wastewater, neutralizing and clarifying to obtain
calcium fluoride and
sodium chloride wastewater; b, mixing the
sodium chloride wastewater with the
precipitation wastewater, adding
lime water in an
aeration manner to adjust the pH value, hydrolyzing heavy
metal ions in the wastewater, and performing
solid-liquid separation to obtain filter residues and filtrate which is
sodium chloride high-
salinity wastewater; and C, adding
oxalic acid into the sodium chloride high-
salinity wastewater, stirring, standing, carrying out
solid-liquid separation, pressurizing, concentrating, recovering
hydrochloric acid, and crystallizing to obtain a
crystal substance, namely a sodium chloride product. According to the method,
fluorine in the wastewater is removed firstly, then the wastewater is recovered into wastewater containing sodium chloride,
oxalate is dissolved into the high-salinity wastewater to separate out
sodium oxalate and recover
hydrochloric acid, so that the content of sodium chloride in the
system is greatly reduced, and the
recovery efficiency of sodium ions in the wastewater is improved.