Anti-crocking rubber sole

A rubber sole and anti-blowout technology, which is applied to shoe soles, footwear, material inspection products, etc., can solve the problems of manufacturing process differences, raw material quality fluctuations, rubber aging, etc.

Inactive Publication Date: 2009-09-30
泉州泰亚鞋业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] (2) Improper process operation
[0009] (3) Raw material quality fluctuations
[0011] (4) Rubber aging
[0016] Although the above-mentioned patent documents have done appropriate research on the anti-blooming of some materials, due to the large differences...

Method used

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  • Anti-crocking rubber sole

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Embodiment 1: the preparation method of anti-blooming rubber sole of the present invention comprises the following steps:

[0042] 1) Material weighing

[0043] Raw material formula is shown in Table 1, wherein, the addition of insoluble sulfur, tetramethylthiuram monosulfide and promotor is according to A part (the raw material composition of A part comprises butadiene rubber, natural rubber, styrene-butadiene rubber, precipitated hydrated two Silicon oxide, bis-(3-triethoxysilylpropyl)-tetrasulfide, zinc oxide, polyethylene glycol, stearic acid, rubber tackifier, active agent, phenolic antioxidant, tackifying resin and Antifogging agent) is calculated as the total mass of 500g.

[0044] Table 1

[0045]

[0046] 2) Banbury

[0047] Mix the rubber and tackifier raw materials, start the banbury mixer to mix the materials evenly, add 2 / 3 of the precipitated hydrated silica, continue banburying, mix the rubber and the precipitated hydrated silica, and re-agglomera...

Embodiment 2

[0056] Embodiment 2: Similar to Embodiment 1, the difference is that the raw material formula is shown in Table 2, the start-up temperature of the internal mixer is 25° C., and the roll distance of the first and second triangular buns is 1 mm.

[0057] Table 2

[0058]

Embodiment 3

[0059] Embodiment 3: Similar to Embodiment 1, the difference is that the raw material formula is shown in Table 3, and the starting temperature of the internal mixer is 30°C.

[0060] table 3

[0061]

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PUM

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Abstract

The invention discloses an anti-crocking rubber sole and relates to a rubber sole. The invention provides the anti-crocking rubber sole with low production cost, long service life, ageing resistance and no crocking and a method for manufacturing the same. Raw materials comprise A and B; the raw material A comprises 72.9 percent of cis-1,4-polybutadiene rubber, 20.2 percent of caoutchouc, 6.9 percent of styrene-butadiene rubber, 44.5 percent of precipitated hydrated silicon dioxide, 0.8 percent of bi-(3- propyl triethoxysilane)- tetrasulfide, 5.3 percent of zinc oxide, 3.5 to 4.5 percent of polyethylene glycol, 1.0 to 2.0 percent of stearic acid, 1.1 percent of rubber viscosity increaser, 0.8 percent of activating agent, 0.3 to 0.6 percent of phenolic antioxidant, 0.4 percent of tackifying resin and 1.0 percent of antifogging agent; the raw material B comprises insoluble sulfur, tetramethylthiuram monosulfide and an accelerant; and the ratio of the A to the insoluble sulfur to the tetramethylthiuram monosulfide to the accelerant is 500 : 1.0-2.5 :1.0 : 0.7. The anti-crocking rubber sole is prepared by banburying, mill opening, sulfur treatment, measurement of a vulcanizing curve, oil pressure molding and a crocking test.

Description

technical field [0001] The invention relates to a rubber sole, in particular to a production formula for a spray-out-proof rubber sole. Background technique [0002] China is currently the world's largest producer and exporter of footwear. However, the problem of frequent frosting on rubber soles has become one of the limiting factors for China's footwear industry at present, and frosting also has a certain seasonality. In summer and autumn, Blooming problems are more likely to occur. Frosting on the rubber surface not only seriously affects the appearance quality of the product, but also affects the service performance and life of the rubber product to a certain extent, and also affects the process performance and physical and mechanical properties of the rubber compound. Frosting will also cause scorching of the rubber material and aging of the product, which will accelerate the aging of the product and shorten the service life. The harm of blooming frost brings huge eco...

Claims

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Application Information

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IPC IPC(8): A43B13/04C08L9/00C08K3/06C08K3/36C08K5/09C08J3/24B29C43/02B29B7/28B29B7/72G01N33/44G01N17/00
Inventor 林松柏李清彪苏金定丁建平邹友思王远鹏贾立山
Owner 泉州泰亚鞋业有限公司
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