The invention discloses a
lithium battery
composite membrane and a preparation method thereof, and belongs to the technical field of
lithium batteries, the
composite membrane comprises a base membrane and a
coating layer coated on one side or two sides of the base membrane;
slurry of the
coating layer is obtained through graft copolymerization of EVA,
polyamic acid and aluminum
oxide, the EVA is hydrolyzed to generate hydroxyl, the aluminum
oxide is modified by amino
silane to introduce amino, and then the aluminum
oxide is subjected to graft copolymerization with the
polyamic acid. According to the invention, combination of PI, EVA and
alumina is realized through graft copolymerization, multi-component molecular-level compounding is realized, the cost is reduced, and the EVA has
low density, so that the
mass of a
coating layer can be reduced, and the influence on the
energy density of a battery is reduced. Based on the combination of a rigid material of PI and aluminum oxide and an EVA flexible material, the provided diaphragm is more tightly attached to a positive
electrode material and a negative
electrode material, the
thermal stability and the
mechanical property of the diaphragm are enhanced, and the
electrolyte wettability of the diaphragm is good.