The invention pertains to the technical field of treatment of waste water, and particularly relates to a method of
hydrolysis-catalytic iron-aerobic
coupling for treating poisonous and harmful hard-degradation waste water, which comprises the following steps: waste water after
primary treatment directly enters an up flow type
hydrolysis system 1 and stays for 4.0-10.0 hours; the
effluent enters an
electrolytic cell in the catalytic iron; the
mass ratio of iron scraps and
copper scraps in the
electrolytic cell of the catalytic iron is 1:1 to 20:1, the bulk
specific weight thereof is 0.1 to 0.3, the
contact time thereof in a filling area is 0.5 to 2.0 hours, and the
reflux ratio of the
effluent refluxing to the up flow type
hydrolysis system is 20 to 100 percent; the
effluent enters an aerobic biological
treatment system and stays for 6.0 to 12.0 hours; then the effluent enters a
solid-liquid
separation system with a
reflux ratio of
sludge being 10 to 50 percent; and the effluent of the
solid-liquid
separation system refluxes to the
electrolytic cell of the catalytic iron with the
reflux ratio being 20 to 200 percent. Under the premise of fully playing the function of different treatment units and maintaining the
treatment effect and respective advantages, the treatment method of waste water realizes the
coupling synergetic action of the three units, strengthens the
impact of the
system to
water quality and water quantity load, reduces a plurality of steps of pretreatment, effectively improves the removal rate of
ammonia nitrogen, and can be flexibly adjusted.