The present invention relates to a 1, 5, 9-trisubstituted
coronene compound and a synthesis method thereof. The
structural formula of the compound is shown in
img file = 'dest _ path _ image 001. TIF 'wi = '109 'he = '108', wherein R represents H, C1-C18
alkyl, phenyl, 4-methylphenyl, 4-methoxy phenyl, benzyl, cyclohexyl, 4-trifluoromethylphenyl,
thiophene,
furan and the like. According to the technical scheme of the invention, the easily prepared 1, 5, 9-triamido
triphenylene is subjected to diazotization and
halogenation reaction to obtain the tri-halogenated
triphenylene. After that, the tri-halogenated
triphenylene is subjected to Sonogashira reaction with various alkynes to generate atriyne-triphenylene compounds. Finally, through the
metal-catalyzed reaction and the cyclization reaction under the effect of an
organic base, various 1, 5, 9-trisubstituted
coronene compounds, novel in structure, can be obtained. According to the technical scheme of the invention, raw materials are easy for
mass preparation. Meanwhile, the synthesis step is relatively short and the operation is convenient. The obtained trisubstituted
coronene compound is good in
thermal stability and
chemical stability, and the trisubstituted coronene emits the relatively strong
fluorescence within the range of 420-550 nm according to the
fluorescence emission spectrum of the trisubstituted coronene compound. Therefore, the trisubstituted coronene is an excellent fluorescent material for preparing UV
ultraviolet charge-coupled devices (UV-CCD) and organic light-emitting diodes (OLEDs), and has a wide application prospect in the field of
electronic materials.