1415 results about "SULFATE ION" patented technology

The invention discloses a technique method for producing high-concentration nitric phosphate, which comprises the following steps of: adding nitric acid into phosphorus ore for acidolysis, depositing and separating acid non-soluble substance, freezing and crystallizing calcium nitrate, filtering the calcium nitrate, neutralizing the mother liquid, vaporization, pelleting and drying. The invention is characterized in that: a step of thoroughly removing the calcium of the mother liquid is arranged between the steps of filtering the calcium nitrate, and neutralizing the mother liquid. The steps comprise the following steps of: I) thoroughly removing the calcium of the mother liquid and adding sulfuric acid or ammonium sulfate; the calcium ions and the sulfate ions in the mother liquid generate dihydrate calcium sulfate crystal; II) the grading processing of reaction slurry: employing a grading device to carry out grading processing to the reaction slurry; returning the reaction slurry provided with small grain calcium sulfate to the mother liquid for thoroughly removing the calcium, and feeding the reaction slurry provided with large grain calcium sulfate to the calcium sulfate for filtering; and III) filtering and washing the filtering reaction slurry of calcium sulfate by a filter, feeding the primary filtrate and the primary lavage fluid into the working procedure of neutralizing, and returning the secondary lavage fluid to the filter. The invention has the advantage of using middle-low quality phosphorite to prepare the high-concentration nitric phosphate.

The invention discloses a composition used in a scale-inhibition corrosion inhibitor, a scale-inhibition corrosion inhibitor, and an application thereof. The composition used in the scale-inhibition corrosion inhibitor comprises cyclodextrin and/or a cyclodextrin derivative, a carboxylic-acid-group-containing homopolymer, a sulfonic-acid-group-containing copolymer, and selectively hydroxycarboxylic acid with a weight ratio of 1:0.2-20:0.04-15:0.2-30:0-20. The scale-inhibition corrosion inhibitor provided by the invention is environment-friendly. According to the invention, the application of phosphorus-containing compound or non-renewable molybdate or tungstate is prevented, such that the scale-inhibition corrosion inhibitor is phosphorus-free and nitrogen-free. The scale-inhibition corrosion inhibitor has high tolerance to calcium and alkali, resistance to corrosion of high-concentration chloride ion and sulfate ion, and wide applicability to water quality. Therefore, technical condition is provided for operation of circulation water under high concentration multiple and for reducing sewage discharge. The scale-inhibition corrosion inhibitor provided by the invention has excellent scale inhibition and corrosion inhibition performances in circulation water system application. With the scale-inhibition corrosion inhibitor, a dose is low, scale-inhibition treatment process is simple and substantial effect is provided. The scale-inhibition corrosion inhibitor is suitable for popularization.

The invention discloses a phosphoric-acid-base modified polycarboxylic-acid water reducer with high adaptability and a preparation method thereof. The water reducer is prepared from the following raw materials: isopentenol polyoxyethylene ether, hydrogen peroxide, acrylic acid, an unsaturated phosphoric acid monomer, deionized water, a reducing agent, and a chain transferring agent. The chain transferring agent is one of mercaptoethanol, mercaptoacetic acid and mercaptopropionic acid. The unsaturated phosphoric acid monomer is prepared from 2-phosphono-1,2,4-butanetricarboxylic acid, p-toluenesulfonic acid and hydroquinone. The preparation method for the water reducer comprises adding isopentenol polyoxyethylene ether and deionized water into a reaction vessel, uniformly stirring, heating, keeping warm, adding oxygen peroxide, then dropwise adding a material solution by employing a constant-flow pump, continuing to keep warm for reacting for 1-1.5 h after dropwise adding of the material solution is finished, naturally cooling to room temperature, and adjusting the pH value of the obtained product to 5-6 by using an alkaline solution. The phosphoric-acid-base modified polycarboxylic-acid water reducer possesses good sulfate ion resisting capability and sludge resisting capability, thereby satisfying engineering demand.

The invention pertains to an organic light emitting diode (LED) comprising a transparent electrode, superposed by a layer of a conductive transparent polymer (CTP), superposed by a layer of a light emitting polymer, oligomer, or low molecular weight compound superposed by a metal cathode, characterized in that the CTP layer has a sulfate ion content of less than 7,500 ppm, and a metal ion content of more than 0.04 mmoles/g.

The environment friendly methyl sulfonic acid preparing process includes the following steps: the reaction of the water solution or solid of ammonium sulfite or mixture of ammonium sulfite and ammonium bisulfite with dimethyl sulfate at high temperature to produce ammonium methyl sulfonate; treating the reacted solution containing ammonium methyl sulfonate and ammonium sulfate with calcium hydroxide or other compound capable of producing precipitate with sulfate radical ion to produce water soluble calcium methyl sulfonate, water insoluble calcium sulfate and ammonium hydroxide; treating obtained calcium methyl sulfonate with strong acid capable of forming precipitate with calcium ion; and final decompression distilling to obtain methyl sulfonic acid. The present invention has facile material, simple technological process, high product quality, low cost and no environmental pollution, and is suitable for industrial production.

The invention provides an electrolyte for an all-vanadium redox flow battery and a preparation method thereof, and an all-vanadium redox flow battery including the electrolyte. The electrolyte for an all-vanadium redox flow battery comprises anode electrolyte and cathode electrolyte which contain vanadiferous ions and sulfate ions, concentration of the sulfate ions in the anode electrolyte is more than that of the sulfate ions in the cathode electrolyte, the total vanadium concentration of the anode electrolyte and the cathode electrolyte is 2.0-8.0mol/L respectively. The preparation method of the electrolyte for an all-vanadium redox flow battery comprises the following steps: dissolving one or more vanadium oxides and optional reducers in sulfuric acid solution with a first concentration and a second concentration respectively to obtain an anode electrolyte precursor and a cathode electrolyte precursor with the total vanadium concentration of 2.0-8.0mol/L respectively, wherein, the first concentration is larger than the second concentration; and electrolyzing the anode electrolyte precursor and the cathode electrolyte precursor respectively to obtain the anode electrolyte and the cathode electrolyte of the all-vanadium redox flow battery.

There is disclosed an organic electro luminescence display device comprising a two-dimensional array of pixels comprising organic electro luminescence elements capable of emitting a of color or different plural colors, each of the organic electro luminescence elements being provided with an anode, a cathode, a polymeric luminescence layer located between the anode and the cathode, and a hole injection layer. The hole injection layer is constituted by solid matters containing a donor molecule comprising polythiophene and/or a derivative thereof, and an acceptor molecule comprising polystyrenesulfonic acid and/or a derivative thereof, a concentration of sulfate ion in the hole injection layer is 125 ppm or less, and components having a molecular weight of 110,000 or less is 35% or less based on an entire solid matters, the molecular weight being converted as sodium polystyrenesulfonate in an aqueous gel permeation chromatography measured by using UV of 254 nm in wavelength.

The invention provides a higher rust preventive effect than alkaline water prepared by conventional electrolysis, and washing water compatible with safety and washing quality. In the method of preparing washing water, a process by which sulfate ions in raw water are made to be <=0.2 mmol/dm3 and /or chloride ions <=0.5 mmol/dm3, calcium ions <=1.0 mmol/dm3, and Mg ions <=1.0 mmol/dm3, is performed and subsequently a process by which sodium carbonate concentration in raw water is made to be 0.1-10.0 mmol/dm3, is performed, and then this water is electrolyzed to obtain washing water having >=8.0 and <=13.0 pH and /or 100 mV to 1,000 mV oxidation reduction potential.

The invention relates to a concrete admixture, in particular to a composite cement preservative which can enhance the salty ion erosion resistance, freezing-thawing cyclic damage resistance and penetration resistance of concrete. The concrete preservative disclosed by the invention comprises the following components in percentage by weight: 30.0-50.0 percent of mineral admixture, 30.0-50.0 percent of expanding agent, 5.0-10.0 percent of corrosion inhibitor, 0.001-0.005 percent of air entraining agent and 1.0-10.0 percent of water reducing agent. By adopting the concrete preservative disclosed by the invention, the compactness of concrete can be enhanced, the concentration of sulfate ions capable of invading concrete can be lowered, the pore diameters of capillary pores can be reduced and the precipitating speed of calcium hydroxide from set cement can be restrained, so that the structural durability of concrete is enhanced. The concrete preservative is suitable for reinforced concrete structures in unfavorable geological regions, such as coal measure strata containing sulfate and magnesium and chloride ions, sulfide ore strata, seashore saline fields, coastal harbors and the like, as well as marine waters.

The invention discloses a method for preparing calcium sulfate whisker from phosphogypsum. The method comprises the following steps: (1) crushing and grinding phosphogypsum serving as a raw material to obtain phosphogypsum powder; (2) mixing the obtained phosphogypsum powder and diluted acid to obtain a mixture, placing the mixture in a reactor with a stirring device, reacting by controlling a certain temperature to obtain an acidic mixed solution containing calcium, sulfate ions and insoluble matters; (3) filtering the obtained mixed solution while the solution is hot to obtain an acidic filtrate; and (4) cooling the obtained acidic filtrate and crystallizing, filtering, washing and drying to obtain the calcium sulfate whisker product. The calcium sulfate dihydrate whisker with large length-diameter ratio is directly prepared from the raw material by virtue of one-step acid leaching impurity removal method instead of pretreatment impurity removal and thus the advantages that the process flow is simple, the production cost is low, the energy consumption is small and the acidic wastewater and washing water can be recyclable are achieved; the obtained calcium sulfate whisker has the characteristics of high purity, large length-diameter ratio and the like and is conductive to popularization and application.

The invention relates to a preparation method of a fluorescent molecular probe for detecting sulfite ions through naked eyes and fluorescence ratio as well as the application of the fluorescent molecular probe in detecting sulfite ions. The fluorescent molecular probe is prepared by condensing 4-hydroxy naphthalimide serving as raw material and acetylpropionic acid in refluent methylene dichloride. The synthesis is simple and convenient, and the reaction conditions are mild. The probe molecule provided by the invention has higher sensitivity, stable fluorescence performance, higher synthesis yield and good selectivity, and furthermore, the response range of the probe is 0-1500 mu m, the detection limit is 6 mu m; the detection range is wide, the lower detection limit is low, and the probe is suitable for naked eye detection. Meanwhile, the florescence-ratio detection is adopted to avoid errors caused by exciting light intensity, probe concentration and environment factors of an off-on type probe which detects ions only depending on the change of fluorescence intensity and the probe disclosed by the invention is not influenced by anions such as F<->, Cl<->, Br<->, I<->, HPO4<2->, SO4<2->, NO<3->, AcO<->, ClO<4->, N<3-> and HCO<3->. Even interfering ions exist, the probe has very good response to sulfite ions. Therefore, the fluorescent molecular probe has practical application value in the fields of biochemistry, environmental science and the like.

A process for the extraction of a metal from an ore or concentrate comprises subjecting the ore or concentrate to pressure oxidation in the presence of oxygen and an acidic solution containing halogen ions and a source of bisulphate or sulphate ions, such as H2SO4. The metals which can be extracted by the process comprises copper as well as non-cuprous metals such as zinc, nickel and cobalt. During pressure oxidation the metal may be precipitated as an insoluble basic salt, such as basic copper sulphate, or substantially completely solubilized and precipitated later as the basic metal salt.

The invention discloses a recovery processing method of high salinity wastewater containing sodium chloride and sodium sulfate, and belongs to the field of industrial wastewater treatment. According to the recovery processing method, sodium chloride and sodium sulfate are recycled via primary evaporative crystallization, removing of sulfate ions via adding of materials and generation of precipitations, and secondary evaporative crystallization. The recovery processing method can be used for effective recovery of sodium chloride and sodium sulfate in coal chemical industry high salinity wastewater; process conditions are simple and stable; the recovery processing method is convenient for industrialized popularization; recovered sodium chloride and sodium sulfate are capable of satisfying quality requirements of industrial-grade products, and can be recycled and reused directly or be sold as by-products; processing of high salinity wastewater is realized; environmental requirements are satisfied; waste is changed into valuables; salt resource utilization is realized; and factory income is increased.

The invention relates to a catalysis wet-type oxidation treatment method for sulfur-containing wastewater, which is mainly used for solving the problems of biological inhibition, not high removal rate of COD (chemical oxygen demand) and complex technique for treating sulfur-containing wastewater. In the method, industrial wastewater of which the COD value is 2000mg/l to 200000mg/l and the sulfur content is less than 70g/l and gases containing elemental oxygen are taken as raw materials which are in contact with a catalyst under the conditions that the reaction temperature is 230 to 300 DEG C, the reaction pressure is 3 to 10MPa, the liquid space velocity is 0.5 to 2.5h<-1> and the volume ratio in a standard state of the gas and liquid materials is (70-300):1, and therefore, the removal rate of the COD is larger than 95% and sulfurs in the wastewater are all converted into sulfate ions, wherein the catalyst comprises at least one oxide carrier selected from TiO2, Al2O3, SiO2 or ZrO2 and at least one metal or oxide carried on the oxide carrier and selected from Pt, Pd, Ru, Ir or Rh in parts by weight. The problems are nicely solved with the technical scheme, and the catalysis wet-type oxidation treatment method for sulfur-containing wastewater can be used in the industrial treatment of sulfur-containing industrial wastewater.

Desalination is carried out by a hybrid ion exchange-nanofiltration process in which ion exchange is followed by pressure-driven nanofiltration. Monovalent ions of sodium and chloride of saline water are exchanged for equivalent concentrations of poly-valent ions (for example, sodium ions for magnesium ions or chloride ions for sulfate ions) when passed through ion exchangers in the form of those poly-valent ions. The resultant solution has a lower osmotic pressure than the initial solution containing monovalent sodium and chloride ions, and requires less transmembrane pressure for membrane desalination compared to traditional reverse osmosis. The concentrated reject stream from the membrane process is used as regenerant for the exhausted ion exchanger, which has been converted to monovalent anionic or cationic form.

A solution for etching copper or copper alloys which can be used to prepare copper surfaces as bright as possible for subsequent metal plating. The solution has a pH of about 4 or less and is free of sulfate ions. The solution comprises: a) at least one oxidizing agent selected from hydrogen peroxide and peracids; b) at least one substance selected from aromatic sulfonic acids and aromatic sulfonates; and optionally c) at least one N-heterocyclic compounds. The present application also discloses a method of depositing metal onto a copper or copper alloy surface. Said method comprises the steps of: a) contacting said surface with a solution according to the invention; and b) coating said surface with at least one metal. The solution and the method are particularly suitable for the manufacture of circuit carriers, more particularly for semiconductor manufacture.

The invention relates to a highly hydrophobic antistatic composite coating and a preparation method thereof. The hydrophobicity of a conventional hydrophobic material is improved mainly by adding fluorine-containing substances. The preparation method comprises the following steps: adding graphite powder and sodium nitrate into concentrated sulfuric acid, stirring in an ice bath, adding potassium permanganate, slowly dropwise adding distilled water, removing excessive potassium permanganate, filtering sulfate ions to obtain oxidized graphite, adding the oxidized graphite into an organic solvent, and ultrasonically processing to prepare an oxidized graphene solution; adding isocyanic acid, a long-chain modified substance and a reducer into the oxidized graphene solution in sequence to chemically modify oxidized graphene, washing and drying to obtain modified graphene; by taking resin as a base body, uniformly dispersing the resin and the modified graphene through ultrasonic blending or quick stirring to obtain the highly hydrophobic antistatic composite coating. The composite coating provided by the invention has hydrophobic and antistatic performances, does not contain the fluorine-containing substances, and is environment-friendly and excellent in durability.

The invention relates to double-membrane-method technology for refining brine and equipment for the same. After pretreatment, brine to be treated enters a filtration procedure to form high-concentration nitrate-containing water and refined brine; pretreatment refers to carrying out a removal procedure of calcium and magnesium ions, a removal procedure of ammonium, a reduction procedure and a pH adjusting procedure to the brine to be treated; the filtration procedure refers to the steps that: the pretreated brine is pumped to gas-stripping tubular type membrane module for ultrafiltration, thereby organic impurities, suspended matters and partial precipitates of the brine are intercepted; pressure raising is carried out to the brine which permeates a tubular type membrane, then the brine directly enters nanofiltration membrane module for nanofiltration; the brine which can not permeate the tubular type membrane returns the removal procedure of calcium and magnesium ions; and in a high pressure state, sulfate ions are intercepted by a nanofiltration membrane to form high-concentration nitrate-containing water, and chloride ions and sodium ions permeate smoothly the nanofiltration membrane to form refined brine. The technology in the invention is simple, low energy consumption, small land-occupation area, low investment and low production cost, a stable operation system, strong impact-resistance load capability and no secondary pollution.

The invention relates to an original halogen denitration production process and original halogen denitration production equipment. The process comprises the following steps of: 1, removing calcium ions and/or magnesium ions from original halogen extracted by a water solution method; 2, removing sulfate ions from the original halogen of which the calcium ions and/or the magnesium ions are removed by using a nano-filtration membrane denitration device; and 3, collecting high aqueous glauber salt and low aqueous glauber salt which are produced by the nano-filtration membrane denitration device respectively. In the invention, the nano-filtration membrane denitration device is used for denitrating the original halogen and can only be used for denitrating light salt brine generally in the prior art; the produced liquid salt reaches a standard of first-time salt brine, and the SO4<2-> content is less than 4g/l required by the requirement of the first-time salt brine and can be controlled to be less than 3g/l; the high aqueous glauber salt subjected to nano-filtration membrane denitration is used for preparing salt through hot press, and the energy consumption of the nano-filtration membrane denitration is about 20 percent less than that of multiple-effect vacuum evaporation; and the liquid salt has lower production energy consumption, salt slurry is not generated in the denitration method, and the denitration method is more environment-friendly compared with a chemical method.

The present invention provides an ink-jet recording sheet having a coloring agent accepting layer which contains a dispersion containing a cationic polymer with an average molecular weight of 60,000 or lower and having a sulfate ion concentration of 1.5% by mass or lower to the cationic polymer together with a water-soluble resin; an particle dispersion obtained by further granulating a pre-dispersion obtained by pre-dispersing a solution containing at least fine particles and a cationic polymer and the pre-dispersion and/or the particle dispersion is heated at room temperature for 5 hours or longer after pre-dispersion and/or after granulating; and a coating solution for coloring agent accepting layer obtained by adding a water-soluble resin to the particle dispersion.

The invention provides a desulfurized waste water treatment method. The method comprises the steps that 1, desulfurized waste water enters an aeration adjusting pool, and sulfite ions in the desulfurized waste water are oxidized into sulfate ions under the action of an aeration device; 2, the desulfurized waste water is conveyed into a pH adjusting box, and lime is put into the pH adjusting box to relieve temporary hardness; 3, in a first-level reaction settling box, organic sulfur is added for further depositing heavy metal which can not be deposited in a hydroxide form; 4, in a first-level flocculation box divided into two cases, coagulant is added, many tiny floccules are condensed and formed; 5, the tiny floccules are conveyed into a first-level clarification tank so that the generated floccules and suspended solids in the waste water can be deposited and separated; 6, sodium carbonate and a sodium hydroxide solution are added into a second-level reaction settling box, and calcium ions and remaining magnesium ions in the waste water are deposited; a second-level clarification tank is used for depositing and separating the generated floccules; water produced by a multi-medium filter is sprayed into a flue to be vaporized through a spiral atomizing nozzle.