The invention provides a water-proof self-luminous printing film of the thickness of 0.150-0.156mm, and the film comprises an ink receiving layer, a connection layer, a light-storage photoluminescent film from top to bottom, wherein the ink receiving layer is prepared from inorganic stuffing, adhesive, color fixing agent, coupling agent, surfactant, cross-linking agent, fluorescent brightener and water according to certain proportion; the film has good water proofness, fast ink drying speed, clearer images after ink-jet printing and high color density and is self-luminous in the dark after absorbing external visible light; and when printed on the surface of the printing film, patterns or characters can be viewed in dark, and the film has a lighting function with low illumination. Wide application of light-storage self-luminous film products can be realized in home decoration, hotels, corridors, office buildings, cinemas, warehouses, cabins, underground passages, places needing to print a large area of high-precision patterns, and the like.