The invention discloses a stirling thermoelectric generation mechanism which belongs to the energy field, mainly faces thermoelectric generation and aims at utilizing low-
temperature difference residual heat or residual cool. A
steam engine based on
Rankine cycle utilizes high-pressure steam generated in the water gasification process to push a
steam turbine to do work, and the
heat energy is converted into the
electric energy, so that the
steam engine is usually used for recovering industrial residual heat with the temperature being 400-600 DEG C; as for the residual heat with the temperature lower than 200 DEG C, an organic working substance with the
boiling point smaller than that of water is adopted, namely an
organic Rankine cycle residual
heat power generation technology is adopted, but complex
thermodynamic process including
phase transition of the organic working substance is involved, so that the
system has a complex structure, is high in cost and is not widely applied in China at present. According to the stirling thermoelectric generation mechanism disclosed by the invention, with the traditional
stirling engine as a basis, a novel gas distribution
piston structure made of a heat conductive material is added, the heat exchange efficiency of working gas and residual heat or residual
cool storage working substance is improved, the residual heat or residual cool with a
temperature difference lower than 200 DEG C is recovered, and the problems of complex structure and high cost caused by
phase transition of the organic working substance are solved.