The invention relates to a ZSM-22/ ZSM-23 composite molecular sieve and a method for synthesis it, which contains: mixing ZSM-22 molecular sieve with alumina silica colloid prepared by mixing carbon source, aluminum source, inorganic base, water with template agent, and adjusting the acid-base quality of the solution with inorganic acid to prepare initial colloid, the mole composition of the colloid being: SiO2/ Al2O3= 60-300, R/SiO2= 0.05-3, OH-/ SiO2= 0.05-0.5, M/ SiO2=0.1-0.5, H2O/ SiO2= 10-65, the usage of ZSM-22 molecular sieve being 1-60% of silica dioxide by weight, and the temperature agent being one or more of pyrrolidine, isopropyl amine or isobutylamine. The ZSM-22/ ZSM-23 composite molecular sieve is prepared by hydrothermal crystallization of initial colloid.