475results about "Working-up pitch/asphalt/bitumen" patented technology

A wide-cut lubricant base stock is made by hydroisomerizing and then catalytically dewaxing a waxy Fischer-Tropsch synthesized hydrocarbon fraction feed and comprises the entire dewaxate having an initial boiling point in the 650-75O° F.+ range. Formulated lubricating oils made by admixing the base stock with a commercial automotive additive package meet all specifications, including low temperature properties, for multigrade internal combustion engine crankcase oils. The waxy feed has an initial boiling point in the 650-750° F. range and continuously boils to an end point of at least 1050° F.+. Lower boiling hydrocarbons produced by the process are separated from the base stock by simple flash distillation. The base stock comprises the entire dewaxate having an initial boiling point in the 650-750° F. range.

This invention relates to a novel method for economically processing vacuum residue from heavy crude oils by selectively processing the difficult and easy components in reactors whose design and operating conditions are optimized for the specific feed. The process utilizes an integrated solvent deasphalting (SDA)/ebullated-bed design wherein the heavy vacuum residue feedstock is initially sent to an SDA unit operated with C₄/C₅ solvent to achieve a high deasphalted oil (DAO) yield. The resulting SDA products, namely asphaltenes and DAO are separately treated in ebullated-bed reactor(s) systems whose design and operating conditions are optimized for a particular feedstock. The resulting net conversion, associated distillate yield and product qualities are greatly improved relative to treatment of the entire residue feedstock in a common ebullated-bed reactor system.

This invention relates to a novel integrated method for economically processing vacuum residue from heavy crude oils. This is accomplished by utilizing a solvent deasphalter (SDA) in the first step of the process with a C₃/C₄/C₅ solvent such that the DAO product can thereafter be processed in a classic fixed-bed hydrotreater or hydrocracker. The SDA feed also includes recycled stripper bottoms containing unconverted residue/asphaltenes from a downstream steam stripper unit. The asphaltenes from the SDA are sent to an ebullated-bed reactor for conversion of the residue and asphaltenes. Residue conversion in the range of 60-80% is achieved and asphaltene conversion is in the range of 50-70%. The overall residue conversion, with the DAO product considered non-residue, is in the range of 80 W %-90 W % and significantly higher than could be achieved without utilizing the present invention.

The present invention is directed to the upgrading of heavy petroleum oils of high viscosity and low API gravity that are typically not suitable for pipelining without the use of diluents. It utilizes a short residence-time pyrolytic reactor operating under conditions that result in a rapid pyrolytic distillation with coke formation. Both physical and chemical changes taking place lead to an overall molecular weight reduction in the liquid product and rejection of certain components with the byproduct coke. The liquid product is upgraded primarily because of its substantially reduced viscosity, increased API gravity, and the content of middle and light distillate fractions. While maximizing the overall liquid yield, the improvements in viscosity and API gravity can render the liquid product suitable for pipelining without the use of diluents. This invention particularly relates to reducing sulfur emissions during the combustion of byproduct coke (or coke and gas), to reducing the total acid number (TAN) of the liquid product, and to reducing the hydrogen sulfide content of one, or more than one component of the product stream. The method comprises introducing a particulate heat carrier into an up-flow reactor, introducing the feedstock at a location above the entry of the particulate heat carrier, allowing the heavy hydrocarbon feedstock to interact with the heat carrier for a short time, separating the vapors of the product stream from the particulate heat carrier and liquid and byproduct solid matter, regenerating the particulate heat carrier in the presence of the calcium compound, and collecting a gaseous and liquid product from the product stream.

A process derived hydrogen donor solvent is used to increase the maximum resid conversion and conversion rate in an ebullated bed resid hydrocracker. The hydrogen donor solvent precursor is produced by hydroreforming reactions within the resid hydrocracker, recovered as the resin fraction from a solvent deasphalting unit, regenerated in a separate hydrotreater reactor, and recycled to the ebullated bed resid hydrocracker. The major advantage of this invention relative to earlier processes is that hydrogen is more efficiently transferred to the resin residual oil in the separate hydrotreater and the hydrogen donor solvent effectively retards the formation of coke precursors at higher ebullated bed resid hydrocracker operating temperatures and resid cracking rates.

One exemplary embodiment can include a slurry hydrocracking process. The process can include combining one or more hydrocarbons and a slurry hydrocracking catalyst as a feed to a slurry hydrocracking reaction zone, fractionating an effluent from the slurry hydrocracking reaction zone, separating the pitch from at least a portion of the slurry hydrocracking catalyst, and recycling the suspension to the slurry hydrocracking reaction zone. The slurry hydrocracking catalyst may include a support. Fractionating the effluent may provide a light vacuum gas oil, a heavy vacuum gas oil, and a mixture comprising a pitch and the slurry hydrocracking catalyst. Generally, the separated slurry hydrocracking catalyst is comprised in a suspension.

The present invention is directed to the upgrading of heavy petroleum oils of high viscosity and low API gravity that are typically not suitable for pipelining without the use of diluents. It utilizes a short residence-time pyrolytic reactor operating under conditions that result in a rapid pyrolytic distillation with coke formation. Both physical and chemical changes taking place lead to an overall molecular weight reduction in the liquid product and rejection of certain components with the byproduct coke. The liquid product is upgraded primarily because of its substantially reduced viscosity, increased API gravity, and the content of middle and light distillate fractions. While maximizing the overall liquid yield, the improvements in viscosity and API gravity can render the liquid product suitable for pipelining without the use of diluents. This invention particularly relates to reducing sulfur emissions during the combustion of byproduct coke (or coke and gas) and to reducing the total acid number (TAN) of the liquid product. The method comprises introducing a particulate heat carrier into an up-flow reactor, introducing the feedstock at a location above the entry of the particulate heat carrier, allowing the heavy hydrocarbon feedstock to interact with the heat carrier for a short time, separating the vapors of the product stream from the particulate heat carrier and liquid and byproduct solid matter, regenerating the particulate heat carrier in the presence of the calcium compound, and collecting a gaseous and liquid product from the product stream.

The present invention provides one kind of waste rubber powder modified asphalt and its preparation process. In the temperature of 150-200 deg.c, waste tyre rubber powder of different grain size within 60 mesh, thermoplastic rubber and stabilizer in certain proportion are added into asphalt; and the mixture is processed in high shearing apparatus or colloid mill to prepare the asphalt product with high storage stability and excellent high and low temperature performance. The simple production process is suitable for industrial production.

The invention relates to processes for removing impurities, such as asphalt, from whole crude oil. The invention is accomplished by first deasphalting a feedstock, followed by processing resulting DAO and asphalt fractions. The DAO fraction is hydrocracked, resulting in removal of sulfur and hydrocarbons which boil at temperatures over 370° C., and gasifying the asphalt portion.

Feed oil is subject to atmospheric distillation, to thereby be separated into light oil or light distillate and atmospheric residue oil. The light distillate is catalytically contacted with pressurized hydrogen in the presence of a catalyst, resulting in a first hydrotreating step being executed. In this instance, various fractions of the light distillate produced in the atmospheric distillation are subject to hydrotreating in a lump. The atmospheric residue oil is then separated into a light matter and a heavy matter. The light matter is subject to second hydrotreating in the presence of a catalyst to produce refined oil (light matter), which is mixed with refined oil produced in the first hydrotreating to prepare a mixture. The mixture is used as gas turbine fuel oil.

A paving asphalt composition for improving the durability and longevity of asphalt road surfaces is disclosed. The paving asphalt composition includes asphalt base stock, heavy residuum of re-refined motor oil, and a chemical modifier. The heavy residuum of re-refined motor oil preferably has an API gravity of at least about 12, a kinematic viscosity greater than about 400 centistokes at 140 DEG F., a flash point greater than about 400 DEG F. and a mass loss less than about 3%. The paving asphalt composition may also include a polymer. A method of forming the paving asphalt composition and a method of paving roads are also disclosed.

Integrated slurry hydrocracking (SHC) and coking methods for making slurry hydrocracking (SHC) distillates are disclosed. Representative methods involve passing a slurry comprising a deasphalted oil (DAO) produced in a solvent deasphalting (SDA) process, optionally with recycled SHC gas oil and recycled SHC pitch, and a solid particulate through an SHC reaction zone in the presence of hydrogen to obtain the SHC distillate. Recovery and recycle of SHC gas oil and pitch from the SHC effluent improves the overall conversion to naphtha and distillate products and decreases catalyst requirements.

A method for manufacturing a processed asphalt suspension is provided. The method includes dry grinding shingle waste material to a particle size of less than 1 cm, forming ground recycled shingle material, introducing virgin asphalt into a heated slurry tank and mixing the ground recycled shingle material with the virgin asphalt in the heated slurry tank, forming a mixed asphalt slurry, introducing the mixed asphalt slurry into a wet grinding machine, and recovering a processed asphalt suspension comprising particles having a size no greater than about 200 microns. Roofing and paving products manufactured from the processed asphalt suspension are also provided.

The invention relates to a coal tar pitch refining method, in particular to a method for refining pitch for coal tar pitch needle coke, impregnant and binding agent for manufacturing high-power and ultrahigh-power graphite electrodes and pitch for manufacturing coal tar pitch carbon fibers. The method is characterized in that the method comprises the following steps: diluting coal tar pitch and the liquid containing coal tar pitch with organic solvent at a weight ratio of the organic solvent to coal tar pitch and the liquid containing coal tar pitch of 1:(5 to 30), removing impurities in the pitch solution by the combination of separation by a centrifuge and filtering with an organic film, and distilling and recovering the solvent in the refined mixture solution to obtain the coal tar pitch free of quinoline insoluble materials. The method has the advantages of good continuity of the separation process and high efficiency, and the pitch contains no quinoline insoluble materials.

A process and apparatus to remove asphaltenic contaminants from bitumen, heavy oil or residue to produce lower viscosity petroleum products and high purity asphaltenes.

A chemical composition of matter comprising a wax plasticizing agent (plasticizer) tributoxyethyl phosphate, a mixture of selected long chain fatty acids (preferably C₁₀ to C₂₂), and a mixture of selected low-surface tension surfactants, which when added in solution to crude oil or refined products has been shown to lower both the B.S. & W. (rag layer) and the coefficient of friction of crude oils and refined products. This chemical composition of matter is particularly useful as a wax liquefaction, dispersant, and solubilization agent for asphaltene and paraffins in crude oil and refined products. The reduction in the co-efficient of friction resulting from the addition of this product to crude oil will allow crude oil to pump through pipelines with a minimum amount of resistance due to friction (drag).

The invention provides a lubricating base oil with a saturated component content of 90% by mass or greater, a proportion of cyclic saturated components of no greater than 40% by mass of the saturated components, a viscosity index of 110 or greater, an aniline point of 106 or greater and an ε-methylene proportion of 14-20% of the total constituent carbons, as well as a lubricating oil composition comprising the lubricating base oil.

In the invention, tar is upgraded by deasphalting and then hydrocracking to produce valuable products such as low sulfur diesel fuel and mogas. The invention is also directed to a system integrating a pyrolysis furnace operation with refinery operations.

The present invention is directed to the upgrading of heavy hydrocarbon feedstock that utilizes a short residence pyrolytic reactor operating under conditions that cracks and chemically upgrades the feedstock. The process of the present invention provides for the preparation of a partially upgraded feedstock exhibiting reduced viscosity and increased API gravity. This process selectively removes metals, salts, water and nitrogen from the feedstock, while at the same time maximizes the yield of the liquid product, and minimizes coke and gas production. Furthermore, this process reduces the viscosity of the feedstock in order to permit pipeline transport, if desired, of the upgraded feedstock with little or no addition of diluents. The method for upgrading a heavy hydrocarbon feedstock comprises introducing a particulate heat carrier into an upflow reactor, introducing the heavy hydrocarbon feedstock into the upflow reactor at a location above that of the particulate heat carrier so that a loading ratio of the particulate heat carrier to feedstock is from about 15:1 to about 200:1, allowing the heavy hydrocarbon feedstock to interact with the heat carrier with a residence time of less than about 1 second, to produce a product stream, separating the product stream from the particulate heat carrier, regenerating the particulate heat carrier, and collecting a gaseous and liquid product from the product stream. This invention also pertains to the products produced by the method.

Viscoelastic surfactant based aqueous fluid systems useful as thickening agents in various applications, e.g. to suspend particles produced during the excavation of geologic formations. The surfactants are zwitterionic/amphoteric surfactants such as dihydroxyl alkyl glycinate, alkyl ampho acetate or propionate, alkyl betaine, alkyl amidopropyl betaine and alkylimino mono- or di-propionates derived from certain waxes, fats and oils. The thickening agent is used in conjunction with an inorganic water-soluble salt or organic additive such as phthalic acid, salicylic acid or their salts.

Various systems and methods are described that can be used as part of a process to separate bitumen from oil sands. The process may include adding a hydrocarbon solvent to a bitumen containing extract. The tailings from this process may contain a significant amount of solvent. The solvent may be recovered from the tailings with a tailings solvent recovery unit that utilizes negative pressure to significantly reduce the cost of the process in comparison to a conventional steam stripping unit. In one embodiment, the tailings may also separated prior to entering the tailings solvent recovery unit with a gravity separation apparatus or a cyclonic separation apparatus, such as a hydrocyclone.

Recycled tire rubber, either in the presence or the absence of carbonaceous waste solids such as those from petroleum refinery operations, is first subjected to a heat treatment to release volatile materials and then combined with a liquid asphalt composition to achieve an asphalt mastic that is storage stable and of uniform consistency.

A method and a system for transporting a flow of fluid hydrocarbons containing wax and/or asphaltenes or any other precipitating solids through a treatment and transportation system including a pipeline are disclosed. The flow of fluid hydrocarbons is introduced into a reactor (4), where it is mixed with another fluid flow having a temperature below a crystallization temperature for the wax and/or asphaltenes or other solids and containing particles or crystals acting as nucleating and/or growth cores for the wax and/or asphaltenes or other solids, the mixing temperature providing precipitation of the wax and/or asphaltenes or other solids from the flow of fluid hydrocarbons, and the effluent flow of hydrocarbons and particles is conveyed from the reactor (4) to a pipeline (6) for transportation.